• Title/Summary/Keyword: Reduction Orientation

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Effect of Natural Convection Instability on Reduction of Fouling and Increasing of Critical Flux in Constant-flow Ultrafiltration (정유량 한외여과에서 자연대류 불안정성의 막오염 감소 및 임계 플럭스 증가 효과)

  • Jang, A-Rum;Nam, Sang-Won;Youm, Kyung-Ho
    • Membrane Journal
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    • v.22 no.5
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    • pp.332-341
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    • 2012
  • We studied the effects of induction of natural convection instability flow (NCIF) according to the gravitational orientation (inclined angle) of the membrane cell on the reduction of membrane fouling in the constant-flow ultrafiltration (UF) of colloidal silica solutions. Five colloidal silica solutions with different silica size (average size = 7, 12, 22, 50 nm and 78 nm) were used as UF test solutions. The silica particles in colloidal solutions form cakes on the membrane surface thereby causing severe membrane fouling. The constant-flow UF performance according to the gravitational orientation of the membrane cell (from $0^{\circ}$ to $180^{\circ}$ inclined angle), was examined in an unstirred dead-end cell. We evaluate the effects of NCIF on the suppression of fouling formation by measuring the variation of transmembrane pressure (TMP) and the increase of critical flux by using the flux-stepping method. In the constant-flow dead-end UF for the smaller size (7, 12 nm and 22 nm) silica colloidal solutions, changing the gravitational orientation (inclined angle) of the membrane cell above the $30^{\circ}$ angle induces NCIF in the membrane module. This induced NCIF enhances back transport of the deposited silica solutes away from the membrane surface, therefore gives for the reduction of TMP. But in the constant-flow UF for the more larger size (50 nm and 78 nm) silica colloidal solutions, NCIF effects are not appearing. The critical flux is increased as increasing the module angle and decreasing the silica size. Those results show that the intesity of NCIF occurrence in membrane module is more higher as increasing the module angle and decreasing the silica size.

Regulation Mechanism of Redox Reaction in Rubredoxin

  • Tongpil Min;Marly K. Eidsness;Toshiko Ichiye;Kang, Chul-Hee
    • Journal of Microbiology
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    • v.39 no.3
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    • pp.149-153
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    • 2001
  • The electron transfer reaction is one of the most essential processes of life. Not only does it provide the means of transforming solar and chemical energy into a utilizable form for all living organisms, it also extends into a range of metabolic processes that support the life of a cell. Thus, it is of great interest to understand the physical basis of the rates and reduction potentials of these reactions. To identify the major determinants of reduction potentials in redox proteins, we have chosen the simplest electron transfer protein, rubredoxin, a small (52-54 residue) iron-sulfur protein family, widely distributed in bacteria and archaea. Rubredoxins can be grouped into two classes based on the correlation of their reduction potentials with the identity of residue 44; those with Ala44 (ex: Pyrococcus furiosus) have reduction potentials that are ∼50 mV higher than those with Va144 (ex: Clostridium pasteurianum). Based on the crystal structures of rubredoxins from C. pasteurianum and P. furiosus, we propose the identity of residue 44 alone determines the reduction potential by the orientation of the electric dipole moment of the peptide bond between 43 and 44. Based on 1.5 $\AA$ resolution crystal structures and molecular dynamics simulations of oxidized and reduced rubredoxins from C. pasteurianum, the structural rearrangements upon reduction suggest specific mechanisms by which electron transfer reactions of rubredoxin should be facilitated.

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Influence of thermo-physical properties on solutal convection by physical vapor transport of Hg2Cl2-N2 system: Part I - solutal convection

  • Kim, Geug-Tae;Kim, Young-Joo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.3
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    • pp.125-132
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    • 2010
  • For typical governing dimensionless parameters of Ar = 5, Pr = 1.16, Le = 0.14, Pe = 3.57, Cv = 1.02, $Gr_s=2.65{\times}10^6$, the effects of thermo physical properties such as a molecular weight, a binary diffusivity coefficient, a partial pressure of component B on solutally buoyancy-driven convection (solutal Grashof number $Gr_s=2.65{\times}10^6$) are theoretically investigated for further understanding and insight into an essence of solutal convection occurring in the vapor phase during the physical vapor transport of a $Hg_2Cl_2-N_2$ system. The solutally buoyancy-driven convection is significantly affected by any significant disparity in the molecular weight of the crystal components and the impurity gas of nitrogen. The solutal convection in a vertical orientation is found to be more suppressed than a tenth reduction of gravitational accelerations in a horizontal orientation. For crystal growth parameters under consideration, the greater uniformity in the growth rate is obtained for either solutal convection mode in a vertical orientation or thermal convection mode in horizontal geometry. The growth rate is also found to be first order exponentially decayed for $10{\leq}P_B{\leq}200$ Torr.

Impact of composite patch on the J-integral in adhesive layer for repaired aluminum plate

  • Kaci, D. Ait;Madani, K.;Mokhtari, M.;Feaugas, X.;Touzain, S.
    • Advances in aircraft and spacecraft science
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    • v.4 no.6
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    • pp.679-699
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    • 2017
  • The aim of this study is to perform a finite element analysis of the Von Mises stresses distribution in the adhesive layer and of the J-Integral for a damaged plate repaired by a composite patch. Firstly, we study the effect of the fiber orientation, especially the position of the layers that have orientation angle different of $0^{\circ}$ from the first layer which is in all cases of our study oriented at ($0^{\circ}$) on the J-Integral. Secondly, we evaluate the effects of the mechanical properties of the patch and the use of a hybrid patch on the reduction of stresses distribution and J-Integral. The results show clearly that the stacking sequence for the composite patch must be selected to absorb optimally the stresses from the damaged area and to position the various layers of the composite under the first layer whose fibers orientation will remain in all cases equal to $0^{\circ}$. The use of a hybrid composite reduces significantly the J-Integral and the stresses in both damaged plate and the adhesive layer.

High Temperature Tensile Property of Transient Liquid Bonded Joints of Ni-base Single Crystal Superalloy (액상확산접합한 Ni기 단결정 초내열합금의 고온인장특성)

  • 김대업;강정윤
    • Journal of Welding and Joining
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    • v.18 no.3
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    • pp.106-113
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    • 2000
  • Single crystallization behavior ad high temperature tensile properties of TLP bonded joints of Ni-base single crystal superalloy, CMSX-2 were investigated using MBF-80 and F-24 insert metals. CMSX-2 was bonded at 1523~1548K for 1.5~1.8ks in vacuum. The (100) orientation of bonded specimen was aligned perpendicular to the joint interface. Crystallographic orientation analyzed points over the bonded region possessed the almost same orientation across the joint interface and misorientation $\Delta^{\theta}$ was negligibly small in as-bonded and post-bond heat-treated situations. It was confirmed that single crystallization could be readily achieved during TLP bonding. The tensile strengths of all joints at elevated temperatures were equal to or greater than those of base metal the range of testing temperature between 923K and 1173K. The elongation and reduction of area in values were almost the same as those of base metal. SEM observation of the fracture surfaces of joints after tensile test revealed that the fracture surface indicated the similar morphologies each other, and that the fracture of joints occurred in the base metal in any cases.

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Study on Characteristics of Electrodeposited Thin Copper Film by Inorganic Additives in Pyrophosphate Copper Plating Bath (피로인산동욕의 무기첨가제에 의한 전해동박의 특성에 관한 연구)

  • Koo, Seokbon;Hur, Jinyoung;Lee, Hongkee
    • Journal of Surface Science and Engineering
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    • v.47 no.1
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    • pp.1-6
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    • 2014
  • The copper deposit on steel plate was prepared by pyrophosphate copper plating solution made with variation of inorganic additive. $NH_4OH$ and $NH_4NO_3$ were used as inorganic additives. The copper layer characteristics - tensile strength, crystallite size and crystal orientation - were evaluated by X-ray diffraction and Universal Test Machine. The presence of ammonium nitrate results in reduction of average roughness value from $0.08{\mu}m$ to $0.03{\mu}m$. In pyrophosphate copper plating solution without Inorganic additive, tensile strength of electrodeposit copper foil was reduced from 600 MPa to 180 MPa after 7 days aging. However, when adding ammonium nitrate, there was almost no change of tensile strength, intensity of crystal orientation - (111), (200) and (220) - and crystallite size (2~30 nm).

Gross Error Detection and Determination of Exterior Orientation Elements in Non-metric Photos (비측량용(非測量用) 사진(寫眞)에서의 과대오차(過大誤差) 검출(檢出) 및 외부표정요소(外部標定要素) 결정(決定))

  • Yeu, Bock Mo;Sohn, Duke Jae;Park, Hong Gi
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.4
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    • pp.125-132
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    • 1987
  • The bundle adjustment used in photogrammetric data reduction is based on the collinearity condition. Photogrammetry has been used in many non-topographic applications. Due to the necessities of having fiducial marks and knowing initial approximations for interior and exterior orientation elements in bundle adjustment, it cannot be applied when non-metric cameras are used. Marzan and Karara develop the DLT(Direct Linear Transformation) program which directly transforms comparator coordinates into object space coordinates without approximate values. In this paper, several modifications of original DLT program have been made for accuracy improvement in close-range photogrammetry using non-metric cameras. In modified program, gross error detection method and computation of exterior orientation elements are incorporated, and more iterations are introdued.

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The study of the relationships between the MgO crystal orientation and the conditions of deposition on AC-PDP (AC PDP의 MgO 결정방향성과 증착조건간의 상관관계에 관한 연구)

  • Jang, Yong-Min;Heo, Jeong-Eun;Kim, Duk-Won;Shin, Joong-Hong;Park, Chung-Hoo
    • Proceedings of the KIEE Conference
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    • 2006.07c
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    • pp.1523-1524
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    • 2006
  • There arc several important issues in AC PDP researches such as cost reduction, reliability, and good image quality. The properties of MgO layer is thought to be one of the most important (actors that affects the panel reliability through the firing voltage variation. The MgO thin film mainly has (111), (200) and (220) crystal orientation. It is reported that (111)-oriented film helps decreasing the discharge voltage, and (200)-oriented film improves the misfiring on high temperature and the image sticking. In this study, we investigated the relations between the crystal orientation and e-beam evaporation process parameters such asdeposition rate, temperature of substrate, and distance between the target(MgO tablet) and the substrate.

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Foodborne Pathogen Reduction을 위한 항균제의 새로운 Delivery System인 Aerosolization

  • O, Se-Uk;Gang, Dong-Hyeon
    • Bulletin of Food Technology
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    • v.18 no.1
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    • pp.91-98
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    • 2005
  • Aims: As a preliminary experiment on new sanitizer delivery tools, the efficacy of aerosolizedsanitizer on foodborne pathogens was investigated in larger model chamber system.Methods: Peroxyacetic acid and hydrogen peroxide were aerosolized in a model system againstartificially inoculated target microorganisms on laboratory media. Cultures of 4 different foodborne pathogens were inoculated and affixed onto 3 different heights (bottom, wall, and ceiling), and 3different orientations (face-down, vertical, and face-down) inside a commercial semi-trailer cabinet(14.6 x 2.6 x 2.8 m). Sanitizer was aerosolized into 2 m droplet size fog and treated for 1 h atambient temperature.Results: Populations of Bacillus cereus, Listeria innocua, Staphylococcus aureus, and Salmonellatyphimurium were reduced by an average of 3.09, 7.69, 6.93 and 8.18 log units per plate, respectively.Interestingly, L. innocua, Staph. aureus, and Salm. typhimurium showed statistically not different (P$\leq$ 0.05) reduction patterns relative to height and orientation that were never expected in a sprayingsystemConclusion and significance: Aerosolized sanitizers diffuse like gaseous sanitizers, so it has greatpotential for use in commercial applications.

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Comparison Analysis of Factor of Safety on Rock Slope in Boeun Region Using Limit Equilibrium Method and Distinct Element Method (한계평형법과 개별요소법을 이용한 보은지역 암반사면 안전율 비교해석)

  • 이지수;유광호;박혁진;민경덕
    • Proceedings of the Korean Geotechical Society Conference
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    • 2002.03a
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    • pp.643-650
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    • 2002
  • The large planar failure has occurred in a rock cut slope of highway construction site in Boeun. This area is considered as unstable since the discontinuities whose orientations are similar to the orientation of the failure plane, are observed in many areas. Therefore, several analysis techniques such as SMR, stereographic analysis, limit equilibrium, numerical analysis, which are commonly used in rock slope stability analysis, are adopted in this area. In order to analyze the stress redistribution and nonlinear displacement caused by cut, which are not obtained in limit equilibrium method, the UDEC and shear strength reduction technique were used in this study Then the factors of safety evaluated by shear strength reduction technique and limit equilibrium were compared. In addition, the factor of safety under fully saturated slope condition was calculated and subsequently, the effect of the reinforcement was evaluated.

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