• Title/Summary/Keyword: Reduction Model

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Assessment factors for the Selection of Priority Soil Contaminants based on the Comparative Analysis of Chemical Ranking and Scoring Systems (국내.외 Chemical Ranking and Scoring 체계 비교분석을 통한 우선순위 토양오염물질 선정을 위한 평가인자 도출)

  • An, Youn-Joo;Jeong, Seung-Woo;Kim, Tae-Seung;Lee, Woo-Mi;Nam, Sun-Hwa;Baek, Yong-Wook
    • Journal of Soil and Groundwater Environment
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    • v.13 no.6
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    • pp.62-71
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    • 2008
  • Soil quality standards (SQS) are necessary to protect the human health and soil biota from the exposure to soil pollutants. The current SQS in Korea contain only sixteen substances, and it is scheduled to expand the number of substances. Chemical ranking and scoring (CRS) system is very effective to screen the priority chemicals for the future SQS in terms of their toxicity and exposure potential. In this study, several CRS systems were extensively compared to propose the assessment factors that required for the screening of soil pollutants The CRS systems considered in this study include the CHEMS-1 (Chemical Hazard Evaluation for Management Strategies), SCRAM (Scoring and Ranking Assessment Model), EURAM (European Union Risk Ranking Method), ARET (Accelerated Reduction/Elimination of Toxics), CRSKorea, and other systems. The additional assessment factors of CRS suitable for soil pollutants were suggested. We suggest soil adsorption factor as an appropriate factor of CRS system to consider chemical transport from soil to groundwater. Other factors such as soil emission rate and cases of accident of soil pollutants were included. These results were reflected to screen the priority chemicals in Korea, as a part of the project entitled ‘Setting the Priority of Soil Contaminants'.

Effect of Iron Activators on the Persulfate Oxidation of Polycyclic Aromatic Hydrocarbons (PAHs) in Contaminated Soils (다환방향족 탄화수소(PAHs) 오염토양의 과황산 산화 시 철 활성화제의 영향)

  • Choi, Jiyeon;Park, Jungdo;Shin, Won Sik
    • Journal of Soil and Groundwater Environment
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    • v.25 no.1
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    • pp.62-73
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    • 2020
  • PAHs commonly found in industrial sites such as manufactured gas plants (MGP) are potentially toxic, mutagenic and carcinogenic, and thus require immediate remediation. In-situ chemical oxidation (ISCO) is known as a highly efficient technology for soil and groundwater remediation. Among the several types of oxidants utilized in ISCO, persulfate has gained significant attention in recent years. Peroxydisulfate ion (S2O82-) is a strong oxidant with very high redox potential (E0 = 2.01 V). When mixed with Fe2+, it is capable of forming the sulfate radical (SO4) that has an even higher redox potential (E0 = 2.6 V). In this study, the influence of various iron activators on the persulfate oxidation of PAHs in contaminated soils was investigated. Several iron sources such as ferrous sulfate (FeSO4), ferrous sulfide (FeS) and zero-valent iron (Fe(0)) were tested as a persulfate activator. Acenaphthene (ANE), dibenzofuran (DBF) and fluorene (FLE) were selected as model compounds because they were the dominant PAHs found in the field-contaminated soil collected from a MGP site. Oxidation kinetics of these PAHs in an artificially contaminated soil and the PAH-contaminated field soil were investigated. For all soils, Fe(0) was the most effective iron activator. The maximum PAHs removal rate in Fe(0)-mediated reactions was 92.7% for ANE, 83.0% for FLE, and 59.3% for DBF in the artificially contaminated soil, while the removal rate of total PAHs was 72.7% in the field-contaminated soil. To promote the iron activator effect, the effects of hydroxylamine as a reducing agent on reduction of Fe3+ to Fe2+, and EDTA and pyrophosphate as chelating agents on iron stabilization in persulfate oxidation were also investigated. As hydroxylamine and chelating agents (EDTA, pyrophosphate) dosage increased, the individual PAH removal rate in the artificially contaminated soil and the total PAHs removal rate in the field-contaminated soil increased.

Analysis of the Behavior of Fluorescent Whitening Agents in Recycling Process of White Ledger (형광증백제가 함유된 백상고지의 재활용에 따른 형광증백제의 거동 분석)

  • Lee, Ji Young;Kim, Chul Hwan;Park, Jong-Hye;Kim, Eun-Hea;Sung, Yong Joo;Heo, Young-Jun;Kim, Young-Hoon;Kim, Yeon-Oh
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.1
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    • pp.52-58
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    • 2015
  • White ledger usually includes white office paper, computer paper, and copy machine paper. Because these grades need high optical properties, fluorescent whitening agents (FWAs) are widely used in the papermaking process. FWAs are the most powerful and effective chemical used to obtain high CIE whiteness and ISO brightness in papers. The rising demand for white or ultra-white papers has increased the use of FWAs. However, FWAs used in white ledger can restrict its use, even though white ledger is widely used as a raw material in paperboard mills. Therefore, it is necessary to develop methods to control FWAs from white ledger to increase its use in paperboard mills. In this study, the behaviors of disulpho fluorescent whitening agent (D-FWA), tetrasulpo fluorescent whitening agent (T-FWA), and hexasulpho fluorescent whitening agent (H-FWA) during the recycling process were identified as a first step to remove FWAs from white ledger. We prepared four types of papers (dyed with D-FWA, T-FWA, and H-FWA), disintegrated these papers, and made handsheets. This recycling process was carried out three times in a laboratory. After each round of recycling, the hand-sheets' CIE whiteness and fluorescence index were measured, and the distribution of FWAs in the Z-direction was observed using CLSM images. FWA reductions in the model papers were calculated using fluorescence indices as a function of the number of recycling. FWAs in handsheets containing T-FWA and H-FWA decreased linearly as a function of the number of recycling, but D-FWA did not show a significant reduction in the fluorescence index after recycling. T-FWA and H-FWA showed similar distributions of D-FWA after recycling. Therefore, as much T-FWA and H-FWA as possible must be detached in the early processes of papermaking at paperboard mills.

Numerical Analysis for Bed Changes in the Upstream Channel due to the Installation of Sediment Release Openings in the Flood Control Dam (홍수조절댐에서의 배사관 설치에 따른 상류 하천의 하상변동에 관한 수치모의 연구)

  • Ji, Un;Son, Kwang-Ik;Kim, Mun-Mo
    • Journal of Korea Water Resources Association
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    • v.42 no.4
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    • pp.319-329
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    • 2009
  • Sediment release openings or pipes are installed in the flood control dam constructed to reduce flood damages, which are to allow water and sediments pass through the dam and to prevent flow blockage and sedimentation in the upstream area of the dam. The Hantan River Flood Control Dam (HRFCD) has been projected for flood damage reduction and sediment release openings and ecological passages are considered for the dam design. In this study, sediment deposition due to the construction of HRFCD was analyzed using the HEC-6 model and compared with the state before the dam construction with respect to the conditions of the annual mean daily discharge and annual discharge hydrograph. According to the numerical results, although downstream water levels were changed by the dam structure, the effects of bed changes were not propagated from the dam over 2 km upstream. Also, 2D numerical models of RMA2 and SED2D were used to predict bed changes in the upstream area with and without sediment release openings. Consequently, it is presented that sediment release openings decreased maximum deposition height in the upstream channel of the dam.

Effects of the Trade Insurance and Exchange Risk on Export: The Experience of Korea (무역보험과 환위험이 수출에 미치는 영향)

  • Kim, Chang-Beom
    • International Commerce and Information Review
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    • v.13 no.3
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    • pp.77-95
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    • 2011
  • This paper investigates the relationship between export and economic variables such as trade insurance, world economy activity, relative price, unemployment rate, exchange rate volatility, using monthly data. I employ Johansen cointegration methodology since the model must be stationary to avoid the spurious results. The results indicate that there is a long-run relationship between export and variables. Also, the empirical analysis of cointegrating vector using the CCR, DOLS, FMOLS reveals that the increases of trade insurance has positive relations and the increases of exchange rate volatility have negative relations with export. Especially, DOLS based on Monte Carlo simulations, of this estimator being superior in small samples compared to a number of alternative estimators, as well as being able not only to accommodate higher orders of integration but also to account for possible simultaneity within regressors of a potential system. This paper also applies impulse-response functions to get the additional information regarding the responses of the export to the shocks of the variables. The result indicates that export positively to trade insurance and then decay fast compare with exchange rate volatility. Consequently, trade insurance plays the role of trade policy for export promotion in Korea. Whereas, increase of exchange risk result in reduction of export. Therefore, the support of trade insurance should be expanded and the stabilization of the foreign exchange market must be done for the export promotion.

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Herbal extract THI improves metabolic abnormality in mice fed a high-fat diet

  • Han, So-Ra;Oh, Ki-Sook;Yoon, Yoo-Sik;Park, Jeong-Su;Park, Yun-Sun;Han, Jeong-Hye;Jeong, Ae-Lee;Lee, Sun-Yi;Park, Mi-Young;Choi, Yeon-A;Lim, Jong-Seok;Yang, Young
    • Nutrition Research and Practice
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    • v.5 no.3
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    • pp.198-204
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    • 2011
  • Target herbal ingredient (THI) is an extract made from two herbs, Scutellariae Radix and Platycodi Radix. It has been developed as a treatment for metabolic diseases such as hyperlipidemia, atherosclerosis, and hypertension. One component of these two herbs has been reported to have anti-inflammatory, anti-hyperlipidemic, and anti-obesity activities. However, there have been no reports about the effects of the mixed extract of these two herbs on metabolic diseases. In this study, we investigated the metabolic effects of THI using a diet-induced obesity (DIO) mouse model. High-fat diet (HFD) mice were orally administered daily with 250 mg/kg of THI. After 10 weeks of treatment, the THI-administered HFD mice showed reduction of body weights and epididymal white adipose tissue weights as well as improved glucose tolerance. In addition, the level of total cholesterol in the serum was markedly reduced. To elucidate the molecular mechanism of the metabolic effects of THI in vitro, 3T3-L1 cells were treated with THI, after which the mRNA levels of adipogenic transcription factors, including C/$EBP{\alpha}$ and $PPAR{\gamma}$, were measured. The results show that the expression of these two transcription factors was down regulated by THI in a dose-dependent manner. We also examined the combinatorial effects of THI and swimming exercise on metabolic status. THI administration simultaneously accompanied by swimming exercise had a synergistic effect on serum cholesterol levels. These findings suggest that THI could be developed as a supplement for improving metabolic status.

Generation of Food Waste from Different Sources and Its Composting Measures at the Apartment Complex (배출원별 음식물 쓰레기 발생 특성 및 아파트 단지에서의 퇴비화 방안 (대전 및 충청남도 지역을 중심으로))

  • Kang, H.;Lee, O.L.;Kim, J.W.;Hur, H.W.;Han, S.H.
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.1
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    • pp.53-66
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    • 1998
  • This study was carried out to investigate the typical composition of food waste from municipal solid wastes (MSW) and unit food waste generation rates from different sources in the model cities and to study the food waste management system from unit household to composting facilities. The annual average food waste composition of MSW was determined as 49% in Taejon and 52% in Chungnam Province, respectively. No big difference in food waste composition was found among the different sources. Since the paper waste generally occupied the half of food waste, over 75% of MSW was found to be compostable or biodegradable. Per capita food waste generation rate, 200~250g/capita day was determined by the direct measurement from 32 households, while 380g/capita day for Chungnam Province and 400 g/capita day for Taejon were estimated by the load count analysis In the sanitary landfills. This difference means people contribute generating food waste at outside house approximately twice as much as that at inside house. Per capita food waste generation rates from several sources were determined as follows; 166~215g/capita day at municipalities, 400g/visitor day at a first class hotel, 170g/student day at a university restaurant. Food waste generation from restaurant was strongly dependant upon it's level or quality; 670g/capita day at the high level restaurant, 190g/capita day at the middle class and 60 g/capita day at the lower class restaurant. The food waste reduction rate in a In situ fermentor showed 30~40g/kg day.

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Optimal Site Selection of Carbon Storage Facility using Satellite Images and GIS (위성영상과 GIS를 활용한 CO2 지중저장 후보지 선정)

  • Hong, Mi-Seon;Sohn, Hong-Gyoo;Jung, Jae-Hoon;Cho, Hyung-Sig;Han, Soo-Hee
    • Korean Journal of Remote Sensing
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    • v.27 no.1
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    • pp.43-49
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    • 2011
  • In the face of growing concern about global warming, increasing attention has been focused on the reduction of carbon dioxide emissions. One method to mitigating the release of carbon dioxide is Carbon Capture and Storage (CCS). CCS includes separation of carbon dioxide from industrial emission in plants, transport to a storage site, and long-term isolation in underground. It is necessary to conduct analyses on optimal site selection, surface monitoring, and additional effects by the construction of CCS facility in Gyeongsang basin, Korea. For the optimal site selection, necessary data; geological map, landcover map, digital elevation model, and slope map, were prepared, and a weighted overlay analysis was performed. Then, surface monitoring was performed using high resolution satellite image. As a result, the candidate region was selected inside Gyeongnam for carbon storage. Finally, the related regulations about CCS facility were collected and analyzed for legal question of selected site.

Utilizing the Revised Universal Soil Loss Equation (RUSLE) Technique Comparative Analysis of Soil Erosion Risk in the Geumhogang Riparian Area (범용토양유실공식(RUSLE) 기법을 활용한 금호강 수변지역의 토양유실위험도 비교 분석)

  • Kim, Jeong-Cheol;Yoon, Jung-Do;Park, Jeong-Soo;Choi, Jong-Yun;Yoon, Jong-Hak
    • Korean Journal of Remote Sensing
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    • v.34 no.2_1
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    • pp.179-190
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    • 2018
  • The purpose of this study is an analysis of the risk of soil erosion before and after the maintenance of riparian area using the Revised Universal Soil Loss Equation (RUSLE) model based on GIS and digitizing data. To analysis of soil erosion loss in the study area, land cover maps, topographical maps, soil maps, precipitation and other data were used. After digitizing the riparian area of the Geumhogang, the area is divided into administrative district units, respectively. Amount of soil loss was classified into 5 class according to the degree of loss. Totally, 1 and 5 class were decreased, and 2-4 class were increased. Daegu and Yeongcheon decreased the area of 5 class, and Gyeongsan did not have area of 5 class. The reason for this is thought to be the decrease of the 5 class area due to the park construction, expansion of artificial facilities, and reduction of agricultural land. Simplification of riverside for river dredging and park construction has increased the flow rate of the riverside and it is considered that the amount of soil erosion has increased.

Analysis on Temperature Distribution and Current-Carrying Capacity of GIL Filled with Fluoronitriles-CO2 Gas Mixture

  • Chen, Geng;Tu, Youping;Wang, Cong;Cheng, Yi;Jiang, Han;Zhou, Hongyang;Jin, Hua
    • Journal of Electrical Engineering and Technology
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    • v.13 no.6
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    • pp.2402-2411
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    • 2018
  • Fluoronitriles-$CO_2$ gas mixtures are promising alternatives to $SF_6$ in environmentally-friendly gas-insulated transmission lines (GILs). Insulating gas heat transfer characteristics are of major significance for the current-carrying capacity design and operational state monitoring of GILs. In this paper, a three-dimensional calculation model was established for a GIL using the thermal-fluid coupled finite element method. The calculated results showed close agreement with experimentally measured data. The temperature distribution of a GIL filled with the Fluoronitriles-$CO_2$ mixture was obtained and compared with those of GILs filled with $CO_2$ and $SF_6$. Furthermore, the effects of the mixture ratio of the component gases and the gas pressure on the temperature rise and current-carrying capacity of the GIL were analyzed. Results indicated that the heat transfer performance of the Fluoronitriles-$CO_2$ gas mixture was better than that of $CO_2$ but worse than that of $SF_6$. When compared with $SF_6$, use of the Fluoronitriles-$CO_2$ gas mixture caused a reduction in the GIL's current-carrying capacity. In addition, increasing the Fluoronitriles gas component ratio or increasing the pressure of the insulating gas mixture could improve the heat dissipation and current-carrying capacity of the GIL. These research results can be used to design environmentally-friendly GILs containing Fluoronitriles-$CO_2$ gas mixtures.