• Title/Summary/Keyword: Reducing $CO_2$

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Gas-sensing Characteristics of $WO_3$-$SnO_2$Thin-film Sensors ($WO_3$-$SnO_2$박막 센서의 가스감지특성)

  • 유광수;김태송
    • Journal of the Korean Ceramic Society
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    • v.38 no.12
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    • pp.1180-1186
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    • 2001
  • W $O_3$-Sn $O_2$thin film sensors with approximately 1${\mu}{\textrm}{m}$ in thickness were fabricated by using a high-vacuum resistance-heating evaporator, were annealed at 50$0^{\circ}C$ for 4 hours in air, and then their crystallinities and surface microstructures were analyzed. As results of gas-sensing characteristics to oxidizing gas, N $O_2$, and reducing gas, CO, of 100 ppm, the highest gas sensitivities (S= $R_{gas}$/ $R_{air}$) were the W $O_3$thin-film sensor measured at 25$0^{\circ}C$ for N $O_2$(S≒1000) and the Sn $O_2$thin-film sensor measured at 15$0^{\circ}C$ to 25$0^{\circ}C$ range for CO (S≒0.25), respectively.ely.

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Analysis of Variables Influencing the Pressure Build-up and Volume Expansion of Kimchi Package (김치포장의 압력 및 부피 변화에 영향을 미치는 인자의 분석)

  • 이동선;최홍식;박완수
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.2
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    • pp.429-437
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    • 1999
  • A mathematical model was established for estimating changes in pressure and volume of permeable kimchi packages. The model comprises the CO2 gas production from kimchi and permeation of O2, CO2 and N2 through the permeable film or sheet. Using the developed model, the effects of various packaging variables on the pressure and volume changes were analyzed for rigid and flexible packag es of kimchi(3% salt content) at 15oC, and then effect of storage temperature was also looked into. In case of rigid pack of 400g, using the plastic sheet of high CO2 permeability and initial vacuumizing can help to relieve the problem of pressure build up. The lower fill weight can further reduce the pressure, but will result in higher packaging cost. For the flexible package of 3 kg, highly permeable films such as low density polyethylene(LDPE) and polypropylene can reduce the volume expansion. Higher ratio of CO2 permeability to O2 and N2 permeabilities are effective in reducing the volume expansion. Increased surface area cannot contribute to reduction of volume expansion for highly permeable flexible packages of kimchi. For the impermeable packages, pressure and volume at over ripening stage (acidity 1.0%) increase with decreased temperature, while those at optimum ripening stage(acidity 0.6%) change little with temperature. Pressure of permeable rigid LDPE package increases with tem perature at any ripening stage, and temperature affects the volume of flexible LDPE package very slightly. Experimental verification of the present results and package design with economical consid eration are needed as a next step for practical application.

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Discovery of Porous Materials for H2/CO2 Gas Separation and High-Throughput Computational Screening (수소/이산화탄소 가스분리용 다공성 물질 탐색 및 고속전산스크리닝 연구동향)

  • Byung Chul Yeo
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.1-7
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    • 2023
  • Gas separation technology becomes more useful because key gases such as H2 and CO2 regarding renewable energy resources and environmental pollutant can be effectively extracted in mixed gases. For reducing energy consumption on gas separation, membrane and adsorption processes are widely used. In both processes, porous materials are needed as membrane and adsorbent. In particular, metal-organic frameworks (MOFs), one class of the porous materials, have been developed for the purpose of gas adsorption and separation. While the number of the MOF structures is increasing due to chemical and structural tunability, good MOF membranes and adsorbents have been rarely reported by trial-and-error experiments. To accelerate the discovery of high-performing porous materials that can separate H2 and CO2, a high-throughput computational screening technique was used as efficient skill. This review introduces crucial studies of porous materials and the high-throughput computational screening works focusing on gas separation of H2 and CO2.

CO2 sequestration and heavy metal stabilization by carbonation process in bottom ash samples from coal power plant

  • Ramakrishna., CH;Thriveni., T;Nam, Seong Young;kim, Chunsik;Ahn, Ji Whan
    • Journal of Energy Engineering
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    • v.26 no.4
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    • pp.74-83
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    • 2017
  • Coal-fired power plants supply roughly 50 percent of the nation's electricity but produce a disproportionate share of electric utility-related air pollution. Coal combustion technology can facilitate volume reduction of up to 90%, with the inorganic contaminants being captured in furnace bottom ash and fly ash residues. These disposal coal ash residues are however governed by the potential release of constituent contaminants into the environment. Accelerated carbonation process has been shown to have a potential for improving the chemical stability and leaching behavior of bottom ash residues. The aim of this work was to quantify the volume of $CO_2$ that could be sequestrated with a view to reducing greenhouse gas emissions and stabilize the contaminated heavy metals from bottom ash samples. In this study, we used PC boiler bottom ash, Kanvera reactor (KR) slag and calcined waste lime for measuring chemical analysis and heavy metals leaching tests were performed and also the formation of calcite resulting from accelerated carbonation process was investigated by thermo gravimetric and differential thermal analysis (TG/DTA).

Evaluating Vehicle Emission Reduction (CO, VOC and NOx) Using Real-time Traffic Information (실시간교통정보 이용에 따른 차량의 CO, VOC, NOx 저감효과 평가)

  • Kim, Jun-Hyung;Um, Jung-Sup
    • Journal of Environmental Impact Assessment
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    • v.20 no.2
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    • pp.217-226
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    • 2011
  • This paper was inspired by the fact that Real-time Traffic Information Service could play a key role in reducing incomplete combustion time remarkably since it can provide traffic jam information in real-time basis. Emission characteristics of experimental engines were studied with variable travel distances and speed of car in terms of traffic information provided. 12 Km distance road of Susung district in Daegu is taken as an experimental area to examine this new approach. The emission was tested while the driving was done at 8 AM, 3 PM, 6 PM which represents various traffic conditions. The reduced emission has been measured for a travel distance running at different loads (conventional shortest route and Real-time Traffic Information) and various loads (CO, VOC and NOx) are all inventoried and calculated in terms of existing emission factors. The emission has been shown to reduce linearly with travel distance : carbon monoxide (20.56%), VOC (29.21%), NOx(8.86%).

An Analysis on the Properties of Concrete Used as the Mixture Material with Carbon Black (카본블랙을 혼화재료로 사용한 콘크리트의 특성 분석)

  • Ryu, Hyun-Gi;Kwon, Yong-Ju
    • Journal of the Korea Institute of Building Construction
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    • v.10 no.2
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    • pp.59-66
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    • 2010
  • The purpose of this study is to determine the possibilities of blending carbon black, which is known for its permeability as well as its strong heat and fire resistance, into concrete, in a manner that reinforces its strengths mentioned above. Experiments show that in non-solidified, fresh-mixed concrete, the addition of carbon black effectively reduced slump level and air content due to its absorptiveness and minute particle size. It also showed good results in terms of coagulation time, penetration resistance and bleeding level. In solid concrete, it showed better strength than plain concrete. Due to the pozzolanic reaction, its strength became more pronounced over time. At approximately 850 degrees Celsius, the heat and fire resistance level increased in parallel to the level of chemical substitution (by carbon black). Drying shrinkage level appeared to be optimal, and environmental assessment test results related to CO, CO2 and formaldehyde also scored better than plain concrete. In summary, with the appropriate use of AE water-reducing agents, carbon black can prove to be a strong candidate as an ingredient for industry-grade concrete.

Reduction of pH of Recycled Fine Aggregate due to Natural and Artificial Treatment Method (자연 및 인위적 처리방법 변화에 따른 순환잔골재의 pH저감)

  • Han, Cheon-Goo;Han, Min-Cheol;Han, Sang-Yoon
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.1
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    • pp.103-110
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    • 2011
  • This study is to comparatively analyze the characteristics of pH decrease in recycled fine aggregates for embankment and landfill produced from waste concrete by using natural process and artificial process. The result was as follows In case of recycled fine aggregates left outdoor, it was found that pH level was decreased if the thickness of embankment becomes thinner, or the materials left outdoors owing to high concentration of $CO_2$ in atmosphere caused by respirations of people. When the air was permeated, pH level was decreased more effectively. It was analyzed that this phenomenon was caused by efficient supply of $CO_2$ in the recycled fine aggregates owing to high-pressure ventilators. In case of water spraying treatment, sprayed water facilitated hydration of unhydrated cement to dissolve calcium hydroxides which neutralized $CO_2$ in the atmosphere during desiccation process and decrease pH level by a considerable margin. In case of Immersed treatment, decrease of pH was not sufficient. When facilitating the supply of $CO_2$, pH level of the recycled fine aggregates was decreased by the largest margin. It was analyzed that this phenomenon was caused by efficient supply of $CO_2$. From the above results, it was analyzed that the most effective method of reducing pH level of the recycled fine aggregates from the aspects of pH reduction performance, economic efficiency and workability was repeated wet-dry cycles of spraying water to the aggregates in the proportion of 1:0.5 by weight and then treating by forcefully blowing $CO_2$ gas into the aggregates.

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Improvement Proposal for the Fire Suppression Systems of Open Parking Lots (개방형주차장의 소방설비 개선 제안)

  • Jeong, Keesin
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.1-8
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    • 2016
  • In cars, the amount of combustibles, such as plastics, textiles, etc., have increased dramatically to improve the fuel efficiency of cars by reducing the gross vehicle weight according to the increases in an oil price and to reduce environmental problems. One or two cars were involved in a parking lot fire prior to the mid-2000 s. On the other hand, there were many parking lot fires where the entire car was destroyed due to increasing the use of plastics. In this study, the quantity of combustibles in a car was 316.2 kg over a total weight 1935 kg. This is 16.34% of total weight and 10 times greater than that three decades earlier. When a sprinkler is installed as a parking lot fire protection system as a substitute for water spray, the water discharge of the sprinkler must maintain the original density of water spray, $20lpm/m^2$. In addition, the use of a hose reel $CO_2$ system at pilotis parking lots must be prohibited because the hose reel $CO_2$ system has no adaptability for a car fire. Instead, this study proposes foam, dry powder, loaded stream systems be used in parking lot fire suppression systems.

Magnetization Switching of MTJs with CoFeSiB/Ru/CoFeSiB Free Layers (CoFeSiB/Ru/CoFeSiB 자유층을 갖는 자기터널 접합의 스위칭 자기장)

  • Lee, S.Y.;Lee, S.W.;Rhee, J.R.
    • Journal of the Korean Magnetics Society
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    • v.17 no.3
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    • pp.124-127
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    • 2007
  • Magnetic tunnel junctions (MTJs), which consisted of amorphous CoFeSiB layers, were investigated. The CoFeSiB layers were used to substitute for the traditionally used CoFe and/or NiFe layers with an emphasis given on understanding the effect of the amorphous free layer on the switching characteristics of the MTJs. CoFeSiB has a lower saturation magnetization ($M_s\;:\;560\;emu/cm^3$) and a higher anisotropy constant ($K_u\;:\;2800\;erg/cm^3$) than CoFe and NiFe, respectively. An exchange coupling energy ($J_{ex}$) of $-0.003\;erg/cm^2$ was observed by inserting a 1.0 nm Ru layer in between CoFeSiB layers. In the Si/$SiO_2$/Ta 45/Ru 9.5/IrMn 10/CoFe 7/$AlO_x$/CoFeSiB 7 or CoFeSiB (t)/Ru 1.0/CoFeSiB (7-t)/Ru 60 (in nm) MTJs structure, it was found that the size dependence of the switching field originated in the lower $J_{ex}$ using the experimental and simulation results. The CoFeSiB synthetic antiferromagnet structures were proved to be beneficial for the switching characteristics such as reducing the coercivity ($H_c$) and increasing the sensitivity in micrometer size, even in submicrometer sized elements.

A Study on the Environment-Conscious Logistics considering Sales Volume (환경친화적 물류활동의 실태에 관한 연구 - 매출액 규모를 중심으로 -)

  • Park, Seong-Ha
    • Korean Business Review
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    • v.20 no.2
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    • pp.87-104
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    • 2007
  • With the effectuation of Kyoto Protocol, one of the important movement throughout the world is reducing the emission of greenhouse gas which is the main reason of making global warming. The actual factor of greenhouse gas is CO2, and in year of 2002 20% of total CO2 emission was produced only through transportation throughout the South Korea. In the contrary, the recycling of municipal wastes in South Korea was 44.0% in 2002, but it will be targeted upto 53.5% in 2011. This study applied survey research for the activities affecting to the emission of CO2 and packaging wastes produced from transportation and packaging stages in logistics area. For this, survey questionary was constructed with five specific areas - strategy, transportation & distribution, custody, packaging, and information. Based on the 144 returned survey questionaries, this study analyzed 54 categories and finally suggests necessary four alternative in Korea.

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