• 제목/요약/키워드: Reduce $CO_2$

검색결과 1,955건 처리시간 0.029초

Exploring Rational Design of Single-Atom Electrocatalysts for Efficient Electrochemical Reduction of CO2 to CO

  • Joonhee Ma;Jin Hyuk Cho;Kangwon Lee;Soo Young Kim
    • 한국재료학회지
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    • 제33권2호
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    • pp.29-46
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    • 2023
  • The electrochemical reduction of carbon dioxide (CO2) to value-added products is a remarkable approach for mitigating CO2 emissions caused by the excessive consumption of fossil fuels. However, achieving the electrocatalytic reduction of CO2 still faces some bottlenecks, including the large overpotential, undesirable selectivity, and slow electron transfer kinetics. Various electrocatalysts including metals, metals oxides, alloys, and single-atom catalysts have been widely researched to suppress HER performance, reduce overpotential and enhance the selectivity of CO2RR over the last few decades. Among them, single-atom catalysts (SACs) have attracted a great deal of interest because of their advantages over traditional electrocatalysts such as maximized atomic utilization, tunable coordination environments and unique electronic structures. Herein, we discuss the mechanisms involved in the electroreduction of CO2 to carbon monoxide (CO) and the fundamental concepts related to electrocatalysis. Then, we present an overview of recent advances in the design of high-performance noble and non-noble singleatom catalysts for the CO2 reduction reaction.

조적벽의 CO2 배출비용을 포함한 건설원가 비교에 관한 연구 (Comparison of Construction Costs of Masonry Wall Types, including CO2 Emission Costs)

  • 이병윤;김보라;김광희
    • 한국건축시공학회지
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    • 제10권3호
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    • pp.83-90
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    • 2010
  • 건설산업에서 발생하는 $CO_2$배출량은 지구 온난화를 유발하는 주요 원인 중 하나이다. 이에 따라 건설산업에서는 $CO_2$배출량을 줄이기 위해 노력하고 있다. 최근 건축물의 $CO_2$배출량에 관한 다양한 연구가 진행되고 있지만 $CO_2$배출비용에 관한 연구는 아직 없는 실정이다. 본 연구에서는 벽체별(시멘트벽돌벽, 블록벽돌벽, 점토벽돌벽)로 기존 공사비에 $CO_2$배출비용을 포함하여 비교해 보았다. 그 결과 $CO_2$배출비용은 점토벽돌벽, 시멘트벽돌벽, 블록벽 순으로 높았다. 본 연구는 $CO_2$배출량을 비용으로 환산하는 방법을 제시함으로써 향후 $CO_2$배출량을 비용측면으로 비교해 볼 수 있는 기초적 자료를 제공할 수 있을 것이다.

산소부화연소에서 Co2 첨가에 대한 연소 특성 (Characteristics for Effects of Co2 Addition to Oxygen-Enriched Combustion)

  • 김한석;김호근;안국영;김용모
    • 대한기계학회논문집B
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    • 제28권1호
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    • pp.9-15
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    • 2004
  • $CO_2$ is a well-known green house gas as well as the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. Among the method for reducing $CO_2$ emission, oxygen-enriched combustion has been proposed. Because its adiabatic flame temperature is relatively too high, existing facilities must be changed or the flame temperature in the combustion zone should be reduced. The combustion characteristics, composition in the flame zone, temperature profile and emission gases were investigated experimentally for the various oxygen-enriched ratios(OER) by the addition of $CO_2$, under constant $O_2$ flow rate. Results showed that the reaction zone was quenched and broadened as the addition of $CO_2$ was increased. The emission of NOx in flue gas was decreased as decreasing temperature in reaction zone. It was also shown that the reaction was delayed by the cooling effect. As the addition of $CO_2$ was increased, the composition of CO in the flame zone was increased due to the increase of reaction rate by increasing mixing effect of oxidant/fuel at OER=0%, but the composition of CO was decreased by quenching effect at OER=50% and 100%.

산소부화연소에서 $CO_2$ 첨가에 대한 영향 (Effects of $CO_2$ addition to Oxygen-Enriched Combustion)

  • 김호근;김한석;안국영;김용모
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 춘계학술대회
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    • pp.1389-1394
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    • 2003
  • $CO_2$ is a well-known green house gas, which is the major source of global warming. Many researchers have studied to reduce $CO_2$ emission in combustion processes. Among the method for reducing $CO_2$ emission, oxygen-enriched combustion has been proposed. But the adiabatic flame temperature is too high. So existing facilities must be changed, or the adiabatic flame temperature in the combustion zone should be reduced. The combustion characteristics, composition in the flame zone, temperature profile and emission gases were studied experimentally for the various oxygen-enriched mtios(OER) by addition of $CO_2$ under coustant $O_2$ flowrate. Results showed that the reaction zone was quenched, broadened, as addition of $CO_2$ was increased. Temperature has a large effect on the NOx emission. The emission of NOx in flue gas decreased due to the decreased temperature of reaction zone. It was also shown that the reaction was delayed by the cooling effect. As the addition of $CO_2$ was increased, the composition of CO in the flame zone increased due to the increase of reaction rate by increasing mixing effect of oxidant/fuel at OER=0, but the composition of CO decreased by quenching effect at OER=50 and 100%.

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에너지저장시스템의 서울메트로 2호선 적용 효과에 관한 연구 (A Study on Effect of Applying Energy Storage System on SeoulMetro Line 2)

  • 안천헌;이한민;김길동;이희성
    • 한국철도학회:학술대회논문집
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    • 한국철도학회 2009년도 춘계학술대회 논문집
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    • pp.966-971
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    • 2009
  • The recent environmental protection trend requires more strict energy saving, therefore every transportation system should reduce energy consumption to the minimum value. High-efficiency operation system, energy saving and CO2 emissions shall be addressed as important issue in railway system. These issues are the most essential factors of railway, compared to major public transportation system. Recently, saving energy in the electric railway system has been studied. For such new energy saving, the Energy storage system is considered for saving energy. Energy saving is possible by efficient use of regenerated energy. Regenerated energy is recycled amongst vehicles by mean of charge and discharge corresponding to powering and braking of electric vehicle operations. This energy saving contributes to cut CO2 to reduce greenhouse gas emissions. Recycling regenerated energy demonstrate significant effect on peak cut of consumption energy in railway substation. Absorption of excess energy avoids regeneration failure due to high traction voltage. This paper presents effects by applying the energy storage system to SeoulMetro Line 2.

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2상류이젝터를 이용하는 $CO_{2}$ 냉동사이클의 성능해석 (Performance analysis of $CO_{2}$ refrigeration cycle with two-phase ejector)

  • 이윤환
    • Journal of Advanced Marine Engineering and Technology
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    • 제29권8호
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    • pp.946-952
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    • 2005
  • The $CO_{2}$ refrigeration cycle is expected to reduce the compressor work and increase the COP by applying two-phase ejector as a device for the recovery of dissipated expansion energy. In this study, the performance of the cycle was simulated and effects of the ejector shapes on the performance of the $CO_{2}$ refrigeration cycle were investigated. The following results were obtained through the cycle simulation. The COP of the $CO_{2}$ refrigeration cycle with two-phase ejector flow which expansion is occured in the isentropic manner is increased by a maximum of 24 $\%$ than the basic cycle with expansion valve If the velocity nonequilibrium in the mixing process is assumed the COP of the cycle is increased with the increase of the length and the decrease of the section area of the mixing tube. The best cycle performance is obtained when the divergent angle of diffuser is 7.

인터넷 부동산거래정보 발달에 따른 탄소저감효과 분석 (Study on the Analysis of the CO2 Emissions Reduction Effect through the Development of Internet Real Estate Information in Seoul)

  • 임미화
    • 한국IT서비스학회지
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    • 제12권2호
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    • pp.73-84
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    • 2013
  • The development of the information on the internet brought a lot of changes in the real estate market. Because the real estate has local distinctiveness and individuality household who want to move must to visit place for housing information. But now household use internet real estate information at every decision-moving step and that is able to reduce not only the cost of real estate information but also social benefit like $CO_2$ emissions reduction effect. In this study, I analyzed the effect of $CO_2$ emissions reduction with Seoul household residential mobility data when household take informations from internet real estate site. As increasing a single family who is good at internet service, the effect of $CO_2$ reduction from the development of the Internet real estate information has more increased.

중국 화력발전산업의 CO2 암묵가격 및 잠재감축량, 연료에 대한 대체가능성 분석 (Estimation of the Shadow Price of Carbon Dioxide Emissions, the Potential Reduction, and Substitution Possibility for fuels in the Chinese Fossil-fueled Power Generation Sector)

  • 김영미;이명헌
    • 자원ㆍ환경경제연구
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    • 제22권1호
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    • pp.77-98
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    • 2013
  • 본 논문에서는 향후 포스트 교토협약에서 온실가스 감축의무국으로 분류될 가능성이 높은 세계 최대의 $CO_2$ 배출국 중국의 화력발전산업을 대상으로 Shephard 투입물거리함수를 추정하여 $CO_2$ 암묵가격과 기술효율성, 그리고 투입요소 간 간접 모리시마 대체탄력성을 측정한다. 1981-2009년 기간 동안 $CO_2$ 1톤을 감축하는 데 연간 평균 약 3.2달러의 비용이 드는 것으로 나타났다. 이는 한국, 일본의 발전 산업에 대한 $CO_2$ 암묵가격 추정치보다 낮은 수준으로서 향후 이들 나라와 배출권 거래가 이루어질 경우 배출권 판매를 통한 경제적 이득이 예상된다. 기술효율성의 향상으로 달성할 수 있는 최대 $CO_2$ 잠재 감축량은 연간 평균 약 2천 5백만톤에 이르는 것으로 산정되었다. 석탄과 석유 등의 연료와 자본은 상호 대체가능하며 자본이 연료를 더 용이하게 대체하는 것으로 나타났다.

수치해석기법에 의한 어구 저항 분석 및 저탄소 트롤어구 설계와 비용 분석 (Low-Carbon trawl design with analysis of a gear drags and calculation of construction costs using numerical methods)

  • 이지훈;이춘우
    • 수산해양기술연구
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    • 제46권4호
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    • pp.313-323
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    • 2010
  • Fuel consumption in fisheries is a primary concern due to environmental effects and costs to fishermen. Much research has been carried out to reduce the fuel consumption related to fishing operations. The fuel consumption of fishing gear during fishing operation is generally related to hydrodynamic resistance on the gear. This research demonstrates a new approach using numerical methods to reduce fuel consumption. By designing the fishing gear using drawing software, the whole and partial resistance force on the gear can be calculated as a result of simulations. The simulation results will suggest suitable materials or gear structure for reducing the hydrodynamic forces on the gear while maintaining the performance of the gear. This research will helpful to reduce the $CO_2$ emissions from fishing operations and lead to reduce fishing costs due to fuel savings.

Design and Exergy Analysis for a Combined Cycle of Liquid/Solid $CO_2$ Production and Gas Turbine using LNG Cold/Hot Energy

  • Lee, Geun-Sik
    • International Journal of Air-Conditioning and Refrigeration
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    • 제15권1호
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    • pp.34-45
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    • 2007
  • In order to reduce the compression power and to use the overall energy contained in LNG effectively, a combined cycle is devised and simulated. The combined cycle is composed of two cycles; one is an open cycle of liquid/solid carbon dioxide production cycle utilizing LNG cold energy in $CO_2$ condenser and the other is a closed cycle gas turbine which supplies power to the $CO_2$ cycle, utilizes LNG cold energy for lowering the compressor inlet temperature, and uses the heating value of LNG at the burner. The power consumed for the $CO_2$ cycle is investigated in terms of a solid $CO_2$ production ratio. The present study shows that much reduction in both $CO_2$ compression power (only 35% of the power used in conventional dry ice production cycle) and $CO_2$ condenser pressure could be achieved by utilizing LNG cold energy and that high cycle efficiency (55.3% at maximum power condition) in the gas turbine could be accomplished with the adoption of compressor inlet cooling and regenerator. Exergy analysis shows that irreversibility in the combined cycle increases linearly as a solid $CO_2$ production ratio increases and most of the irreversibility occurs in the condenser and the heat exchanger for compressor inlet cooling. Hence, incoming LNG cold energy to the above components should be used more effectively.