• Title/Summary/Keyword: Red Shift

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Polymer Phosphorescence Device using a New Green Emitting Ir(III) Complex

  • Lee, Chang-Lyoul;Das, Rupasree Ragini;Noh, Yong-Young;Kim, Jang-Joo
    • Journal of Information Display
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    • v.3 no.1
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    • pp.6-10
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    • 2002
  • We have synthesized a new green Ir(III) complex fac-tris-(3-methyl-2-phenyl pyridine)iridium(III) $Ir(mpp)_3$ and fabricated phosphorescent polymer light-emitting device using it as a triplet emissive dopant in PVK. $Ir(mpp)_3$ showed absorption centered at 388 nm corresponding to the $^1MLCT$ transition as .evidenced by its extinction coefficient of the order of $10^3{\cdot}$ From the PL and EL spectra of the $Ir(mpp)_3$ doped PVK film, the emission maximum was observed at 523 nm, due to the radiative decay from the $^3MLCT$ state to the ground state, confirming a complete energy transfer from PVK to $Ir(mpp)_3$. The methyl substitution has probably caused a red shift in the absorption and emission spectrum compared to $Ir(mpp)_3$. The device consisting of a 2 % doped PVK furnished 4.5 % external quantum efficiency at 72 $cd/m^2$ (current density of 0.45 $mA/cm^2$ and drive voltage of 13.9 V) and a peak luminance of 25,000 $cd/m^2$ at 23.4 V (494 $mA/cm^2$). This work demonstrates the impact of the presence of a methyl substituent at the 3-position of the pyridyl ring of 2-phenylpyridine on the photophysical and electroluminescence properties.

Characteristics of Atomic Layer-Controlled ZnO:Al Films by Atomic Layer Deposition (원자층 증착법을 이용한 ZnO:Al 박막의 특성)

  • Oh, Byeong-Yun;Baek, Seong-Ho;Kim, Jae-Hyun;Lee, Hee-Jun;Kang, Young-Gu;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.40-40
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    • 2010
  • Structural, electrical, and optical properties of atomic layer-controlled AI-doped ZnO (ZnO:Al) films grown on glass by atomic layer deposition (ALD) were characterized with various $Al_2O_3$ film contents for use as transparent electrodes. Unlike films made using sputtering methods, the diffraction peak position of the films grown by ALD based on alternate self-limiting surface chemical reactions moved progressively to a wider angle (red shift) with increasing $Al_2O_3$ film content, which seems to be evidence of Zn substitution in the film by layer-by-layer growth. By adjusting the $Al_2O_3$ film content, the electrical resistivity of ZnO:Al film with the $Al_2O_3$ film content of 2.96% reached the lowest electrical resistivity of $9.80{\times}10^{-4}\Omega{\cdot}cm$, in which the carrier mobility, carrier concentration, and optical transmittance were $11.20\;cm^2V^{-1}s^{-1}$, $5.69{\times}10^{20}\;cm^{-3}$, and 94.23%, respectively. Moreover, the estimated figure of merit value for the transparent conductive oxide applications from our best sample was $7.7\;m{\Omega}^{-1}$.

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Fast Dimming Associated with a Coronal Jet Seen in Multi-Wavelength and Stereoscopic Observations

  • Lee, K.S.;Innes, D.E.;Moon, Y.J.;Shibata, K.;Lee, Jin-Yi
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.89.1-89.1
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    • 2012
  • We have investigated a coronal jet observed near the limb on 2010 June 27 by the Hinode/X-Ray Telescope (XRT), EUV Imaging Spectrograph (EIS), and Solar Optical Telescope (SOT), and the SDO/Atmospheric Imaging Assembly (AIA), Helioseismic and Magnetic Imager (HMI), and on the disk by STEREO-A/EUVI. From EUV (AIA and EIS) and soft X-ray (XRT) images we have identified both cool and hot jets. There was a small loop eruption in Ca II images of the SOT before the jet eruption. Using high temporal and multi wavelength AIA images, we found that the hot jet preceded its associated cool jet by about 2 minutes. The cool jet showed helical-like structures during the rising period. According to the spectroscopic analysis, the jet's emission changed from blue to red shift with time, implying helical motions in the jet. The STEREO observation, which enabled us to observe the jet projected against the disk, showed that there was a dim loop associated with the jet. We have measured a propagation speed of ~800 km/s for the dimming front. This is comparable to the Alfven speed in the loop computed from a magnetic field extrapolation of the HMI photospheric field measured 5 days earlier and the loop densities obtained from EIS Fe XIV line ratios. We interpret the dimming as indicating the presence of Alfvenic waves initiated by reconnection in the upper chromosphere.

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Effects of 8 weeks administration of Korean Panax ginseng extract on the mood and cognitive performance of healthy individuals

  • L., Reay J.;B., Scholey A.;O., Kennedy D.
    • Journal of Ginseng Research
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    • v.31 no.1
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    • pp.34-43
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    • 2007
  • Background: Previous research has suggested that single doses of a standardised Panax ginseng extract can decrease fasted blood-glucose levels and modulate cognitive performance in healthy young volunteers. The latter has generally been seen in terms of improved secondary memory performance. However, both the cognitive effects of chronic administration of ginseng and the potential modulation of working memory have received comparatively little research attention. Aims: The current double-blind, placebo-controlled, balanced cross-over study investigated the effects of 8-weeks administration of Korean ginseng extract (200 mg) on cognitive performance, gluco-regulatory parameters and ratings of subjective mood and 'quality of life'. Methods: 'Eighteen healthy young participants were assessed pre-dose and 3 hours post-dose on the mornings of Day 1, Day 29 and Day 57 of 8 week treatment regimens of both placebo and ginseng. A four-week placebo wash-out separated the treatment phases. Each assessment included the Cognitive Drug Research battery, computerised working memory tasks, and Bond-Lader mood scales. The WHO Quality of Life scale (WHOQOL-BREF) was completed once per visit. Gluco-regulatory parameters were assessed with assays of blood glucose, insulin and HbA1c. Results: Data from the 16 participants that completed the study showed that there were no significant, acute treatment related differences on Day 1 of treatment, or in gluco-regulatory parameters throughout the study. However, time related performance improvements were evident following chronic administration of ginseng on the '3-Back' and 'Corsi-block' computerised working memory tasks. Ginseng was also associated with an improved score on the 'social relations' subscale of the WHOQOL-100, and a significant shift on the 'calm' factor of the Bond-Lader mood scales (from calm/relaxed towards excited/tense). Conclusion: The results of the current study suggest that Korean ginseng extract can modulate working memory performance and subjective ratings of 'quality of life' and mood. Replication with a larger sample size may further elucidate the actions of this product.

Sonophotocatalytic Performance of Bi2Se3-Graphene/TiO2 Hybrid Nanomaterials Synthesized with a Microwave-assisted Method

  • Zhu, Lei;Jo, Sun-Bok;Ye, Shu;Ullah, Kefayat;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.51 no.3
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    • pp.162-169
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    • 2014
  • This paper introduces a microwave-assisted synthesis method to prepare hybrid $Bi_2Se_3-GR/TiO_2$ nanocomposites, which exhibit superior properties over single component materials. The as-prepared composites were characterized by XRD, UV-vis absorbance spectra, SEM,TEM, EDX, and BET analyses, revealing uniform covering of the graphene nanosheet with $Bi_2Se_3$ and $TiO_2$ nanocrystals. For visible light photocatalysis of Rh.B, a significant enhancement in the reaction rate was consequently observed with $Bi_2Se_3-GR/TiO_2$ composites. The degradation rate($k_{app}$) obtained for sonophotocatalysis was $6.8{\times}10^{-3}min^{-1}$, roughly 2.2 times better than that of VL photocatalysis under higher concentrations of Rh.B. The sonophotocatalysis was faster due to greater formation of reactive radicals as well as an increase of the active surface area of the $Bi_2Se_3-GR/TiO_2$ composites. The high activity is attributed to the synergetic effects of high charge mobility and red shift of the absorption edge of $Bi_2Se_3-GR/TiO_2$.

Growth Response of the Yellow Perch, Perca flavescens Mitchill, to Different Levels of Protein in Formulated Diets (사료의 단백질 함량이 옐로우$\cdot$퍼치의 성장에 미치는 영향)

  • Huh Hyung Tack
    • Journal of Aquaculture
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    • v.3 no.1
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    • pp.39-48
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    • 1990
  • The growth response of the yellow perch, a highly proteinaceous food feeder in nature, to different protein levels (50, 40 and $27\%$) in formulated diets was determined over a 20-week period. Approximately $23\%$ of dietary protein could be spared by substituting less expensive carbohydrate and lipid materials without any noticeable ill-effects or reduction in weight gains. In turn, there was no statistically significant difference between total weight gains of fish fed at three different levels of protein diets, although fish on the 50 and $40\%$ protein diets grew better in the first few weeks. A shift in the protein requirements occur-red after about 10 weeks of rearing. Growth efficiencies(growth/food intake) became nearly the same at all levels of protein and decreased consistently throughout the remainder of the study period. The results indicate that young yellow perch(6g initial weight) can grow normally with the $27\%$ protein diet after about 10 weeks of initial feeding with higher protein diets(or regular commercial diets).

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Health Disparities among Korean Workers by Enterprise Size: Using Korean Labor and Income Panel Study (17th) (사업체 규모에 따른 근로자 건강수준의 불평등: 제17차 한국노동패널 자료 이용)

  • Park, Bohyun;Choi, Sook Ja;Seo, Sukyong
    • Korean Journal of Occupational Health Nursing
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    • v.25 no.4
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    • pp.277-289
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    • 2016
  • Purpose: This study aims to investigate the cross-sectional association of company size and self-rated health using representative data on Korean workers. Methods: We used the data from 2,884 wage workers collected by Korean Labor and Income Panel Study (17th). The association between company size and self-rated health was analyzed using logistic regression with covariates including demographic characteristics, work environment, job satisfaction, and health-related behaviors. Resulst: Odds ratio (OR) for better health status among workers in large-sized company was 1.351 (CI. 1.054~1.731), compared to workers in small-sized company. We performed three separate models stratified by firm size (small, medium, and large companies). Occupation variables showed different effect on health depending on firm sizes. OR for better health of white-color job (referred to blue-color job) was 1.693 in medium-sized company model but it was 0.615 in large company model. OR for better health of the workers working shift work showed 0.606 in large company model but it was not significant in small and medium company models. Conclusion: We found that small-sized company workers have significantly poor self-rated health compared to large-sized firm workers. This study revealed that there exist differences among health related factors depending on firm sizes.

Characteristics of InGaN/GaN Quantum Well Structure Grown by MBE

  • 윤갑수;김채옥;박승호;원상현;정관수;엄기석
    • Proceedings of the Korean Vacuum Society Conference
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    • 1998.02a
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    • pp.110-110
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    • 1998
  • GaN는 직접천이형 에너지 캡을 가지며 In과 화합물을 형성할 경우 1.geV-3.4eV까지 다양한 에너지 캡을 가지므로 청색 발광소자 고출력소자 고온 전자소자둥 웅용성이 많 은 물절로서 각광을 받고 있다. 그러나 G랴‘에 적합한 기판이 없다는 문제점으로 인하여 F FET, LD와 같은 다양한 구조의 웅용에 제 약이 따랐다. 이에 본 연구에서는 RF(radio frequency) Plasma-Assisted MBE( molecular beam e epitaxy )를 이용하여 InxGaj xN/G암J 양자우물 구조를 성장하였다. 이렇게 성장된 I InxGaj xN 박막과 InxGaj xN/GaN 양자우물구조의 특성의 분석은 광학적 특성올 PL( p photoluminescence ) , 결 정 성 의 분석 은 XRD ( x-ray diffraction ), 표면 과 단변 의 계 변 특성은 SEM(scanning electron microscopy)을 이용하여 분석하였다. 저온 PL의 측정결 과 기판온도를 680$^{\circ}$C로 고정한 후 In cell의 온도를 650$^{\circ}$C에서 775$^{\circ}$C까지 증가함에 따라 I InxGaj xN에 관계된 피크위치가 약3이neV정도 red shift 함을 관찰할 수 있었다. 한편 I InxGaj xN/GaN 양자우물구조의 경우 PL피크가 3.2없eV로써 InxGaj- xN의 PL 피크에 비 해 에서 약 25me V 고에너지 이동이 관측되었으며 이것은 우불 내에서 에너지레벨의 c confinement효과에 의해 에너지의 변화에 의한 것엄올 확인하였으며, 양자우물 구조에서 우물의 두께를 줄임에 따라 변화 폭은 1이neV정도 고에너지 이동을 관찰할 수 있었다. X XRD 측정의 결과 In의 mole fraction에 따라 격자상수의 변화를 관찰하였으며, 결정 성의 변화를 피크의 세기로 관찰하였다 .. XRD로 판단한 In의 mole fraction은 0.2임을 알 았다 .. SEM 측정은 표변과 단면의 측정으로서 표연특성과 단면의 특성을 InxGaj xN, I InxGaj xN/GaN 양자우물 구조 모두 알아보았다. 측정 결과 InxGaj-xN의 성 장조건으로 기판온도가 낮아지면서 표면의 거칠기 정도가 증가하였으며,680$^{\circ}$C의 기판온도에서 성장 한 양자우물 구조에 있어서 매끄라운 표면올 얻올 수 있었다.

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Energy-band model on photoresponse transitions in biased asymmetric dot-in-double-quantum-well infrared detector

  • Sin, Hyeon-Uk;Choe, Jeong-U;Kim, Jun-O;Lee, Sang-Jun;No, Sam-Gyu;Lee, Gyu-Seok;Krishna, S.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.234-234
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    • 2010
  • The PR transitions in asymmetric dot-in-double-quantum-well (DdWELL) photodetector is identified by bias-dependent spectral behaviors. Discrete n-i-n infrared photodetectors were fabricated on a 30-period asymmetric InAs-QD/[InGaAs/GaAs]/AlGaAs DdWELL wafer that was prepared by MBE technique. A 2.0-monolayer (ML) InAs QD ensemble was embedded in upper combined well of InGaAs/GaAs and each stack is separated by a 50-nm AlGaAs barrier. Each pixel has circular aperture of 300 um in diameter, and the mesa cell ($410{\times}410\;{\mu}m^2$) was defined by shallow etching. PR measurements were performed in the spectral range of $3{\sim}13\;{\mu}m$ (~ 100-400 meV) by using a Fourier-transform infrared (FTIR) spectrometer and a low-noise preamplifier. The asymmetric photodetector exhibits unique transition behaviors that near-/far-infrared (NIR/FIR) photoresponse (PR) bands are blue/red shifted by the electric field, contrasted to mid-infrared (MIR) with no dependence. In addition, the MIR-FIR dual-band spectra change into single-band feature by the polarity. A four-level energy band model is proposed for the transition scheme, and the field dependence of FIR bands numerically calculated by a simplified DdWELL structure is in good agreement with that of the PR spectra. The wavelength shift by the field strength and the spectral change by the polarity are discussed on the basis of four-level transition.

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Fabrication of ZnS Powder by Glycothermal Method and Its Photocatalytic Properties (Glycothermal법에 의한 ZnS 분말 합성 및 광촉매 특성)

  • Park, Sang-Jun;Lim, Dae-Young;Song, Jeong-Hwan
    • Korean Journal of Materials Research
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    • v.27 no.9
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    • pp.489-494
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    • 2017
  • ZnS powder was synthesized using a relatively facile and convenient glycothermal method at various reaction temperatures. ZnS was successfully synthesized at temperatures as low as $125^{\circ}C$ using zinc acetate and thiourea as raw materials, and diethylene glycol as the solvent. No mineralizers or precipitation processes were used in the fabrication, which suggests that the spherical ZnS powders were directly prepared in the glycothermal method. The phase composition, morphology, and optical properties of the prepared ZnS powders were characterized using XRD, FE-SEM, and UV-vis measurements. The prepared ZnS powders had a zinc blende structure and showed average primary particles with diameters of approximately 20~30 nm, calculated from the XRD peak width. All of the powders consisted of aggregated secondary powders with spherical morphology and a size of approximately $0.1{\sim}0.5{\mu}m$; these powders contained many small primary nanopowders. The as-prepared ZnS exhibited strong photo absorption in the UV region, and a red-shift in the optical absorption spectra due to the improvement in powder size and crystallinity with increasing reaction temperature. The effects of the reaction temperature on the photocatalytic properties of the ZnS powders were investigated. The photocatalytic properties of the as-synthesized ZnS powders were evaluated according to the removal degree of methyl orange (MO) under UV irradiation (${\lambda}=365nm$). It was found that the ZnS powder prepared at above $175^{\circ}C$ exhibited the highest photocatalytic degradation, with nearly 95 % of MO decomposed through the mediation of photo-generated hydroxyl radicals after irradiation for 60 min. These results suggest that the ZnS powders could potentially be applicable as photocatalysts for the efficient degradation of organic pollutants.