• Clean Technology
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• v.30 no.1
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• pp.37-46
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• 2024

Environmental problems caused by plastic waste have been continuously growing around the world, and plastic waste is increasing even faster after COVID-19. In particular, PP and PE account for more than half of all plastic production, and the amount of waste from these two materials is at a serious level. As a result, researchers are searching for an alternative method to plastic recycling, and plastic pyrolysis is one such alternative. In this paper, a numerical study was conducted on the pyrolysis behavior of non-condensable gas to predict the chemical reaction behavior of the pyrolysis gas. Based on gas products estimated from preceding literature, the behavior of non-condensable gas was analyzed according to temperature and residence time. Numerical analysis showed that as the temperature and residence time increased, the production of H₂ and heavy hydrocarbons increased through the conversion of the non-condensable gas, and at the same time, the CH₄ and C₆H₆ species decreased by participating in the reaction. In addition, analysis of the production rate showed that the decomposition reaction of C₂H₄ was the dominant reaction for H₂ generation. Also, it was found that more H₂ was produced by PE with higher C₂H₄ contents. As a future work, an experiment is needed to confirm how to increase the conversion rate of H₂ and carbon in plastics through the various operating conditions derived from this study's numerical analysis results.

• Proceedings of the Korea Concrete Institute Conference
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• 2005.05a
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• pp.483-486
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• 2005

The polymer concrete is drawing a strong interest as high-performance materials in the construction industry. Resins using recycled PET offer the possibility of a lower source cost of materials for making useful polymer concrete products. Also the recycling of PET in polymer concrete would help solve some of the solid waste problems posed by plastics and save energy. Polymer concrete beams using unsaturated polyester resins based on recycled polyethylene terephthalate (PET) plastic waste were used in our study for grasping its structural behavior of static and fatigue. As a result of static test, Compression stress distribution of Polymer concrete indicates linear behavior such as triangles. Although polymer concrete is high strength materials, its ductility capacity is excellent. From the fatigue test results, There was almost no difference on flexural characteristics between before and after fatigue loading. Therefore, recycled PET polymer concrete remains excellent structural ability after fatigue loading.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.3
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• pp.295-302
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• 2021

Surface modification of recycled plastic film-based aggregates is demonstrated to enhance the interaction between aggregates and cement paste. It is shown that the oxygen(O₂) atmospheric pressure plasma(APP) treatment leads to a drastic increase in hydrophilicity. In case of the plasma treatment at 100W of RF power, 15/4sccm of O₂/Ar flow rate and 30sec of discharging time, the water contact angle on the aggregates surface decreased from 104.5° to 44.0°. In addition, the contact angle of surface modified aggregates kept in air increased with time elapse. Improvement of hydrophilicity can be explained by the formation of new hydrophilic oxygen functional groups which is identified as C-OH, C-O-C, C=O, -COOH by X-ray photoelectron spectroscopy(XPS) analysis and Fourier-transform infrared spectroscopy(FT-IR). Therefore, it can be concluded that the plasma treatment process is an effective method to improve adhesion of the recycled plastic film-based aggregates and cement paste.

• Design Convergence Study
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• v.14 no.4
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• pp.119-132
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• 2015

The enforcement of volume-rate disposal system which has been resulted in reducing the household waste and increasing the amount of recycled contents is showing positive effects that are generating social and economic benefits, However due to the lack of user's perception about how to separate and dispose of recycling wastes, some problems are constantly raised, like food waste is disposed in the standard volume-rate garbage bag. By rearranging visual information printed on standard plastic garbage bags (SPGB), this study attempted to find ways to deliver the information regarding how to use them properly. In order to achieve this, from the perspective of visual information design, the study examined the cases of visual information printed on nine SPGB from domestic and overseas. Among these, this study conducted a survey on user's awareness of visual information printed on SPGB in three districts of Seoul, Korea. As a result, user-preferred items were identified. Based on the result, this study selected information to be printed on SPGB, established the hierarchical order of the selected information, and proposed a guideline for using SPGB with informative graphics; therefore, the effectiveness of information delivery was improved. In addition, this study also examined the external validity of the guideline by comparing a survey on user's awareness.

• Journal of the Korean Society for Marine Environment & Energy
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• v.11 no.1
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• pp.42-45
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• 2008

It has been reported that FRP (fiber reinforced plastic) can be recycled by separating into layers instead of crushing into powder. F-fiber obtained from roving layer separated from FRP, has bigger tensile strength than the bundle of glass fibers of which FRP was made (more than 90%). SEM image of F-fiber shows the presence of some resin. Under the proposition of usage of F-fiber in the concrete material, tensile strength is examined after soaking in a basic solution (NaOH+KOH). The reaction mechanism of strength loss may be considered as an attack of hydroxide ion ($OH^-$) on a chemical bond of Si-O-Si of glass fiber. The simulation graph of the strength loss data implies certain reaction mechanism. While in the early stage kinetically controlled reaction results in a fast drop of tensile strength, after 30 days dispersion rate of hydroxide ion plays a major role in strength loss. This result is similar to the one for the AR glass. An extrapolation of the graph would make an assumption about the lift time of F-fiber possible.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.1
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• pp.175-180
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• 2016

Waste bumpers from out-of-service vehicles are recycled in the manufacturing process of plastic parts by incorporating pristine materials after removing the coated paint on a bumper. This study examined the chemical properties and mechanical properties of a mixture of recycled bumper and pristine materials as a function of the mixing ratio. When the pristine materials and the recycled bumper pieces were mixed, the stiffness (tensile strength and the flexural modulus) was provided by their composition averages. On the other hand, the toughness (Izod impact strength and the elongation-at-break) was lower than their composition averages (i.e., negative deviation). FTIR analysis showed that these results were due to the absence of the compatibility between the pristine materials and recycled bumper pieces. When the recycled bumper pieces were loaded at more than 30 wt. %, the toughness decreased drastically. A previous study showed that a paint removal efficiency up to 80 wt.% was easily attainable. The other 20 wt.% of paint on the bumper is very difficult to remove. Therefore, this study examined the mechanical properties of a mixture of recycled bumper pieces containing the unremoved paint and recycled bumper pieces without paint. When the recycled bumper pieces containing the unremoved paint were incorporated in only small quantities, the mechanical properties were decreased to a great extent. These results show that the paint removal efficiency is very important in the recycled bumper industry.

• Journal of the Korea Concrete Institute
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• v.17 no.1 s.85
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• pp.19-25
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• 2005

Recycling of waste materials in the construction Industry is a useful method that can cope with an environment restriction of every country. In this study, synthetic lightweight aggregates are manufactured with recycled plastic and fly ash with 12 percent carbon. Nominal maximum-size aggregates of 9.5 mm were produced with fly ash contents of 0, 35, and $80\%$ by the total mass of the aggregate. An expanded clay lightweight aggregate and a normal-weight aggregate were used as comparison. Gradation, density, and absorption capacity are reported for the aggregates. Five batches of concrete were made with the different coarse aggregate types. Mechanical properties of the concrete were determined including density, compressive strength, elastic modulus, splitting tensile strength, fracture toughness, and fracture energy. Salt-scaling resistance, a concrete durability property, was also examined. Compressive and tensile strengths were lower for the synthetic aggregates; however, comparable fracture properties were obtained. Relatively low compressive modulus of elasticity was found for concretes with the synthetic lightweight aggregate, although high ductility was also obtained. As nv ash content of the synthetic lightweight aggregate increased, all properties of the concrete were improved. Excellent salt-scaling resistance was obtained with the synthetic lightweight aggregate containing 80 percent fly ash.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.29 no.3
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• pp.153-161
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• 2023

The worldwide effects of COVID-19 have led to a surge in online shopping and contactless services. The consumption pattern has caused the issues such as the environmental pollution together with the increase of plastic waste. Reducing the reliance on the petroleum based plastic use for the package and replacing it with environmentally friendly material are the simple ways in order to solve those problems. Paper is an eco-friendly product with high recyclability as the food packaging materials but has still poor barrier properties. A barrier coating on surface of the paper can be achieved with the proper packaging materials featuring water, gas and grease barrier. Polyethylene (PE) or polypropylene (PP) coatings which are generally laminated or coated to paper are widely used in food packaging applications to protect products from moisture and provide water or grease resistance. However, recycling of packaging containing PE or PP matrix is limited and costly because those films are difficult to degrade in the environment. This study investigated the recyclability of modified acrylic emulsion coating papers compared to PE and PP polymer matrixes as well as their mechanical and gas barrier properties. The results showed that PE or modified acrylic emulsion coated papers had better mechanical properties compared to the uncoated paper as a control. PE or PP coating papers showed strong oil resistance property, achieving a kit rating of 12. Those papers also had a significantly higher percentage of screen reject during the recycling process than modified acrylic coated paper which had a screen rejection rate of 6.25%. In addition an uncoated paper had similar value of a screen rejection rate. It may suggest that modified acrylic emulsion coating paper can be more easily recycled than PE or PP coating papers. The overall results of the study found that modified acrylic emulsion coating paper would be a viable alternative to suggest a possible solution to an environmental problem as well as enhancing the weak mechanical and poor gas barrier properties of the paper against moisture.