• Resources Recycling
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• v.10 no.2
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• pp.13-19
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• 2001

Several hydrolyzed extruded PAN's were prepared through reaction of extruded PAN (7.5% methyl acrylate) with NaOH in methanol at various temperatures and times. These were amidoximated with hydroxylamine in MeOH and/or $H_2$O to introduce an excellent adsorption capacity of heavy metal ions. Amidoximated hydrolyzed extruded fAN showed superior swellability to non-hydrolyzed extruded PAM. The amidoximated extruded PAN hydrolyzed for 6h at $60^{\circ}C$ showed the best dimensional stability. Amidoximated hydrolyzed extruded PAN has more adsorption capacity of $Cu^{2+}$ than that of $Ni^{ 2+}$ These PAN derivates also showed an excellent selectivity for adsorption of metal ions.

• Resources Recycling
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• v.27 no.5
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• pp.49-53
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• 2018

In developing an optimum steelmaking process, the purity of the product, environmental impact, capability and cost of the process should be considered. Desulfurization of molten iron is conducted during preliminary treatment stage before converter operation. Although fluorite is added as a desulfurizing agent in CaO and $CaCO_3$ based agents, the concentration of fluorine in slag is strictly regulated. In order to develop desulfurizing agent without fluorine, CaO was mixed with Al dross and ladle slag containing alumina. The characteristics and desulfurizing capacity of the CaO based desulfurizing agent thus prepared were tested by varying temperature of Kanvara Reactor. Our results showed that the desulfurizing capacity of the samples prepared in this work was found to be similar to that of the traditional desulfurizing agents with fluorine.

• Journal of Biosystems Engineering
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• v.9 no.2
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• pp.65-73
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• 1984

While most of researches on the performance of high temperature grain dryer have dealt mainly with improving dryer capacity and drying speed during the last twenty years, energy efficiency, in fact, has not been emphasized. Current fuel supplies and energy cost have shifted the emphasis to reducing the energy consumption for grain drying while maintaining dryer capacity and grain quality. Since the energy input for drying is relatively large, the recovery and reuse of at least part of the exhaust energy can significantly reduce the total energy consumption in existing drying systems. Unilization of exhaust heat in grain dryer either through direct recycling or by a thermal coupling in heat exchanger have been subject of a number of investigators. However, very seldom research in Korea has been done in this area. Three drying tests(non-recycling, 0.22 recycle ratio, and 0.76 recycle ratio)were performed to investigate the thermal efficiency and heat loss factors of continuous flow type dryer, and to analyze the effect of recycle ratio (weight of exhaust air recycled/total weight of input air) on the energy requriements for rough rice drying. The test results showed that when the exhaust air was not recycled, the energy lost from furnace was 15.3 percent of input fuel energy, and latent and sensible heat of exhaust air were 61.4 percent and 11.2 percent respectively. The heat which was required in raising grain temperature and stored in dryer was relatively small. As the recycle ratio of exhaust air was increased, the drying rate was suddenly decreased, and thermal efficiency of the kerosene burner was also decreased. Drying test with 0.76 recycle ratio resulted in 12.4% increase in fuel consumption, and 38.4% increase in electric power consumption as compared to the non-recycled drying test. Drying test of 0.22 recycle ratio resulted in 6.8% saving in total energy consumption, 8.0% reduction in fuel consumption, and 2.5% increase in electric power consumption as compared to the non-recycled drying test.

• Journal of Environmental Science International
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• v.9 no.6
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• pp.449-454
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• 2000

Sustainable development has been the key concept, both in economic policies and in environmental management. On the basis of an systems ecology perspective, this suggests the sustainable development of Korea\`s natural environment and economic activity using the EMERGY evaluation. The total EMERGY use(7,730E20sej/yr) in Korea is 81 percent from imported sources, fuels and goods and services. The ratio of outside investment to attracting natural resources is already large, like other industrialized countries. Continued availability of purchased inputs at a favorable balance of EMERGY trade, currently about 2.85 to 1 net EMERGY, tis the basis for present economic activity and must decrease as the net EMERGY of purchased inputs including fossil fuels goes down. EMERGY yield ratio and environmental loading ratio were 1.23 and 20.30, respectively. The population level is already in excess of carrying capacity. Its carrying capacity for steady state on its renewable sources is only 2.2 million people, compared to 45.9 million in 1977. EMERGY sustainability index is therefore less than one, which is indicative of highly developed consumer oriented economies. Until now the development of a country has been achieved by the economic growth, but it can be sustained in the long run by the use of renewable resource systems. the efficiency of energy usage, and the transformation of the social-economic structure based on an ecological-recycling concept.

• Resources Recycling
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• v.12 no.3
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• pp.13-24
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• 2003

The production characteristics of activated carbon from waste walnut shell have been investigated by taking activation temperature, activation time, amount of activating agent, and kind of activating agent as the major influential factors. The adsorption capacity of the activated carbon which was produced using phosphoric acid as the activating agent increased with activation temperature and showed its greatest value at about $550^{\circ}C$. Yield for activated carbon was observed to decrease continuously as the activation temperature was raised. The optimal activation time for the highest adsorption capacity was found to be about 2 hr, and as the activation time increased the yield for activated carbon was showed to decrease continuously. The increase in the amount of activating agent resulted in the increase of the yield for activated carbon, however, excessive amount of activating agent deteriorated its adsorption capacity reversely. The variations of the microstructure of activated carbon observed by SEM with several influential factors, correlated very well with its changes in the adsorbability with the same factors and the kind of activating agent was found to play an important role in the determination of the adsorption capacity of activated carbon. To investigate the adsorption characteristics of the produced activated carbon, the adsorption reactions of $Cu^{2+}$ ion were examined using the produced activated carbon as the adsorbent. In general, the kinetics of the adsorption of $Cu^{2+}$ ion was observed to follow a 2nd-order reaction and the rate constant for adsorption reaction increased as the initial concentration of adsorbate was diminished. The equilibrium adsorption of $Cu^{2+}$ was explained well with Freundlich model and its adsorption reaction was found to be endothermic. The activation energy for adsorption was calculated to be 13.07 kcal/mol, which implied that the adsorption reaction was very irreversible, and several thermodynamic parameters of adsorption reaction were estimated using van't. Hoff equation and thermodynamic relationships.

• Resources Recycling
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• v.33 no.3
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• pp.3-11
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• 2024

This study addressed the cost structure of metallurgical plants for vanadium recovery or production, which were previously planned or implemented. Vanadium metallurgy consists of several sub-processes such as such as pretreatment, roasting, leaching, precipitation, and filtration, in order to finally produce vanadium pentoxide. Here, lots of costs should be spent for such plants, in which these costs are largely divided into CAPEX (Capital Expenditure) and OPEX (Operational Expenditure). As a result, the capacities (feed input rates) and vanadium contents are various along the target projects for this study. However, final production rates and grades of vanadium pentoxide showed relatively small differences. In addition, a noticeable correlation is found between capacities and specific operating costs, in that a steadily decreasing trend is described with a non-linear curve with around -0.3 power. Therefore, for the plant capacity below 100,000 tons per year, the specific operating cost rapidly decreases as the capacity increases, whereas the cost remains relatively stable in the range of 0.6 to 1.2 million tons per year of the capacity. From a technical perspective, effective optimization of the metallurgical process plant can be achieved by improving vanadium recovery rate in the pre-treatment and/or roasting-leaching processes. Finally, the results of this study should be updated through future research with on-going field verification and further detailed cost analysis.

• Resources Recycling
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• v.10 no.3
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• pp.37-42
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• 2001

Current iron and steelmaking operation was re-evaluated on the basis of slag engineering technology to optimize slag operations. In blast furnace process, increase in the basicity of slags (C/S) could obtain progressed fluidity and hot metal quality. COREX process would be stabilized in view of slag fluidity and hot metal quality by reducing input content of $SiO_2$and $A1_2$$O_3$In STS-AOD process, addition of small amount of lime could improve refining capacity of the slag; also calcium aluminate flux could be taken into account as a potential substitute for fluorspar, without degradation of operation efficiency and steel quality.

• Resources Recycling
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• v.19 no.2
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• pp.28-34
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• 2010

In this study, cow tibial from cow bone, a kind of beef waste, sintered at $800\sim850^{\circ}C$ for three hours was used to measure its removal capacity for metal ions such as Pb, Cd and Zn in a single and a multi-component equilibrium systems. The sorption equilibrium data were analyzed as measured by the effect of media on lead, cadmium and zinc sorption. This analysis shows that the sorption of metal ions for multi-component systems applying IAST can be predicted more reasonably by the Freundlich and the Sips theory than the Langmuir.

• Journal of the Korea Organic Resources Recycling Association
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• v.5 no.2
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• pp.57-64
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• 1997

This study was performed to investigate the characteristics of compost produced from the composting facility at Nanjido. The capacity of the facility is 10 ton/day. Feed material was food waste generated in Seoul. Moisture content of the compost product was 31% and conductivity was 2.6 mmhos/cm. The compost product met Korean quality standards and EC quality standards for VS and C/N ratio. In case of TOC and TKN, they were met with Japan quality standards. The water soluble-C/N ratio finally reached about 5 based on dry compost. The color of compost product was dark brown. The product had earthy smell. Heavy metal contents of the compost were below Korean quality standards by wet basis.

• Resources Recycling
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• v.22 no.2
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• pp.3-10
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• 2013

Indium is one of the rare metals, and it has been used mainly for preparation of indium tin oxide (ITO). This review investigated the process parameters and the merits and demerits of several methods to recover indium from the leaching solution of secondary resources, such as solvent extraction, ion exchange, and precipitation. D2EHPA has been used mostly as a cationic extractant for indium extraction in moderate acid solutions, while amine extractants are used in strong hydrochloric acid solution. Since the loading capacity of resins for indium is generally small, ion exchange has some advantage over solvent extraction only when the concentration of indium is low.