• Resources Recycling
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• v.8 no.1
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• pp.23-28
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• 1999

Firing characteristics, transverse rupture strength, and heat capacity were studied of the heat-reservoir refractory materials made of red-firing clay, mill scale, and water glass. The firing shrinkage increased with increase of the clay proportion in samples. The volume of fired bodies showed shrinkage by drying up to $300^{\circ}C$, steady expansion in the 300-$700^{\circ}C$ range due to phase transition of iron oxides. and drastic expansion above $1200^{\circ}C$. Flexural strength decreased from 5.6 Mpa to 2.35 Mpa with the decrease of the ratio of clay to mill scale from 1:1 to 1:3 Heat capacities changed from 1.1 Joul/g$^{\circ}$C to 1.35 Joul/g$^{\circ}$C with the ratio of millscale to clay ratio from 1:1 to 1:3. Mill scale in the specimen appears to exist as liquid phase during firing. Firing the specimens in air leads to the eruption of the molten mill scale to the sample surfaces. Contrarily, firing samples in a refractory sagger with a cover suppressed the eruption of the molten mill scale to the surfaces. The addition of mill scale gave rise to porous sintered bodies which would delay cooling rates of heat-reservoir brick.

• Resources Recycling
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• v.14 no.4 s.66
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• pp.47-52
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• 2005

Carbonate species in aqueous solution play an important role in the determination of chemical properties of water in relation with alkalinity, buffer capacity, biological productivity, and so on. These compounds also have reactive characteristics such as interphasal reactions between solid, liquid, and gas phases. In the absence of solid materials, the total amount and relative abundance of each carbonate species are directly influenced by the partial pressure of $CO_2$ gas in the atmosphere, which in turn significantly affects the properties of aquatic system. In the water/wastewater treatment process along with the wastes treatment and recycling process which occurring in aquatic environment, it is essential to figure out its characteristics for their optimization and one of its most influential features upon these processes is determined by carbonate species. To understand the fundamental aspect of the relationship between the partial pressure of $CO_2$ gas and chemical features of water, especially pH, the working partial pressure of pure $CO_2$ gas that produced by contacting the dry ice with water has been estimated based on equilibrium calculation. The equilibrium constants for the dissociation ot carbonic acid were determined using van't Hoff equation and the distribution diagram of carbonate species according to the pH has been constructed to substantiate the results of equilibrium calculation. The estimated working partial pressure of pure $CO_2$ gas was found to be a function of the concentration of carbonates in solution, which suggesting that Prior evaluation of the working partial pressure of gas is essential for a better understanding of aquatic interactions.

• Computers and Concrete
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• v.26 no.4
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• pp.327-342
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• 2020

The objective of this study is to manufacture environmentally-friendly synthetic lightweight aggregates that may be used in the structural lightweight concrete production. The cold-bonding pelletization process has been used in the agglomeration of the pozzolanic materials to achieve these synthetic lightweight aggregates. In this context, it was aimed to recycle the waste fly ash by employing it in the manufacturing process as the major cementitious component. According to the well-known facts reported in the literature, it is stated that the main disadvantage of the synthetic lightweight aggregate produced by applying the cold-bonding pelletization technique to the pozzolanic materials is that it has a lower strength in comparison with the natural aggregate. Therefore, in this study, the metakaolin made of high purity kaolin and calcined kaolin obtained from impure kaolin have been employed at particular contents in the synthetic lightweight aggregate manufacturing as a cementitious material to enhance the particle crushing strength. Additionally, to propose a curing condition for practical attempts, different curing conditions were designated and their influences on the characteristics of the synthetic lightweight aggregates were investigated. Three substantial features of the aggregates, specific gravity, water absorption capacity, and particle crushing strength, were measured at the end of 28-day adopted curing conditions. Observed that the incorporation of thermally treated kaolin significantly influenced the crushing strength and water absorption of the aggregates. The statistical evaluation indicated that the investigated properties of the synthetic lightweight aggregate were affected by the thermally treated kaolin content more than the kaoline type and curing regime. Utilizing the thermally treated kaolin in the synthetic aggregate manufacturing lead to a more than 40% increase in the crushing strength of the pellets in all curing regimes. Moreover, two numerical formulations having high estimation capacity have been developed to predict the crushing strength of such types of aggregates by using soft-computing techniques: gene expression programming and artificial neural networks. The R-squared values, indicating the estimation performance of the models, of approximately 0.97 and 0.98 were achieved for the numerical formulations generated by using gene expression programming and artificial neural networks techniques, respectively.

• Journal of the Korea Institute of Building Construction
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• v.14 no.1
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• pp.94-101
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• 2014

Approximately 240,000 tons of waste shells are produced annually in the south and west coast of South Korea. Some of these waste shells (oyster, cockle) are recycled as seeding collector and fertilizer, but most are dumped illegally near the coast. One of the alternative solutions that can economically utilize a large amount of these waste shells is to apply them to the production of construction materials. In this research, the basic physical properties of waste shells such as oyster, cockle, clam, manila clam were investigated, and were used to prepare cement mortar with a 25% replacement ratio of sand. According to the results, the 28 day compressive strength of cement mortar with cockle and manila clam shells was similar to that of plain cement mortar. The compressive strength decreased by about 18% when clam was used. However, the cement mortar with oyster shell showed about a 35% reduction in 28-day compressive strength, and two times the absorption capacity of plain cement mortar. The reduction in compressive strength and the increase in absorption capacity were mostly associated with the porous nature of the oyster shell.

• Journal of the Korean Geosynthetics Society
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• v.11 no.1
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• pp.57-63
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• 2012

Steel slag has the nature to hydrate and expand when in contact with non-reacting CaO and water, and thus can be used only in limited scope for landfill disposal as well as for recycling as civil construction aggregates. In order to use such steel slags more efficiently, the applicability of steel slag as sand mat alternative material was reviewed. In general, sand mat is used in soft ground surface reinforcement method and horizontal drain method, and is installed simultaneously with soft ground vertical drain method. Therefore in this study steel slag designing method and application standard etc were examined to recycle steel slag as sand mat alternative material, and laboratory soil test and model test were done. Test results indicated that the designing method and application standard meet various environment and quality standards, meaning that steel slag can be utilized as sand mat alternative material, and analysis of slag mat bearing capacity also indicated that use of steel slag produces double or more bearing capacity compared with existing sand mat.

• Structural Engineering and Mechanics
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• v.83 no.3
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• pp.305-326
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• 2022

To realize the recycling utilization of waste concrete and alleviate the shortage of resources, 11 specimens of steel reinforced recycled concrete (SRRC) filled circular steel tube columns were designed and manufactured in this study, and the cyclic loading tests on the specimens of columns were also carried out respectively. The hysteretic curves, skeleton curves and performance indicators of columns were obtained and analysed in detail. Besides, the finite element model of columns was established through OpenSees software, which considered the adverse effect of recycled coarse aggregate (RA) replacement rates and the constraint effect of circular steel tube on internal RAC. The numerical calculation curves of columns are in good agreement with the experimental curves, which shows that the numerical model is relatively reasonable. On this basis, a series of nonlinear parameters analysis on the hysteretic behaviors of columns were also investigated. The results are as follows: When the replacement rates of RA increases from 0 to 100%, the peak loads of columns decreases by 7.78% and the ductility decreases slightly. With the increase of axial compression ratio, the bearing capacity of columns increases first and then decreases, but the ductility of columns decreases rapidly. Increasing the wall thickness of circular steel tube is very profitable to improve the bearing capacity and ductility of columns. When the section steel ratio increases from 5.54% to 9.99%, although the bearing capacity of columns is improved, it has no obvious contribution to improve the ductility of columns. With the decrease of shear span ratio, the bearing capacity of columns increases obviously, but the ductility decreases, and the failure mode of columns develops into brittle shear failure. Therefore, in the engineering design of columns, the situation of small shear span ratio (i.e., short columns) should be avoided as far as possible. Based on this, the calculation model on the skeleton curves of columns was established by the theoretical analysis and fitting method, so as to determine the main characteristic points in the model. The effectiveness of skeleton curve model is verified by comparing with the test skeleton curves.

• Journal of the Korean Recycled Construction Resources Institute
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• v.12 no.2
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• pp.188-195
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• 2024

Recently, the use of recycled aggregates from construction waste has been introduced as a solution for environmental problems and aggregate shortage. In spite of the various methods to promote recycling of recycled aggregate, the use of recycled aggregate as the structural aggregate has been limited because the quality of recycled aggregate(especially recycled fine aggregate) has been considered lower than that of natural aggregate. In this work, recycled fine aggregate was immersed for an hour in acrylic resin solutions of various concentrations to improve its quality, the appropriate immersion concentration was selected by measuring the absorption capacity and skeletal density of the recycled fine aggregate, and mortar specimens were prepared to evaluate the mechanical performance in order to propose a applicable treatment process to promote the use of recycled fine aggregate. According to the experimental results, as the acrylic resin concentration increased, the absorption capacity and skeletal density of the recycled fine aggregate decreased. The absorption capacity was lowest at acrylic resin concentrations around 6 to 8 %. However, among mortar specimens made of recycled fine aggregate immersed in acrylic resin solution, the compressive strength was the highest at 4 % acrylic resin concentration, suggesting that the use of higher concentration acrylic resin solution can actually lower the compressive strength of mortar.

• Microbiology and Biotechnology Letters
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• v.19 no.2
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• pp.171-178
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• 1991

The two-stage enzyme reactor, packed with cyclodextrin glucanotransferase (CGTase) immobilized on Amberite IRA 900, coupled with ultrafiltration membrane was investigated for continuous production of cyclodextrin (CD). 5% (w/v) of soluble starch was partially cyclized, in the 0.1 l first-stage immobilized enzyme reactor, up to CD conversion yield of 10% (w/w) at retention time of 0.56hr and 1.5 units of immobilized CGTase/1g of carrier. In the second stage main immobilized enzyme reactor capacity of 1.5 l, the maximum CD conversion yield of 39% (w/v) was achieved at retention time of 2.8hr and 0.47 unit of CGTase/1 g of carrier. Unreacted residual dextrin was fractionated with ultrafiltration membrane, and then, recycled into the second-stage main bioreactor to increase the CD conversion yield. The most suitable membrane size and the volume concentration ratio (concentrate: filterate) for recycling of unreacted residual dextrin were found to be 5K dalton and 4:6, respectively. CD conversion yield was increased about 3~4% upon co-immobilization of pulluanase along with CGTase. Spent Amberite IRA 900 can be reutilized consecutively more than 3 times for immobilization of CGTase after regeneration.

• Proceedings of the Korea Concrete Institute Conference
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• 2004.05a
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• pp.76-79
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• 2004

The use of recycled aggregate concrete is increasing faster than the development of appropriate design recommendations. This paper is making advances in the recycling of waste concrete material for use as recycled aggregate to make secondary concrete product. Using recycled aggregates from demolished concrete, we manufactured concrete blocks to experiment overall performance in feasible performances. This paper reports limited experimental data on the structural performance of shear wall used concrete blocks made in recycled aggregates. Reinforced concrete frame and shear walls were tested to determine their diagonal cracking and ultimate shear behavior. The variable in the test program was the existence of infilled wall used concrete blocks Made in recycled aggregates. Based on the experimental results, Infilled wall has a high influence on the maximum strength and initial stiffness of reinforced concrete frame. Structural performance of specimen WSB1 and WSB2 is quite different from RCF specimen, particularly strength, stiffness and energy dissipation capacity.

• Journal of The Korean Society of Agricultural Engineers
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• v.50 no.3
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• pp.105-112
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• 2008

Solar energy, which is one of renewable energy, would be the most useful resources that can be applied to making energy recycling villages without using fossil energy. This study analyzed energy potential on solar energy considering weather condition in three traditional villages and compared with energy consumption surveyed. A photovoltaic system having 3.0kWp capacity of unit module can generate 182.5%, 96.1% and 170.9% of the yearly mean consumption of electric power in Makhyun, Boojang, and Soso, respectively. A flat-plate solar collector having $2.64m^2$ area of unit module can generate warm water of $142{\ell}$/day, $89{\ell}$/day, and $173{\ell}$/day, respectively in three study villages. In Makhyun and Soso, photovoltaic power and warm water produced by solar energy were sufficient to supply required amount of electric power and warm water. However, both electric power and warm water produced by unit solar module were not sufficient in Boojang area, and so it is required to increase the module area by more than 50%. According to the results of this study, the appropriate combination of energy resources can be applied to rural green-village planning if the characteristic of energy potential for each local area is considered.