• Journal of the Korean Society of Safety
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• v.19 no.3 s.67
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• pp.57-64
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• 2004

This is the study for the removal of a toxic heavy metal ions and the recycling of expanded polystyrene wastes. Thus expanded polystyrene wastes collected from the packing materials of TV or chemicals and dissolved by $80wt.\%$ solvent(N, N-Dimethylacrylamide), electrospun in DC 20kV by power supply. Generally, the electrospinning is a process of manufacture to the fibers of nanosize from polymer solution. Manufactured nanofiber mats by electrospinning were sulfonated by cone.-sulphuric acid with $Ag_2S_O_4$ catalysts for the exchange capacity of heavy metal ions and the properties of structure with sulfonated time investigated by FESEM(Feild Emission Scaning Electron Microscope). The ion exchange capacity of light metal$(Na^+)$, Cd(II) and Ni(II), and by a nanofiber mats were 1.94[mmo1/g-dry-mat), 1.72(mmol/g-dry-mat), 1.24(mmol/g-dry-mat), respectively., and water uptake content showed a similar trend with IEC. and The selectivity coefficients $K^M_H$ of Cd(II), Ni((II) ions showed 0.324, 0.228. respectively.

• Applied Chemistry for Engineering
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• v.32 no.5
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• pp.589-598
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• 2021

The purpose of this study was to analyze the efficiency with which phosphorylated spent coffee grounds (PSCG) remove cationic Cu(II) ions from an aqueous solution. The pHpzc of the SCG was 6.43, but it was lowered to 3.96 in the PSCG, confirming that an acidic functional group was attached to the surface of the PSCG. According to FT-IR analysis, phosphorylation of the SCG added P=O, P-O-C (aromatic), P=OOH, and P-O-P groups to the surface of the adsorbent, and the peaks of the carboxyl and OH groups were high and broad. Also, the specific surface area, mesopore range, and ion exchange capacity increased significantly by phosphorylation. The adsorption kinetics and isothermal experiments showed that Cu(II) adsorption using SCG and PSCG was explained by PSO and Langmuir models. The maximum Langmuir adsorption capacity of SCG and PSCG was 42.23 and 162.36 mg/g, respectively. The adsorption process of both SCG and PSCG was close to physical adsorption and endothermic reaction in which the adsorption efficiency increased with temperature. PSCG was very effective in adsorbing Cu(II) in aqueous solution, which has great advantages in terms of recycling resources and adsorbing heavy metals using waste materials.

• Advances in concrete construction
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• v.11 no.3
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• pp.239-253
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• 2021

The behavior of concrete containing waste glass as a replacement of cement or aggregate was studied previously in the most of researches, but the present investigation focuses on the recycling of waste glass powder as a substitute for silica fume in high strength concrete (HSC). This endeavor deals with the efficiency of using waste glass powder, as an alternative for silica fume, in the flexural capacity of HSC beam. Thirteen members with dimensions of 0.3 m width, 0.15 m depth and 0.9 m span length were utilized in this work. A comparison study was performed considering HSC members and hybrid beams fabricated by HSC and conventional normal concrete (CC). In addition to the experiments on the influence of glass powder on flexural behavior, numerical analysis was implemented using nonlinear finite element approach to simulate the structural performance of the beams. Same constitutive relationships were selected to model the behavior of HSC with waste glass powder or silica fume to show the matching between the modeling outputs for beams made with these powders. The results showed that the loading capacity and ductility index of the HSC beams with waste glass powder demonstrated enhancing ultimate load and ductility compared with those of HSC specimens with silica fume. The study deduced that the recycled waste glass powder is a good alternative to the pozzolanic powder of silica fume.

• Korean Journal of Materials Research
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• v.34 no.7
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• pp.370-376
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• 2024

In this study, we report significant improvements in lithium-ion battery anodes cost and performance, by fabricating nano porous silicon (Si) particles from Si wafer sludge using the metal-assisted chemical etching (MACE) process. To solve the problem of volume expansion of Si during alloying/de-alloying with lithium ions, a layer was formed through nitric acid treatment, and Ag particles were removed at the same time. This layer acts as a core-shell structure that suppresses Si volume expansion. Additionally, the specific surface area of Si increased by controlling the etching time, which corresponds to the volume expansion of Si, showing a synergistic effect with the core-shell. This development not only contributes to the development of high-capacity anode materials, but also highlights the possibility of reducing manufacturing costs by utilizing waste Si wafer sludge. In addition, this method enhances the capacity retention rate of lithium-ion batteries by up to 38 %, marking a significant step forward in performance improvements.

• Resources Recycling
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• v.15 no.6 s.74
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• pp.48-55
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• 2006

This study was carried out for establishing the physical recycling technique for commercializing process on household batteries. The procedure involves shape separator, crushing, magnetic separation, classification and eddy current separation in sequence. The separation capacity was 400-600 unit cell/hr with shape separation system. The impurities such as manganese and zinc in the magnetic product were below 0.1% respectively, the concentration of iron was above 99% in spent carbon zinc battery. Also non-magnetic products are composed of 22-30% En, 16-22% Mn, 1-3% Fe in the case oi spent zinc carbon battery. The amounts of other components such as carbon rod, plastics and separator were about 37-50%. From the eddy current separation of nonferrous products, the plate-type zinc components were separated up to 96% with 2,250-2,750 meter/min of the conveyor speed.

• Resources Recycling
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• v.21 no.1
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• pp.17-29
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• 2012

potential assessment of converting closed non sanitary landfills into sustainable landfill through the reclamation works(= landfill mining project) of illegal landfill discovered in land development site using Sustainable Landfill Reclamation system(SLR-system) was investigated. The SLR system had treatment capacity of 91.4 $m^3/hr$ (130.61 ton/hr) in condition of 28.0% of water content. Recovery ratio and purity of sorted soil were 98.9% and 99.66%, respectively. Sorted combustibles were 91.8% and 92.0%, respectively. Especially, high heating value (HHV) and low heating value(LHV) of combustibles were 4,282kcal/kg and 3,636 kcal/kg, respectively, in considering the energy content and recovery ratio of combustibles. Therefore, combustibles separated from landfill site have higher value than Fluff RDF standard value(3,500kcal/kg) of MOE. RDF can be produced with combustibles by 84.43%. Averaged size and organic foreign matter content of the sorted soil were less than 035mm and 0.31 %(VN), respectively. In addition, concentration of all contents of hazardous matters containing soils met safety standards. Therefore, it is possible to be recycled as refilling and cover materials to rebuild Sustainable landfills by 98.42%.

• Economic and Environmental Geology
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• v.54 no.2
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• pp.285-297
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• 2021

Globally, nuclear-decommissioning facilities have been increased in number, and thereby hundreds of thousands of wastes, such as concrete, soil, and metal, have been generated. For this reason, there have been numerous efforts and researches on the development of technology for volume reduction and recycling of solid radioactive wastes, and this study reviewed and examined thoroughly such previous studies. The waste concrete powder is rehydrated by other processes such as grinding and sintering, and the processes rendered aluminate (C3A), C4AF, C3S, and ��-C2S, which are the significant compounds controlling the hydration reaction of concrete and the compressive strength of the solidified matrix. The review of the previous studies confirmed that waste concretes could be used as recycling cement, but there remain problems with the decreasing strength of solidified matrix due to mingling with aggregates. There have been further efforts to improve the performance of recycling concrete via mixing with reactive agents using industrial by-products, such as blast furnace slag and fly ash. As a result, the compressive strength of the solidified matrix was proved to be enhanced. On the contrary, there have been few kinds of researches on manufacturing recycled concretes using soil wastes. Illite and zeolite in soil waste show the high adsorption capacity on radioactive nuclides, and they can be recycled as solidification agents. If the soil wastes are recycled as much as possible, the volume of wastes generated from the decommissioning of nuclear power plants (NPPs) is not only significantly reduced, but collateral benefits also are received because radioactive wastes are safely disposed of by solidification agents made from such soil wastes. Thus, it is required to study the production of non-sintered cement using clay minerals in soil wastes. This paper reviewed related domestic and foreign researches to consider the sustainable recycling of concrete waste from NPPs as recycling cement and utilizing clay minerals in soil waste to produce unsintered cement.

• International Journal of Concrete Structures and Materials
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• v.2 no.1
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• pp.35-39
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• 2008

This experimental study examines the applicability of polymer mortar permanent forms using a methyl methacrylate (MMA) solution of waste expanded polystyrene (EPS) to develop effective recycling processes for the EPS, referring to the flexural behavior of a polymer-impregnated mortar permanent form with almost the same performance as commercial products. An MMA solution of EPS is prepared by dissolving EPS in MMA, and unreinforced and steel fiber-reinforced polymer mortars are mixed using the EPS-MMA-based solution as a liquid resin or binder. Polymer mortar permanent forms (PMPFs) using the EPS-MMA-based polymer mortars without and with steel fiber and crimped wire cloth reinforcements and steel fiber-reinforced polymer-impregnated mortar permanent form (PIMPF) are prepared on trial, and tested for flexural behavior under four-point (third-point) loading. The EPS-MMAbased PMPFs are more ductile than the PIMPF, and have a high load-bearing capacity. Consequently, they can replace PIMPF in practical applications.

• Journal of environmental and Sanitary engineering
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• v.15 no.3
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• pp.62-69
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• 2000

In point of recycling wastes, batch test was conducted to examine the neutralization and Fe removal from laboratory wastewater using wastes. Oyster shell and slag had a buffer capacity to neutralize an acidic wastewater but tire rubber didn't. With increasing reaction time, dosage and agitation speed, Fe was well removed by wastes. As a result on the experiments of Freundlich isotherm, the adsorption intensities(1/n) were 0.32∼0.46 and the adsorption capacities(k) were 4.3∼4.6 for removing Fe from laboratory wastewater by wastes. In view of these results, it was estimated that wastes containing the similar compositions as these could utilize the neutralization and adsorption of heavy metals in laboratory wastewater.

• Magazine of the Korean Society of Agricultural Engineers
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• v.38 no.4
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• pp.137-146
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• 1996

This paper presents the results of field experience from an experimental pavement construction on a low volume road using recycled concrete. The recycled concrete was prepared by replacing a half of coarse aggregate with recycled aggregate. Virgin natural sand was used as fine aggregate together a plasticizer and a fly ash (0.8% and 5% by wt. of cement, respectively). The load bearing capacity of the subbase made of recycled aggregate was acceptable. The length, thickness and width of the pavement were l00m, 20cm and 3m, respectively. From construction experience, it was found that workability and finishability of the recycled concrete mixture were relatively poor, but strengths were satisfactory. Flexural strength, compressive strength and elastic modulus at 28 days were 54Kg/$cm^2$, over 250Kg/$cm^2$, and 220,OOOKg/$cm^2$, respectively. The construction could be performed by hand without much difficulty. The surface was finished smoothly by wet fabric and only minor cracks were found on the surface.