• Korean Journal of Materials Research
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• v.13 no.12
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• pp.850-854
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• 2003

The abrasion wear behavior on the hardfacing weld was investigated by performing abrasion wear, hardness, and microstructural tests. The gas metal arc(GMA) weld was produced by using the cored wire which was filled with the hard metal, i.e., the recycled tungsten carbide (WC) reinforced metal matrix composite. For 30% addition of the hard metal, the abrasion wear resistance was significantly improved comparing with that for 20% addition of the hard metal. Above 30% addition of the hard metal, however, there was no significant improvement of the wear resistance. The improvement of the wear resistance was due to the increased amount of eutectic carbides(W$_{6}$C) which was formed during GMA welding. For the weld in which the hard metal was added to 30-40%, an optimum level of abrasion wear resistance was performed.

• International Journal of Korean Welding Society
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• v.3 no.2
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• pp.1-6
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• 2003

The abrasion and impact wear resistance were investigated on the hardfacing weld dispersed with the recycled hard metal(HM). The HM was composed of the tungsten carbide(WC) reinforced metal matrix composite. The cored wire filled with the 35 wt.％ HM and 0­6 wt.％ of the alloying element, Fe­75Mn­7C(FeMnC), was used for the gas metal arc(GMA) welding. The FeMnC addition to the 35 wt.％ HM did not improve the abrasion wear property since the amount of the tungsten carbide formed was decreased with respect to the FeMnC amount. However, the 6 wt.％ FeMnC addition to the 35 wt.％ HM exhibited the better impact wear resistance than the hardfacing weld by the 40 wt.％ HM.

• Journal of Powder Materials
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• v.18 no.3
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• pp.277-282
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• 2011

[ $LiCoO_2$ ] a cathode material for lithium rechargeable batteries, was prepared using recycled $Co_3O_4$. First, the cobalt hydroxide powders were separated from waste WC-Co hard metal with acid-base chemical treatment, and then the impurities were eliminated by centrifuge method. Subsequently, $Co_3O_4$ powders were prepared by thermal treatment of resulting $Co(OH)_2$. By adding a certain amount of $Li_2CO_3$ and $LiOH{\cdot}H_2O$, the $LiCoO_2$ was obtained by sintering for 10 h in air at $800^{\circ}C$. The synthesized $LiCoO_2$ particles were characterized by X-ray diffraction (XRD) and Scanning Electron Microscope (SEM) analysis.

• Korean Journal of Materials Research
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• v.13 no.12
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• pp.839-845
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• 2003

The abrasion and impact wear resistance were investigated on the hardfacing weld dispersed with the recycled hard metal(HM). The HM was composed of the tungsten carbide(WC) reinforced metal matrix composite. The cored wire filled with the 25-35wt.% HM and 2-8wt.% of the alloying element, Fe-75Mn- 7C(FeMnC), was used for the gas metal arc(GMA) welding. By using the cored wire of the 25wt.% HM and FeMnC addition, the weld showed mostly constant wear loss for the abrasion as a function of the FeMnC content. This was due to the insufficient amount of the tungsten carbide formed during the GMA welding. The FeMnC addition to the 35wt.% HM did not improve the abrasion wear property since the amount of the tungsten carbide formed was decreased with respect to the FeMnC amount. The 6wt.% FeMnC addition to the 35wt.% HM exhibited the better impact wear resistance than the hardfacing weld by 40wt.% HM.

• Transactions of Materials Processing
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• v.24 no.4
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• pp.287-292
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• 2015

The possibility of chemical precipitation for recycled ammonium paratungstate (APT) was studied. WO₃ particles were synthesized by chemical precipitation method using a 1:2 weight ratio of APT:DI-water. At the 500℃ sintering temperature, the X-ray diffraction results showed that APT completely decomposed to WO₃. For the granulated powder WC-Co, vacuum heat treatment at proper temperatures increases tap density and flow-ability. Hardness of the WC-Co thermal spray coating layer was measured in the range HV 831~1266. Spray conditions for the best characteristic values were an oxygen flow rate=1500 scfh, a fuel flow rate = 5.25gph and a gun distance = 320mm.

• Journal of Powder Materials
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• v.29 no.3
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• pp.252-261
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• 2022

Cobalt is a vital metal in the modern society because of its applications in lithium-ion batteries, super alloys, hard metals, and catalysts. Further, cobalt is a representative rare metal and is the 30th most abundant element in the Earth's crust. This study reviews the current status of cobalt extraction and recycling processes, along with the trends in its production amount and use. Although cobalt occurs in a wide range of minerals, such as oxides and sulfides of copper and nickel ores, the amounts of cobalt in the minerals are too low to be extracted economically. The Democratic Republic of Congo (DRC) leads cobalt mining, and accounts for 68.9 % of the global cobalt reserves (142,000 tons in 2020). Cobalt is mainly extracted from copper-cobalt and nickel-cobalt concentrates and is occasionally extracted directly from the ore itself by hydro-, pyro-, and electro-metallurgical processes. These smelting methods are essential for developing new recycling processes to extract cobalt from secondary resources. Cobalt is mainly recycled from lithium-ion batteries, spent catalysts, and cobalt alloys. The recycling methods for cobalt also depend on the type of secondary cobalt resource. Major recycling methods from secondary resources are applied in pyro- and hydrometallurgical processes.

• Journal of Powder Materials
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• v.28 no.6
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• pp.497-501
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• 2021

Cobalt (Co) is mainly used to prepare cathode materials for lithium-ion batteries (LIBs) and binder metals for WC-Co hard metals. Developing an effective method for recovering Co from WC-Co waste sludge is of immense significance. In this study, Co is extracted from waste cemented carbide soft scrap via mechanochemical milling. The leaching ratio of Co reaches approximately 93%, and the leached solution, from which impurities except nickel are removed by pH titration, exhibits a purity of approximately 97%. The titrated aqueous Co salts are precipitated using oxalic acid and hydroxide precipitation, and the effects of the precipitating agent (oxalic acid and hydroxide) on the cobalt microstructure are investigated. It is confirmed that the type of Co compound and the crystal growth direction change according to the precipitation method, both of which affect the microstructure of the cobalt powders. This novel mechanochemical process is of significant importance for the recovery of Co from waste WC-Co hard metal. The recycled Co can be applied as a cemented carbide binder or a cathode material for lithium secondary batteries.