• Bulletin of the Korean Chemical Society
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• v.29 no.3
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• pp.682-684
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• 2008

• Journal of the Korean Chemical Society
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• v.52 no.4
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• pp.454-456
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• 2008

• YAKHAK HOEJI
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• v.33 no.4
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• pp.226-228
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• 1989

In connection with the synthesis of the biologically active pimarane diterpenoids, some synthetic routes to the quaternary carbon unit were examined. Especially, Claisen rearrangement of allyl acetates prepared from acetol provided ${\gamma}-hydroxy$ acid containing vinyl substituent as the desired unit.

• Bulletin of the Korean Chemical Society
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• v.24 no.9
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• pp.1284-1288
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• 2003

A very short and concise synthetic route for a novel acyclic version of d4T is described. The required quaternary carbon was successfully installed using a [3,3]-sigmatropic rearrangement. The condensation of the mesylates 16-18 with an adenine base under standard nucleophilic substitution conditions ($K_2CO_3$, 18-Crown- 6, DMF) in addition to deblocking afforded the target acyclic nucleosides 22-24. In addition, the antiviral evaluations against various viruses were performed.

• Bulletin of the Korean Chemical Society
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• v.24 no.9
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• pp.1289-1292
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• 2003

An efficient synthetic route for preparing novel $4'{\alpha}$-C phenyl branched carbocyclic nucleoside is described. The installation of phenyl group at the $4'$-position of carbocyclic nucleoside was successfully accomplished via a sequential [3,3]-sigmatropic rearrangement and ring-closing metathesis (RCM) beginning from simple ketone such as 2-hydroxy acetophenone.

• Bulletin of the Korean Chemical Society
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• v.29 no.9
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• pp.1669-1670
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• 2008

• YAKHAK HOEJI
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• v.47 no.5
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• pp.271-275
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• 2003

Easy and efficient synthetic route of novel 4'-C methyl branched carbocyclic nucleosides is described. The installation of alkyl and aryl groups at 4'-position of carbocyclic nucleosides were successfully made via sequential [3,3]-sigmatropic rearrangement and ring-closing metathesis (RCM) starting from simple ketones such as acetol. Adenine and uracil were coupled via Pd(0) catalyzed reaction, followed by desilylation to give novel compounds 13 and 14, respectively.

• Bulletin of the Korean Chemical Society
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• v.15 no.10
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• pp.889-890
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• 1994

A comparative molecular field analysis (CoMFA) on the substituent effect of the palladium(Ⅱ) catalyzed [3,3]-sigmatropic rearrangement of allylic esters was studied to show a good correlation between the electrostatic property of substituents and the reaction rate. The CoMFA result suggests that the reaction rate will increase as the electron-donating ability of substituents increases.

• Bulletin of the Korean Chemical Society
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• v.7 no.6
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• pp.442-444
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• 1986

Starting with the readily available p-tert-butyl-calix[4]arene 2, tert-butyl groups are removed by $AlCl_3$-catalyzed de-alkylation reaction, and the calix[4]arene 3 formed is converted to the tetraacetate 4. This compound undergoes Fries rearrangement to yield p-acetylcalix[4]arene 6, which seems to be an attractive starting material for the introduction of functional groups. As a preliminary experiment p-(1-hydroxyethyl)calix[4]arene 7 is prepared by LiAlH$_4$ reduction of 6.

• Journal of the Chungcheong Mathematical Society
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• v.24 no.2
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• pp.267-271
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• 2011

Let 0 < s < 1. For $f^{\ast}$ representing the symmetric radial decreasing rearrangement of f, we build up a fractional version of Polya-$Szeg{\ddot{o}}$ inequality: $${\int}_{\mathbb{R}^n}{\mid}(-\Delta)^{s/2}f^{\ast}(x){\mid}^2dx{\leq}{\int}_{\mathbb{R}^n}{\mid}(-\Delta)^{s/2}f(x){\mid}^2dx$$.