• 제목/요약/키워드: Reactivity ratio

검색결과 251건 처리시간 0.022초

청정수소생산을 위한 에탄올 수증기개질반응 및 막반응기에서의 응용 (Ethanol Steam Reforming Reaction for a Clean Hydrogen Production and its Application in a Membrane Reactor)

  • 임한권
    • 청정기술
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    • 제19권4호
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    • pp.379-387
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    • 2013
  • 본 총설에서는 최근 청정수소생산방법으로 큰 관심을 받고 있는 에탄올 수증기개질반응(ethanol steam reforming reaction)에 대해 소개하고자 한다. 다양한 촉매, 반응온도, 에탄올과 물의 몰비에 따른 에탄올 수증기개질반응의 반응특성 및 반응속도식(reaction rate equation)을 검토해 보고자 한다. 또한, 반응기와 분리기를 동시에 장착한 새로운 개념의 막반응기(membrane reactor)를 소개하며, 막반응기의 사용이 일반적인 충전층반응기(packed-bed reactor)에 비해 에탄올 전환율과 수소 수율에 어떠한 영향을 주는지에 대하여 고찰해 보고자 한다.

Measurement of the Moderator Temperature Coefficient of Reactivity for Pressurized Water Reactors

  • Yu, Sung-Sik;Kim, Se-Chang;Na, Young-Whan;Kim, H. S.;J. Y. Doo;Kim, D. K.;S. W. Long
    • Nuclear Engineering and Technology
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    • 제29권6호
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    • pp.488-499
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    • 1997
  • The measurements of the moderator temperature coefficient (MTC) are performed to demonstrate that the calculational model produces results that are consistent with the measurements. Since negative MTC is also a technical specification value that may limit the cycle length, it is important to measure it as accurately as possible. In this report, preferred choice of test method depending on the time in cycle, best power indication and temperature definition in MTC calculation were determined based on the MTC test results taken during initial startup testing and at 2/3 cycle burnup in the Yonggwang nuclear power plant. The results show that the ratio and rodded methods provided good agreement with the predictions during initial startup testing. However, near end-of-cycle the depletion method gives better results, and so is suggested to be used in the MTC measurements at 2/3 cycle burnup. The use of primary Delta T power as a power indicator in the MTC calculations is highly advisable since it responds with good consistent results very quickly to changes unlike secondary calorimetric power. For the appropriate temperature definitions used in the MTC calculations, it is considered that the arithmetic average temperature measured simply by inlet and outlet thermocouples is preferred. Although volumetric average temperature provides better results, the improvement is not sufficient to compensate for the simplicity of calculations by arithmetic average temperature.

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A SENSITIVITY STUDY ON NEUTRONIC PROPERTIES OF DUPIC FUEL

  • Park, Hangbok;Roh, Gyu-Hog
    • 한국원자력학회:학술대회논문집
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    • 한국원자력학회 1998년도 춘계학술발표회논문집(1)
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    • pp.124-129
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    • 1998
  • A sensitivity study has been done to determine the composition of DUPIC fuel from the viewpoint of neutronics fuel design. The spent PWR fuel compositions were generated and fissile contents adjusted by blending fresh uranium after mixing two spent PWR fuel assemblies. The $^{239}$ Pu and $^{235}$ U enrichments of DUPIC fuel were adjusted by controlling the amount of fresh uranium feed and the ratio of slightly enriched and depleted uranium in the fled uranium. Based on the material balance calculation, it is recommended that DUPIC fuel composition be such that spent PWR fuel utilization is more than 90%.. A sensitivity study on the temperature reactivity coefficient of DUPIC fuel has shown that it is desirable to increase the $^{239}$ Pu and $^{235}$ U contents to reduce both the fuel and coolant temperature coefficients. On the other hand, refueling simulations of the DUPIC core have shown that the channel power peaking factor, which is a measure of the reactor trip margin, increases with the total fissile content. Considering these neutronic characteristics of the DUPIC fuel, il is recommended to have enrichments of 0.45 and 1.00 wt% for $^{239}$ Pu and $^{235}$ U, respectively.

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Characterization of a Neutron Beam Following Reconfiguration of the Neutron Radiography Reactor (NRAD) Core and Addition of New Fuel Elements

  • Craft, Aaron E.;Hilton, Bruce A.;Papaioannou, Glen C.
    • Nuclear Engineering and Technology
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    • 제48권1호
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    • pp.200-210
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    • 2016
  • The neutron radiography reactor (NRAD) is a 250 kW Mark-II Training, Research, Isotopes, General Atomics (TRIGA) reactor at Idaho National Laboratory, Idaho Falls, ID, USA. The East Radiography Station (ERS) is one of two neutron beams at the NRAD used for neutron radiography, which sits beneath a large hot cell and is primarily used for neutron radiography of highly radioactive objects. Additional fuel elements were added to the NRAD core in 2013 to increase the excess reactivity of the reactor, and may have changed some characteristics of the neutron beamline. This report discusses characterization of the neutron beamline following the addition of fuel to the NRAD. This work includes determination of the facility category according to the American Society for Testing and Materials (ASTM) standards, and also uses an array of gold foils to determine the neutron beam flux and evaluate the neutron beam profile. The NRAD ERS neutron beam is a Category I neutron radiography facility, the highest possible quality level according to the ASTM. Gold foil activation experiments show that the average neutron flux with length-to-diameter ratio (L/D) = 125 is $5.96{\times}10^6n/cm^2/s$ with a $2{\sigma}$ standard error of $2.90{\times}10^5n/cm^2/s$. The neutron beam profile can be considered flat for qualitative neutron radiographic evaluation purposes. However, the neutron beam profile should be taken into account for quantitative evaluation.

3성분계 포졸란재를 이용한 반응성 분체 콘크리트(RPC)의 고온특성 (The mechanical properties of Reactive Powder Concrete using Ternary Pozzolanic Materials exposed to high Temperature)

  • 장칩도르지;소형석;이제방;소승영
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2013년도 추계 학술논문 발표대회
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    • pp.68-71
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    • 2013
  • Reactive Powder Concrete (RPC) is an ultra high strength and high ductility cement-based composite material and has shown some promise as a new generation concrete in construction field. It is characterized by a silica fume-cement mixture with very low water-binder (w/b) ratio and very dense microstructure, which is formed using various powders such as cement, silica fume and very fine quartz sand (0.15~0.4mm) instead of ordinary coarse aggregate. However, the unit weight of cement in RPC is as high as 900~1,000 kg/㎥ due to the use of very fine sand instead of coarse aggregate, and a large volume of relatively expensive silica fume as a high reactivity pozzolan is also used, which is not produced in Korea and thus must be imported. Since the density of RPC has a heavy weight at 2.5~3.0 g/㎤. In this study, the modified RPC was made by the combination of ternary pozzolanic materials such as blast furnace slag and fly ash, silica fume in order to economically and practically feasible for Korea's situation. The fire resistance and structural behavior of the modified RPC exposed to high temperature were investigated.

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소음에 장기 노출되었을 때 나타나는 심리생리적 효과 (Effects of Long-term Exposure to Noise on Psychophysiological Responses)

  • Estate Sokhadze;Park, Sangsup;Lee, Kyung-Hwa;Kim, Yeon-Kyu;Sohn, Jin-Hun
    • 한국감성과학회:학술대회논문집
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    • 한국감성과학회 1999년도 추계학술대회 논문집
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    • pp.211-215
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    • 1999
  • It is well known that a long-term exposure to a loud noise environment affects performance, since it distracts attention, and also is able to evoke stress accompanied by negative emotional states. The purpose of this study was to analyze dynamics of subjective and physiological variables during long-lasting (30 min) exposure to intensive white noise (85 dB[A]). Physiological signals on 23 college students were recorded by BIOPAC, Grass Neurodata systems and AcqKnowledge 3.5 software. Autonomic variables, namely skin conductance level (SCL), non-specific SCR number (N-SCR), inter-beat intervals in ECG (RR intervals), heart rate variability index (HF/LF ratio of HRV), respiration rate (RESP), and skin temperature (SKT) were analyzed on 5 min epoch basis. Psychological assessment (subjective rating of stress level) was also repeated on every 5 min basis. Regression and correlation analyses were employed to trace the time course of the dynamics of the subjective and autonomic physiological variables and their relationship. Results showed that intense noise evokes subjective stress with associated autonomic nervous system responses. However, it was shown that physiological variables endure specific changes in the process of exposure to loud white noise. Discussed are probable psychophysiological mechanisms mediating reactivity to long-term auditory stimulation of high intensity.

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Study on Characteristic difference of Semiconductor Radiation Detectors fabricated with a wet coating process

  • Choi, Chi-Won;Cho, Sung-Ho;Yun, Min-Suk;Kang, Sang-Sik;Park, Ji-Koon;Nam, Sang-Hee
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.192-193
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    • 2006
  • The wet coating process could easily be made from large area film with printing paste mixed with semiconductor and binder material at room temperature. Semiconductor film fabricated about 25mm thickness was evaluated by field emissions-canning electron microscopy (FE-SEM). X-ray performance data such as dark current, sensitivity and signal to noise ratio (SNR) were evaluated. The $Hgl_2$ semiconductor was shown in much lower dark current than the others, but the best sensitivity. In this paper, reactivity and combination character of semiconductor and binder material that affect electrical and X-ray detection properties would prove out though experimental results.

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PC에 의한 열중성자로 중성자의 무작위 특성 측정 (PC-Based Random Neutron Process Measurement in a Thermal Reactor)

  • Jun, Byung-Jin;Park, Sang-Jun;Hong, Kwang-Pyo;Lee, Chung-Sung
    • Nuclear Engineering and Technology
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    • 제22권1호
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    • pp.58-65
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    • 1990
  • 열중성자로의 무작위 중성자 특성을 PC로써 측정하는 체계를 개발하고 이를 한국에너지연구소의 TRIGA Mark-II 원자로에 응용하였다. 그 결과 이 체계는 재래의 여러 방법에 비하여 많은 장점을 가지고 있음을 확인하였다. 아직은 한개의 계측기를 사용하였고, 즉발중성자만 고려한 시간 영역에 대하여 autocorrelation과 VTMR 두가지 방법으로 분석하였다. 두 방법의 결과는 서로 잘 일치하였으나 통계적인 신뢰도 면에서는 VTMR이 훨씬 나았고, 특히 임계 근처에서 이것이 두드러졌다. TRIGA Mark-II의 $\beta$/Λ 는 임계에서 -3$까지는 약 125/초, -4$이하에서는 약 150/초로 측정되었다.

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Neutronic study of utilization of discrete thorium-uranium fuel pins in CANDU-6 reactor

  • Deng, Nianbiao;Yu, Tao;Xie, Jinsen;Chen, Zhenping;Xie, Qin;Zhao, Pengcheng;Liu, Zijing;Zeng, Wenjie
    • Nuclear Engineering and Technology
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    • 제51권2호
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    • pp.377-383
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    • 2019
  • Targeting at simulating the application of thorium-uranium (TU) fuel in the CANDU-6 reactor, this paper analyzes the process using the code DRAGON/DONJON where the discrete TU fuel pins are applied in the CANDU-6 reactor under the time-average equilibrium refueling. The results show that the coolant void reactivity of the assembly analyzed in this paper is lower than that of 37-element bundle cell with natural uranium and 37-element bundle cell with mixed TU fuel pins; that the max time-average channel/bundle power of the core meets the limits - less than 6700kW/860 kW; that the fuel conversion ratio is higher than that of the CANDU-6 reactor with natural uranium; and that the exit burnup increases to 13400 MWd/tU. Thus, the simulation in this paper with the fuel in the 37-element bundle cell using discrete TU fuel pins can be considered to be applied in CANDU-6 reactor with adequate modifications of the core structure and operating modes.

보쉬 공정의 식각 메커니즘에 대한 전산모사 연구 (Simulation Study on the Etching Mechanism of the Bosch Process)

  • 김창규;문재승;이원종
    • 대한금속재료학회지
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    • 제49권10호
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    • pp.797-804
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    • 2011
  • In this study, the mechanisms of the three steps (the polymer deposition step, the polymer etching step and the Si etching step) that constitute the Bosch process were investigated. The effects of radicals and ions on each step were quantitatively analyzed by comparing the simulated aspect ratio dependency of the deposition or etch rate with the experimental results. In the polymer deposition step, fluorocarbon polymer is deposited by chemical reactions of $CF_x$ radicals, of which the reaction probability is 0.13. Although the polymer etching step and the Si etching step were conducted under the same conditions, the etching mechanisms of polymer and Si were found to be quite different. In the polymer etching step, both chemical etching and physical sputter-etching contribute to the polymer etching. Whereas, in the Si etching step, Si is chemically etched by F radicals, of which the reactivity is greatly increased by the bombardment of energetic ions.