• Title/Summary/Keyword: Reactive Fuel

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A CFD Study on Thermo-Acoustic Instability of Methane/Air Flames in Gas Turbine Combustor

  • Sohn, Chae-Hoon;Cho, Han-Chang
    • Journal of Mechanical Science and Technology
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    • v.19 no.9
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    • pp.1811-1820
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    • 2005
  • Thermo-acoustic instability of methane/ air flames in an industrial gas-turbine combustor is numerically investigated adopting CFD analysis. The combustor has 37 EV burners through which methane and air are mixed and then injected into the chamber. First, steady fuel! air mixing and flow characteristics established by the burner are investigated by numerical analysis with single burner. And then, based on information on the flow data, the burners are modeled numerically via equivalent swirlers, which facilitates the numerical analysis with the whole combustion system including the chamber and numerous burners. Finally, reactive flow fields within the chamber are investigated numerically by unsteady analysis and thereby, spontaneous instability is simulated. Based on the numerical results, scaling analysis is conducted to find out the instability mechanism in the combustor and the passive control method to suppress the instability is proposed and verified numerically.

Atomization Characteristics of a Double Impinging F-0-0-F Type Injector with Four Streams for Liquid Rockets

  • Kang, Shin-Jae;Rho, Byung-Joon;Oh, Je-Ha;Kwon, Ki-Chul
    • Journal of Mechanical Science and Technology
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    • v.14 no.4
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    • pp.466-476
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    • 2000
  • This paper presents atomization characteristics of a double impinging F -0-0- F type injector with four streams. A phase Doppler particle analyzer was employed to measure the droplet-size and water was used as the inert simulant liquid instead of reactive propellant liquids. The droplet mean diameter (SMD) and size distribution were measured to investigate the effects of the momentum ratio and pressure drop variations. This experimental results can be used during the preliminary design stage of a impinging stream type injector for liquid rockets.

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Power Output Control of Wind Generation System Through Energy Storage System and STATCOM (에너지저장장치 및 STATCOM을 이용한 풍력발전시스템의 출력제어 기법)

  • Kim, Jong-Yul;Park, June-Ho
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.10
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    • pp.1718-1726
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    • 2010
  • Utilization of renewable energy is becoming increaingly important from the viewpoints of environmental protection and conservation of fossil fuel. However, the generating power of renewable energy is always fluctuating due to the environmental status. This paper presents a scheme for supervisory control of wind generation system with the energy storage and STATCOM to reduce the power variation. In this paper, we especially concentrate on constant power output control of wind generation system. In order to achieve this purpose, the coordinated control strategy between different types of energy storage system and reactive power compensation device. The proposed control scheme has been validated by PSCAD/EMTDC simulation. As a result, the proposed scheme can handle the power output of wind generation system with a constant value.

Optimal Power Flow considering Security in Interconnected Power Systems (연계계통에서 안전도제약을 고려한 최적전력조류)

  • Kim, Kyu-Ho;Lee, Jae-Gyu;Rhee, Sang-Bong;You, Seok-Ku
    • Proceedings of the KIEE Conference
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    • 2001.07a
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    • pp.194-196
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    • 2001
  • This paper presents a hybrid algorithm for solving security constrained OPF in interconnected power systems, which is based on the combined application of evolutionary programming (EP) and sequential quadratic programming (SQP). The objective functions are the minimization of generation fuel costs and system power losses. In OPF considering security, the outages are selected by contingency ranking method. The control variables are the active power of the generating units, the voltage magnitude of the generator, transformer tap settings and SVC setting. The state variables are the bus voltage magnitude, the reactive power of the generating unit, line flows and the tie line flow. The method proposed is applied to the modified IEEE 14buses model system.

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A Study on the Modified Fenton Oxidation of MTBE in Groundwater with Permeable Reactive Barrier using Waste Zero-valent Iron (폐영가철 투수성반응벽체를 이용한 Modified Fenton 산화에 의한 MTBE 처리연구)

  • Moon, So-Young;Oh, Min-Ah;Lee, Jai-Young
    • Journal of Soil and Groundwater Environment
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    • v.17 no.2
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    • pp.15-21
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    • 2012
  • MTBE (Methyl tertiary-butyl ether) has been commonly used as an octane enhancer to replace tetraethyl lead in gasoline, because MTBE increases the efficiency of combustion and decreases the emission of carbon monoxide. However, MTBE has been found in groundwater from the fuel spills and leaks in the UST (Underground Storage Tank). Fenton's oxidation, an advanced oxidation catalyzed with ferrous iron, is successful in removing MTBE in groundwater. However, Fenton's oxidation requires the continuous addition of dissolved $Fe^{2+}$. Zero-valent iron is available as a source of catalytic ferrous iron of MFO (Modified Fenton's Oxidation) and has been studied for use in PRBs (Permeable Reactive Barriers) as a reactive material. Therefore, this study investigated the condition of optimization in MFO-PRBs using waste zero-valent iron (ZVI) with the waste steel scrap to treat MTBE contaminated groundwater. Batch tests were examined to find optimal molar ratio of MTBE : $H_2O_2$ on extent to degradation of MTBE in groundwater at pH 7 with 10% waste ZVI. As the results, the ratio of optimization of MTBE to hydrogen peroxide for MFO was determined to be 1:300[mM]. The column experiment was conducted to know applicability of MFO-PRBs for MTBE remediation in groundwater. As the results of column test, MTBE was removed 87% of the initial concentration during 120days of operational period. Interestingly, MTBE was degraded not only within waste ZVI column but also within sand column. It means the aquifer may affect continuously the MTBE contaminated groundwater after throughout the waste ZVI barrier. The residual products showed acetone, TBF (Tert-butyl formate) and TBA (Tert-butyl acetate) during this test. The results of the present study showed that the recycled materials can be effectively used for not only a source of catalytic ferrous iron but also a reactive material of the MFO-PRBs to remove MTBE in groundwater.

Experimental Ignition Delay Assessment of H2O2 Based Low Toxic Hypergolic Propellants with Variation of Reactive Additive Concentration (반응성 첨가제 농도에 따른 과산화수소 기반 저독성 접촉점화성 추진제의 점화지연 시험평가)

  • Rang, Seongmin;Kim, Kyu-Seop;Kwon, Sejin
    • Journal of Aerospace System Engineering
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    • v.14 no.3
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    • pp.24-31
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    • 2020
  • A study on the H2O2 based low toxic hypergolic propellant was conducted. The fuel candidates were chosen as a mixture of Amine solvent and reactive additive. The analytical performance was calculated via the NASA CEA code and 96% Isp of the NTO/UDMH was confirmed. The ignition delay measurement with drop test was performed and all candidates showed less than 10 ms in the best performance cases. Based on these results, the feasibility of high response H2O2 based low toxic hypergolic propellant was confirmed.

Characterization of CO2 Gasification of 17 Coals With Regard to Coal Rank (다양한 등급의 17종 석탄의 CO2 가스화 반응특성 연구)

  • Kim, Soohyun;Yoo, Jiho;Chun, Donghyuk;Lee, Sihyun;Rhee, Young Woo
    • Clean Technology
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    • v.19 no.3
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    • pp.333-341
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    • 2013
  • This paper presents results on $CO_2$ gasification of 17 raw coals containing a wide range of volatile matter (21-57 wt%). The gasification is performed using a TGA under $CO_2$ and also under $N_2$ atmosphere. An amount of weight loss with increasing temperature is proportional to that of volatile matter in a coal under $N_2$ atmosphere. Reactivity of $CO_2$ gasification also increases with a content of volatile matter. However, the correlation is a little scattered. Oxygenated functional groups in a coal are generally reactive and therefore, an increase in O/C ratio leads to enhanced reactivity. However, $CO_2$ reactivity is affected by neither H/C ratio nor a content of ashes that possibly activate the gasification reaction. These findings are also applicable to steam coal gasification and the reactivity series are confirmed in the test at a fixed bed reactor.

Electrode characteristics of $AB_2$ type hydrogen storage alloy modified by Cr, La addition and fluorination ($AB_2$계 수소저장합금의 전극특성에 미치는 Cr, La 첨가 효과 및 표면 불화처리 효과)

  • Chang I.;Lee B. H.;Cho W. I.;Jang H.;Cho B. W.;Yun K. S.
    • Journal of the Korean Electrochemical Society
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    • v.1 no.1
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    • pp.45-51
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    • 1998
  • [ $AB_2-type$ ] alloy, one kind of hydrogen storage alloys used as an anode of Ni-MH batteries, has large discharge capacity but has remaining problems regarding initial activation, cycle life and self-discharge. This study investigates the effects of Cr-addition and fluorination after La-addition on $Zr_{0.7}Ti_{0.3}V_{0.4}Mn_{0.4}Ni_{1.2}$, composition $AB_2-type$ alloy. EPMA and SEM surface analysis techniques were used and the crystal structure was characterized by XRD analysis. In addition, electrodes were fabricated out of the alloys and characterized by constant current cycling test, electrochemical impedance spectroscopy and potentiodynamic polarization. Cr-addition was found to be effective to cycle life and self-discharge but ineffective to initial activation due to formation of stable oxide film on surface. Fluorination after La-addition to the alloys improved initial activation remarkably due to formation of highly reactive particles on surface.

A Study of Correlation between Flame Propagation Velocity and Scalar Dissipation Rate for a Liftoff Flame (부상화염에서 화염전파속도와 스칼라소산율의 상호 관계에 관한 연구)

  • Ha, Ji-Soo;Kim, Tae-Kwon
    • Journal of the Korean Institute of Gas
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    • v.13 no.3
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    • pp.33-42
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    • 2009
  • A numerical analysis of reactive flow in a liftoff flame is accomplished to elucidate the characteristics of liftoff flame. To verify reliance of numerical calculation, the liftoff heights of liftoff flame for various fuel exit velocities are compared between the existing experimental research results and the present calculation results. The flame propagation velocity is conducted at the flow redirection point which is on a stoichiometric line ahead of flame front. This point was selected constant distance from triple point regardless of fuel exit velocity at the previous research. This causes considerable errors for the flame propagation velocity and scalar dissipation rate. The main issue of the present research is to establish the resonable method to select the redirection point and so that to clarify the relationship between flame propagation velocity and scalar dissipation rate, which is the core properties in a triple flame stability.

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LES Analysis on Combustion Characteristics of a Hydrogen/Methane Gas Turbine Combustor (LES 기법을 이용한 수소/메탄 가스터빈 연소기의 연소특성 분석)

  • Nam, Jaehyun;Lee, Younghun;Yoh, Jai-ick
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.48 no.8
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    • pp.589-595
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    • 2020
  • Large eddy simulation (LES) of a partially premixed gas turbine combustor is conducted. Four different hydrogen compositions are considered to investigate the fuel composition effects on the flow field inside the combustor. The comparison with the experimental flame structure and velocity profile is conducted to verify the LES results, revealing that the partially premixed flame structure is altered when hydrogen composition is changed. The flame structure becomes shorter and thicker as the hydrogen composition is increased, and therefore, the flame effect in the rigid wall is minimized. The change in the recirculation zone at the combustor wall with hydrogen addition is further investigated. Overall, the LES with combustion model is quite promising for accurately predicting the reactive flow characteristics in connection with the fuel composition.