• 한국재료학회지
• /
• 제9권6호
• /
• pp.551-555
• /
• 1999

The deposition condition to obtain stoichiometric $Ta_2$O\ulcorner films, which is still controversial, using magnetron reactive sputtering was studied. The films were deposited by varying $O_2$gas flow rate with sputtering power and Ar gas flow rate of 200W and 60 sccm fixed. At the conditions of $O_2$ gas flow rate over 20 sccm, amorphous Tantalum oxide films with the refractive index of 2.1 and dielectric constant of 25 were deposited. Among those films, the capacitors dielectric properties of the film deposited at the condition of $O_2$ gas flow rate 50 sccm was best, the leakage current was 1$\times$10\ulcornerA/$\textrm{cm}^2$ at the electric field strength of 0.5 MC/cm and the breakdown field strength was over 2.0 MV/cm. This result could be explained from the analysis comparing with a standard sample using RBS because the composition of the film deposited at this condition was closest to the stoichiometric $Ta_2$O\ulcorner. The result of XPS analysis convinced that this film was stoichiometric $Ta_2$O\ulcorner film. A maximum cathode voltage was observed when $O_2$gas flow rate was 30 sccm. This shows that the Schiller's proposition that one can obtain stoichiometric films at the condition of maximum cathode voltage is not correct and more oxygen than that of the maximum voltage condition is necessary to deposit the stoichiometric Ta$_2$O\ulcorner films.

• 한국자동차공학회논문집
• /
• 제5권3호
• /
• pp.171-171
• /
• 1997

Sound intensity distributions and energy flow in the near field of dipole source system and flat plate were investigated. First, the effectiveness of complex acoustic intensity was proved by using mathmatical and experimental methods in order to indentify noise sources and transmission paths of dipole field which is effected by the presence of neighbouring coherent sources. Next, analytical complex acoustic intensity method was discussed and the characteristics and energy flow of sound induced from the plate are clarified. The velocity of plate obtained from Finite Element Method was used for calculation of complex acoustic intensity in the near field. Finally experimental complex acoustic intensity method was applied to a passenger car. It can be seen that complex acoustic intensity method using both of active and reactive intensity is vital in devising a strategy for the identification and the reduction of vibration and noise.

• 한국자동차공학회논문집
• /
• 제5권3호
• /
• pp.159-171
• /
• 1997

Sound intensity distributions and energy flow in the near field of dipole source system and flat plate were investigated. First, the effectiveness of complex acoustic intensity was proved by using mathmatical and experimental methods in order to inden- tify noise sources and transmission paths of dipole field which is effected by the presence of neighbouring coherent sources. Next, analytical complex acoustic intensity method was discussed and the characteristics and energy flow of sound induced from the plate are clarified. The velocity of plate obtained from Finite Element Method was used for calculation of complex acoustic intensity in the near field. Finally experimental complex acoustic intensity method using both of active and reactive intensity is vital in devising a strategy for the identification and the reduction of vibration and noise.

• 대한화학회지
• /
• 제15권1호
• /
• pp.37-44
• /
• 1971

The reaction of amino acids and the reactive hydroxyl radical generated by $Ti^{3+}-H_2O_2$ system was studied using fast flow techniques coupled with ESR. Upon adding methionine to the 0.2M $H_2O_2$ solution (0.05M methionine after addition) and mixing with 0.01M $TiCl_3$, the low field component of the two incompletely resolved peaks, in the spectrum of $Ti^{3+}-H_2O_2$ system alone, vanished completely whereas the high field component remained almost constant and superimposed on the secondary spectrum of the methionine free radical. Similar results were obtained for other amino acids and proteins. The results strongly demonstrate that the $T^{3+}-H_2O_2$ flow system generates two different radical species, only one of which, giving rise to the low field component, is alone responsible for abstracting hydrogen atoms from substrate molecules. The effects of HCl, $H_2SO_4$ and NaOH on the system were also studied with widely varying results.

• Journal of Mechanical Science and Technology
• /
• 제18권8호
• /
• pp.1479-1489
• /
• 2004

The effect of fluctuation of Equivalence Ratio (ER) in a turbulent reactive field has been studied in order to check the global combustion characteristics induced by the local fluctuation. When the flow is premixed on a large scale, closer examination on a small scale reveals that local fluctuations of ER exist in an imperfectly premixed mixture, and that these fluctuations must be considered to correctly estimate the mean reaction rate. The fluctuation effect is analyzed with DNS by considering the joint PDF of reactive scalar and ER, followed by modeling study where an extension of stochastic mixing models accounting for the ER fluctuation is reviewed and tested. It was found that models prediction capability as well as its potential is in favor to this case accounting the local ER fluctuation. However, the effect of local fluctuation did not show any notable changes on the mean global characteristics of combustion when statistical independence between the reactive scalar and ER field is imposed, though it greatly influenced the joint PDF distribution. The importance of taking into account the statistical dependency between ER and combustible at the initial phase is demonstrated by testing the modeled reaction rate.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2013년도 제46회 KOSCO SYMPOSIUM 초록집
• /
• pp.123-126
• /
• 2013

Combustor development requires high fidelity simulation capable of predicting recirculation zone (RZ), temperature field, and pollutant emission. Swirling flow is widely used in combustor for its benefits in efficient mixing and flame stabilization by RZ. Large eddy simulation (LES) is used to calculate swirling flow in an expanding pipe [1], and shows higher accuracy than RANS. Reactive flow modeling using LES and flamelet model is validated with experiments by Barlow et al. [4] and Masri et al. [3]. Finally, heat transfer simulation of Samsung Techwin's combustor liner is presented.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 1998년도 제11회 학술강연회논문집
• /
• pp.13-13
• /
• 1998

램가속기의 발진 과정에서 유동장 내에는 수백 기압 이상의 고압 영역이 존재하며 이러한 영역에서는 이상기체 가정이 더 이상 유효하지 않게 된다. 따라서 램가속기 작동조건에 적용 가능한 적절한 형태의 실제 기체 상태 방정식이 요구된다 또한 기존의 온도에 종속적인 Arrhenius 형태의 기초 반응들로 이루어진 축소 화학 반응 모델은 상압 조건하에서 적용 가능하므로 고압 화경에서 적용하기 위해서는 온도뿐 아니라 압력에 종속적인 형태의 반응율 상수가 도입되어야 한다.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 2003년도 추계학술발표회
• /
• pp.168-171
• /
• 2003

This research was conducted to assess the performance of the mixed reactive materials with sand, iron filings, and HDTMA-bentonite for trichloroethylene (TCE) and chromate removal under controlled groundwater flow conditions. TCE and chromate removal rates with the mixtures of iron filing/HDTMA-bentonite were highest among four columns due to reduction by iron filings and sorption by HDTMA-bentonite. The greater capacity of the mixed iron filing/HDTMA-bentonite compared HDTMA-bentonite was due to an enhanced chromate reduction in addition to chromate sorption. The presence of chromate caused greater inhibition of TCE removal in the column with iron filings, while the presence of TCE caused less inhibition of TCE. Also, nitrate caused the decrease in TCE removal relative to chloride. Nitrate ions may also significantly affect TCE reduction rates by competing for electrons with the chlorinated compounds. The anion and co-existed contaminants competing effects should be considered when designed permeable reactive barriers (PRBs) composed of zero valent iron for field applications to remediate TCE and chromate.

• Nuclear Engineering and Technology
• /
• 제44권1호
• /
• pp.21-32
• /
• 2012

Fluorinated compounds mainly used in the semiconductor industry are potent greenhouse gases. Recently, thermal plasma gas scrubbers have been gradually replacing conventional burn-wet type gas scrubbers which are based on the combustion of fossil fuels because high conversion efficiency and control of byproduct generation are achievable in chemically reactive high temperature thermal plasma. Chemical equilibrium composition at high temperature and numerical analysis on a complex thermal flow in the thermal plasma decomposition system are used to predict the process of thermal decomposition of fluorinated gas. In order to increase economic feasibility of the thermal plasma decomposition process, increase of thermal efficiency of the plasma torch and enhancement of gas mixing between the thermal plasma jet and waste gas are discussed. In addition, noble thermal plasma systems to be applied in the thermal plasma gas treatment are introduced in the present paper.

• 한국소음진동공학회논문집
• /
• 제21권9호
• /
• pp.787-797
• /
• 2011

The noise in a vehicle is an important factor for customers purchasing a car. Particularly, reduction of the noise that is generated from HVAC(heating, ventilation and air conditioning) is very important since it has considerable effects on interior noise. In general, identification of noise source is crucial to reduce noise level. The complex acoustic intensity method is widely used to obtain the accurate measurement and identification of noise source. Therefore, in the previous study, noise source of HVAC was identified through experimental approach using the complex acoustic intensity method. In this study, we are intended to confirm reduced level of noise by comparing the result between before and after modification of cam curve that is based on identified noise source of HVAC. It is found out that noise source of HVAC are motor and cam area using the complex acoustic intensity method in the previous study. We performed experiments to compare noise level between before and after modification of cam curve. Especially, it can be seen that complex acoustic intensity method using both active and reactive intensity is vital in devising a strategy for comparison to noise level. Also, the vector flow of acoustic intensity was investigated to identify sound intensity distributions and energy flow in the near field of HVAC.