• 제목/요약/키워드: Reaction zone

검색결과 433건 처리시간 0.022초

고체산화물 연료전지용 연료.물 직접 분무식 촉매 개질기에 관한 실험적 연구 (An Experimental Study on Catalytic Reformer with Direct Spraying of Fuel and Water for SOFC)

  • 이대근;동상근;양제복;김학주;정헌
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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    • pp.260-265
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    • 2006
  • An experimental study on the catalytic reformer adopted in the auxiliary power unit system of solid oxide fuel cell was conducted. A 3-fluid nozzle, by which liquid fuel such as diesel, water and air are sprayed and uniformed mixed, was designed and used in this study. An electrically heated monolith inserted in the reformer was used for the vaporization of fuel and water in the transient state of reformer. The reformer uses the partial oxidizing reaction at the catalyst and the supply of water prevents the flame combustion in the spraying zone and lessens the deactivation of catalyst. The result showed that the reforming of liquid fuel can be started by the electrically heated monolith and the 3-fluid nozzle can give the uniform mixing of fuel, water and air. It was also found that the reformer fueled by n-hexadecane can make the reformate, at best, containing $H_2$ at 15.5% and CO at 11.5% that are used as fuel in the solid oxide fuel cell.

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Gas detonation cell width prediction model based on support vector regression

  • Yu, Jiyang;Hou, Bingxu;Lelyakin, Alexander;Xu, Zhanjie;Jordan, Thomas
    • Nuclear Engineering and Technology
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    • 제49권7호
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    • pp.1423-1430
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    • 2017
  • Detonation cell width is an important parameter in hydrogen explosion assessments. The experimental data on gas detonation are statistically analyzed to establish a universal method to numerically predict detonation cell widths. It is commonly understood that detonation cell width, ${\lambda}$, is highly correlated with the characteristic reaction zone width, ${\delta}$. Classical parametric regression methods were widely applied in earlier research to build an explicit semiempirical correlation for the ratio of ${\lambda}/{\delta}$. The obtained correlations formulate the dependency of the ratio ${\lambda}/{\delta}$ on a dimensionless effective chemical activation energy and a dimensionless temperature of the gas mixture. In this paper, support vector regression (SVR), which is based on nonparametric machine learning, is applied to achieve functions with better fitness to experimental data and more accurate predictions. Furthermore, a third parameter, dimensionless pressure, is considered as an additional independent variable. It is found that three-parameter SVR can significantly improve the performance of the fitting function. Meanwhile, SVR also provides better adaptability and the model functions can be easily renewed when experimental database is updated or new regression parameters are considered.

산소부화를 통한 화염온도 변화에 따른 연소합성된 TiO2 나노입자의 결정구조 변화 (Effect of Oxygen-Enriched Flame Temperature on the Crystalline Structures of the Flame-Synthesized TiO2 Nanoparticles)

  • 이교우
    • 대한기계학회논문집B
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    • 제30권7호
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    • pp.692-699
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    • 2006
  • In this work, $TiO_2$ nanoparticles were synthesized using $N_2-diluted$ and Oxygen-enriched co-flow hydrogen diffusion flames. The effect of flame temperature on the crystalline structure of the formed $TiO_2$ nanoparticles was investigated. The measured maximum centerline temperature of the flame ranged from 2,103k for oxygen-enriched flame to 1,339K for $N_2-diluted$ flame. The visible flame length and the height of the main reaction zone were characterized by direct photographs. The crystalline structures of $TiO_2$ nanoparticles were analyzed by XRD. From the XRD analysis, it was evident that the crystalline structures of the formed nanoparticles were divided into two sorts. In the higher temperature region, over the 1,700K, the fraction of formed $TiO_2$ nanoparticles having anatase-phase crystalline structure increased with increasing the flame temperature. On the contrary, in the lower temperature region, below the 1,600K, the fraction of anatase-phase nanoparticles increased with decreasing the flame temperature.

고온공기를 이용한 제트확산화염의 연소특성에 관한 실험 (Experiment on the Characteristics of Jet Diffusion Flames with High Temperature Air Combustion)

  • 조은성;대야건;소림수소;정석호
    • 대한기계학회논문집B
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    • 제28권3호
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    • pp.359-364
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    • 2004
  • For the development of high efficiency and low emission combustion systems, high temperature air combustion technology has been tested by utilizing preheated air over 1100 K and exhaust gas recirculation. In this system, combustion air is diluted with large amount of recirculated exhaust gases, such that the oxygen concentration is relatively low in the reaction zone, leading to low flame temperature. Since, the temperature fluctuations and sound emissions from the flame are small and flame luminosity is low, the combustion mode is expected to be flameless or mild combustion. Experiment was performed to investigate the turbulent flame structure and NO$_x$ emission characteristics in the high temperature air combustion focused on coflowing jet diffusion flames which has a fundamental structure of many practical combustion systems. The effect of turbulence has also been evaluated by installing perforated plate in the oxidizer inlet nozzle. LPG was used as a fuel. Results showed that even though NO$_x$ emission is sensitive to the combustion air temperature, the present high temperature air combustion system produce low NO$_x$ emission because it is operated in low oxygen concentration condition by the high exhaust gas recirculation.

연소실 압력 강하에 의한 고체 추진제의 동적 소화 (Dynamic Extinction of Solid Propellants by Depressurization of Combustion Chamber)

  • 정호걸;이창진
    • 한국항공우주학회지
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    • 제30권2호
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    • pp.91-97
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    • 2002
  • 응축영역 에너지 방정식과 기체 영역에 관한 화염모델을 사용하여 연소실 압력 강하에 반응하는 고체 추진제의 동적 소화 특성을 살펴보았다. 화염모델에서는 기체가 반응영역을 통과하는데 걸리는 시간(잔존시간, r,)이 동적 소화 특성을 결정하는 중요한 인자임을 확인하였다. 본 논문에서는 r,을 확산과 화학반응 시간의 다양한 조합으로 가정하였으며 이를 이용하여 동적 소화 특성을 살펴보았다. 또한 연소실 부피의 유한함에 따른 압력변화와 이에 대한 연소의 동적 반응도 살펴보았다. 동적 소화는 화학반응 시간보다는 확산 시간에 의하여 커다란 영향을 받는 현상임을 확인하였다. 그리고 연소실 부피가 유한한 경우가 무한한 경우보다 복잡한 동적 소화 특성을 보여주었다.

Numerical Modeling for the $H_2/CO$ Bluff-Body Stabilized Flames

  • Kim, Seong-Ku;Kim, Yong-Mo;Ahn, Kook-Young;Oh, Koon-Sup
    • Journal of Mechanical Science and Technology
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    • 제14권8호
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    • pp.879-890
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    • 2000
  • This study investigates the nonpremixed $H_2/CO$-air turbulent flames numerically. The turbulent combustion process is represented by a reaction progress variable model coupled with the presumed joint probability function. In the present study, the turbulent combustion model is applied to analyze the nonadiabatic flames by introducing additional variable in the transport equation of enthalpy and the radiative heat loss is calculated using a local, geometry independent model. Calculations are compared with experimental data in terms of temperature, and mass fraction of major species, radical, and NO. Numerical results indicate that the lower and higher fuel-jet velocity flames have the distinctly different flame structures and NO formation characteristics in the proximity of the outer core vortex zone. The present model correctly predicts the essential features of flame structure and the characteristics of NO formation in the bluff-body stabilized flames. The effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

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부상된 수소 난류확산화염의 화염구조 (Flame Structure of a Liftoff Non-Premixed Turbulent Hydrogen Jet with Coaxial Air)

  • 오정석;윤영빈
    • 대한기계학회논문집B
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    • 제33권9호
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    • pp.699-708
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    • 2009
  • To understand hydrogen jet liftoff height, the stabilization mechanism of turbulent lifted jet flames under non-premixed conditions was studied. The objectives were to determine flame stability mechanisms, to analyze coexistence of two different flame structure, and to characterize the lifted jet at the flame stabilization point. Hydrogen flow velocity varied from 100 to 300 m/s. Coaxial air velocity was changed from 12 to 20 m/s. Simultaneous velocity field and reaction zone measurements used, PIV/OH PLIF techniques with Nd:YAG lasers and CCD/ICCD cameras. Liftoff height decreased with the increase of fuel velocity. The flame stabilized in a lower velocity region next to the faster fuel jet due to the mixing effects of the coaxial air flow. The flame stabilization was related to turbulent intensity and strain rate assuming that combustion occurs where local flow velocity and turbulent flame propagation velocity are balanced. At the flame base, two different flame structures were found that was the partial premixed flames and premixed flame.

$Al_2O_3$ 세라믹의 미세구멍 가공시 가공조건과 보조가스가 미치는 영향 (The influence of processing condition and assistance gas in microhole machining of $Al_2O_3$ ceramics)

  • 이광길
    • 한국생산제조학회지
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    • 제8권5호
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    • pp.115-120
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    • 1999
  • This research is a described result of experimental for the parameter's effecting the microhole machining by Nd-Yag laser, The parameters are energy, pulse interval time a kin of assisting gas and its pressure. The result reveals that parameter value of energy 0.08J, pulse 20Hz, interval time of 300 microseconds could be a good machining condition to make upper microhoel that is the diameter range of 50-70${\mu}{\textrm}{m}$. At tat time the assistant gas such air, $O_2$, Ar $N_2$, was appelied. Assistant gas of air makes heat affected zone enlarge due to burning of material surface. Also it makes microhole irregular and damageable. Because of refusion caused by chemical reaction with $Al_2O_3$ ceramic material . The $O_2$(99.9%) has good characteristics to get good drilling and smooth surface on pressure of 0.2kgf/$\textrm{cm}^2$ but it is expensive. Ar, $N_2$ make material crack and burnning and proved that to be unappropriate but, Ar was a better than $N_2$.

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부정류 상태에서의 난지도 매립지 침출수 거동 예측 (The Behavior of Leachate on The Transient Condition in The Nanji Waste Landfill)

  • 강동희;조원철;이재영
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제6권2호
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    • pp.57-67
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    • 2001
  • 본 연구는 난지도 매립지에서 기반암 및 풍화대층을 통해서 거동하는 침출수의 속도와 침출수량을 부정류 상태에서 예측하기 위해 실시되었다. 본 연구에서는 3차원 지하수 거동 모델인 MODFLOW와 지하수에 용해되어 있는 오염물질의 확산, 분산, 화학반응 등을 해석할 수 있는 MT3D를 이용하여 안정화 공사 이후 부정류 상태에서 침출수 거동을 해석하였다. 침출수 발생량은 최근 10년간의 기상자료를 이용해서 HELP모델로 산출하였다. 침출수 거동은 차수벽, 차수층 설치 전,후의 침출수위 변화에 의해 예측되었다.

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부상된 수소난류확산화염에서 동축공기의 음향가진에 의한 NOx 저감 (NOx Reduction by Acoustic Excitation on Coaxial Air Stream in Lifted Turbulent Hydrogen Non-Premixed Flame)

  • 허필원;오정석;윤영빈
    • 한국연소학회지
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    • 제14권1호
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    • pp.31-38
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    • 2009
  • The effects of acoustic excitation of coaxial air on mixing enhancement and reduction of nitrogen oxides (NOx) emission were investigated. A compression driver was attached to the coaxial air supply tube to impose excitation. Measurements of NOx emission with frequency sweeping were performed to observe the trend of NOx emission according to the fuel and air flow conditions and to inquire about the effective excitation frequency for reducing NOx. Then, Schlieren photographs were taken to visualize the flow field and to study the effect of excitation. In addition, phase-locked particle image velocimetry (PIV) was performed to acquire velocity field for each case and to investigate the effect of vortices more clearly. Direct photographs and OH chemiluminescence photographs were taken to study the variation of flame length and reaction zone. It was found that acoustic forcing frequencies close to the resonance frequencies of coaxial air supply tube could reduce NOx emission. This NOx reduction was influenced by mixing enhancement due to large-scale vortices formed by fluctuation of coaxial air jet velocity.

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