• 제목/요약/키워드: Reaction system

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우주추진용 모노메틸하이드라진 반응에 대한 주요 해외연구 동향 조사 Part II : 모노메틸하이드라진-사산화이질소의 화학반응 (A Review on Major Foreign Research Trend of Monomethylhydrazine Reaction for Space Propulsion Part II : Chemical Reaction of Monomethylhydrazine-Dinitrogen Tetroxide)

  • 장요한;이균호
    • 항공우주시스템공학회지
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    • 제10권1호
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    • pp.74-81
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    • 2016
  • Space propulsion system produces required thrust for satellites and space launch vehicles by using chemical reactions of a liquid fuel and a liquid oxidizer typically. Among several liquid propellants, the monomethylhydrazine-dinitrogen tetroxide is expecially preferred for a GEO satellite propellants due to their better storability in liquid phase during a long mission life under a freezing space environment. Recently, a development of the monomethylhydrazine-dinitrogen tetroxide bipropellant system becomes important as the national space program requires the heavier and the more efficient space system. Thus, the objective of the present study is to review a foreign research trend of a chemical reaction between the monomethyhydrazine fuel and the dinitrogen tetroxide oxidizer to understand a fundamental basis of their characteristics to prepare for domestic development in future.

시금치에서 분이한 엽록체의 인산대사에 관한 연구 (A Study on Phosphate Metabolism of Chloroplast Isolated from Spinach)

  • 이종삼
    • Journal of Plant Biology
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    • 제19권3호
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    • pp.71-84
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    • 1976
  • In order to observe the phosphate metabolism in chloroplast, the contents of inorganic phosphate and various compounds in chloroplast from spinach leaf tissues were investigated during the reaction in the light and dark in the reaction mixture and the turnover of phosphate in chloroplast was compared with that of whole cell system: 1. The phosphorus of DNA in chloroplast appears to be transferred from inorganic phosphate, while in whole cell system from phosphate pool. 2. $^{32}P-phosphate$ content of acid soluble fraction in chloroplast as well as in whole cell system was more increased in the light than dark during the reaction. It was noted to be caused by the stimulation of sugar phosphate synthesis in the light. 3. It was confirmed that polyphosphate exists in chloroplast as well as whole cell. Acid insoluble polyphosphate content in whole cell system was significantly decreased during the reaction and the similar tendency was also observed in chloroplst. It is, therefore, considered that acid insoluble polyphosphate also play an most important role as a phosphate pool respectively in chloroplast and in cytoplasm. 4. Protein and lipid phosphorus in chloroplast as well as whole cell system were transferred from acid insoluble polyphosphate.

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Accurate Analysis of Chromium in Foodstuffs by Using Inductively Coupled Plasma Mass Spectrometry with a Collision-Reaction Interface

  • Lee, Seung Ha;Kim, Ji Ae;Choi, Seung Hyeon;Kim, Young Soon;Choi, Dal Woong
    • Bulletin of the Korean Chemical Society
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    • 제34권6호
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    • pp.1689-1692
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    • 2013
  • Food is a common source of chromium (Cr) exposure. However, it is difficult to analyze Cr in complex food matrices by using inductively coupled plasma mass spectrometry (ICP-MS) because the major isotope, $^{52}Cr$, is masked by interference generated by the sample matrix and the plasma gas. Among the systems available to minimize interference, the recently developed collision-reaction interface (CRI) has a different structure relative to that of other systems (e.g., collision cell technology, octopole reaction system, and dynamic reaction cell) that were designed as a chamber between the skimmer cone and quadrupole. The CRI system introduces collision or reaction gas directly into the plasma region through a modified hole of skimmer cone. We evaluated the use of an CRI ICP-MS system to minimize polyatomic interference of $^{52}Cr$ and $^{53}Cr$ in various foodstuffs. The $^{52}Cr$ concentrations measured in the standard mode were 2-3 times higher than the certified values. This analytical method based on an ICP-MS system equipped with a CRI of helium gas was effective for Cr analysis in complex food matrices.

Generation of Sesame Flavor by the Thermal Reaction Technique

  • Yoo, Seung-Seok
    • Food Science and Biotechnology
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    • 제16권1호
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    • pp.110-115
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    • 2007
  • In this study we investigated the volatile compounds that are generated in sesame and contribute to its characteristic flavor. Different reaction systems were used to examine how certain amino acids influenced flavor profiles, and also to evaluate the effects of sugar types on the distribution of those volatile compounds. The volatiles that were generated in each reaction system were selectively isolated and analyzed by gas chromatography and gas chromatography-mass spectrometry, respectively. Among the 20 identified compounds, nitrogen-containing alkylpyrazines were found to be the predominant volatiles. The alkylpyrazine amounts varied across the different model systems, with the total yield being highest in the arginine reaction mixture, followed by the alanine, serine, and lysine mixtures. In general, fructose generated the most extensive amount of volatiles compared to glucose and sucrose. However, the yield of specific flavor compounds varied according to the type of sugar used. Finally, the results clearly showed that a reaction temperature of $135^{\circ}C$ and a reaction time of 20 min generated the highest amount of volatile compounds.

Spatial Symmetry Breaking in the Revival Wave of the Belousov-Zhabotinsky Reaction Containing 1,4-Cyclohexanedione

  • Basavaraja, C.;Kim, Na-Ri;Park, Hyun-Tae;Huh, Do-Sung
    • Bulletin of the Korean Chemical Society
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    • 제30권4호
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    • pp.907-912
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    • 2009
  • Complex breakup behavior in the revival wave has been observed in the Belousov-Zhabotinsky(BZ) reaction system containing 1,4-cyclohexanedione (1,4-CHD) in the dish divided into two compartments with a sliding window. A same reaction mixture is poured into the two compartments individually with time difference. Wave propagation exhibited different behavior in the revival wave of the reaction system. This was largely dependent on the progress time prior to the pouring into each compartment and on the gap between the times of pouring into the two compartments. The revival wave in the reaction system is induced spontaneously as a new wave train with a long time lag after the disappearance of the initially induced wave. A thoroughgoing study of the chaotic breakup of propagating chemical wave train was to be possible since the revival wave has a longer wavelength, clearer wave-train patterns, and longer duration period.

강제동요시 OWC형 파력발전 공기챔버의 공기반력 실험연구 (A Study of Pneumatic Reaction Force of Air Chamber for an OWC Type Wave Energy Device by Forced Heave Experiments)

  • 홍석원;최학선;류재문;김진하
    • 한국해양공학회지
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    • 제19권3호
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    • pp.11-17
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    • 2005
  • The effect of frequency and amplitude of the OWC (Oscillating Water Column) motion on the nonlinear reaction forces in an air duct are studied experimentally. Experimental owe model is idealized as a simple circular cylinder with an orifice type air duct located at the middle oj the top rid. Reaction forces due to forced heave oscillation are measured and analyzed. By subtracting the effect of inertia forces and restoring forces, pneumatic damping force and added spring force are deduced. The effects of the frequency and amplitude of the heave motion are discussed. Also, the effects of solidity of the duct on the reaction forces are discussed.

강제동용시 OWC형 파력발전 공기챔버의 공기반력 실험연구 (A Study of Pneumatic Reaction Force of Air Chamber for an OWC type Wave Energy Device by Forced Heave Experiments)

  • 최학선;류재문;홍석원;김진하
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2004년도 학술대회지
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    • pp.212-219
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    • 2004
  • The effect of frequency and amplitude of the OWC (Oscillating Water Column) motion on the nonlinear reaction forces in an air duct arc studied experimentally. Experimental OWC model is idealized as a simple circular cylinder with an orifice type air duct located at the middle of the top rid. Reaction forces due to forced heave oscillation are measured and analyzed. By subtracting the effect of inertia forces and restoring forces, pneumatic damping force and added spring force are deduced. The effects of the frequency and amplitude of the heave motion are discussed. Also, the effects of solidity of the duct on the reaction forces are discussed.

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Preconcentration and Detection of Herbicides in Water by Using the On-line SPE-HPLC System and Photochemical Reaction

  • 이승호;이성광;박영훈;김현주;이대운
    • Bulletin of the Korean Chemical Society
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    • 제20권10호
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    • pp.1165-1171
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    • 1999
  • The analysis of trace herbicides using the on-line SPE-HPLC system and a photochemical reaction was studied. 18 compounds of herbicides including eight triazines, six phenoxy acids and esters, and four other herbicides were examined. The on-line SPE-HPLC system developed for selection of eluting solvent improved chromatographic efficiency. The recoveries of herbicides were higher than 77%. With 100 mL tap water samples, the detection limits for all analytes were in the 0.1-2.3×10-10 M range. Detection was done by a UV or fluorescence spectrometer after photochemical reaction at the end of the column with 2W or 450W mercury lamp. Without a photochemical reaction, all compounds responded to 230 nm UV detector, but phenoxy acids and esters were weakly detected. However, with a photochemical reaction, these compounds were selectively detected at 320 nm wavelength of UV absorption and 400 nm emission of the fluorescence detectors. This method can be used for the analysis of environmental water containing herbicides at trace levels.

한국형발사체 추력기 자세제어시스템 비행 중 추진제 소모량 추정식 (Propellant Consumption Estimation of Reaction Control System During Flight of KSLV-II)

  • 강신재;오상관;윤원재;민병주
    • 한국항공우주학회지
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    • 제48권7호
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    • pp.529-536
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    • 2020
  • 한국형발사체 3단은 추력기 자세제어시스템에 의해 3단 엔진 점화 시점부터 위성 분리, 위성과 충돌을 막기 위한 회피기동까지 롤 및 3축 자세제어가 수행된다. 추력기 자세제어시스템은 추력기를 작동시킬 때 추진제를 소모하므로, 적정 추진제 충전은 임무 성공에 있어 중요하다. 그러므로 한국형발사체의 비행 중 추력기 자세제어시스템의 추진제 소모량이 얼마인지 추정할 수 있는 수단이 필요하다. 본 연구에서는 추력기 자세제어시스템에서 획득할 수 있는 압력, 온도 데이터를 바탕으로 추진제 소모량을 추정할 수 있는 에너지 관계식을 개발하였다. 개발된 관계식을 검증하기 위해 On-board 시스템과 유사한 시스템을 구성하여 시험을 했고, 추진제 소모량 추정식과 증류수를 사용한 시험 결과를 비교분석하였다. 또한 오차 분석을 통해 예측 결과의 신뢰성을 판단하였다. 마지막으로 시스템 수준 운용시험의 추진제 소모 결과도 나타내었다.

풍력용 동기발전기의 전기자 반작용을 이용한 전기 제동방식에 관한 연구 (A study on electronic braking system using wind power synchronous generator's armature reaction)

  • 박귀열;문채주;정의헌;장영학;김의선
    • 한국태양에너지학회 논문집
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    • 제30권4호
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    • pp.1-8
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    • 2010
  • The mechanical parts of small windp ower generator less than 10kW are manufactured in the form of removing most of the accelerators. The braking system to protect blade from damages caused by high wind speed is manufactured in a manner having apparatus system(furling), manual brake or no brake. This study is on braking system in small size wind power generator, and carried out survey as following steps by applying electric braking system which uses armature reaction. We explained the principle of electric braking system and the principle of existing braking system. Also, this paper interpreted short circuit current through open circuit and short circuit, as well as checking brake system's action using armature reaction with real construction of control device.