• 제목/요약/키워드: Reaction system

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Novel Heterogeneous Carbohydrase Reaction Systems for the Direct Conversion of Insoluble Carbohydrates: Reaction Characteristics and their Applications

  • Lee, Yong-Hyun;Park, Dong-Chan
    • Journal of Microbiology and Biotechnology
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    • 제9권1호
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    • pp.1-8
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    • 1999
  • Most carbohydrates exist in nature in an insoluble state, which reduces their susceptibility towards various carbohydrases. Accordingly, they require intensive pretreatment for structural modification to enhance an enzyme reaction. The direct conversion of insoluble carbohydrates has distinct advantages for special types of reaction, especially exo-type carbohydrase; however, its application is limited due to structural constraints. This paper introduces two novel heterogeneous enzyme reaction systems for direct conversion of insoluble carbohydrates; one is an attrition coupled enzyme reaction system containing attrition-milling media for enhancing the enzyme reaction, and the other is a heterogeneous enzyme reaction system using extruded starch as an insoluble substrate. The direct conversion of typically insoluble carbohydrates, including cellulose, starch, and chitin with their corresponding carbohydrases, including cellulase, amylase, chitinase, and cyclodextrin glucanotransferase, was carried out using two proposed enzyme reaction systems. The conceptual features of the systems, their reaction characteristics and mechanism, and the industrial applications of the various carbohydrates are analyzed in this review.

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Colloidal Silica와 Methyltrimethoxysilane간의 졸겔반응으로 합성된 코팅제 특성 연구 (Properties of Sol-gel Coating Materials Synthesized from Colloidal Silicas and Methyltrimethoxysilane)

  • 강동필;박효열;안명상;이태희;명인혜;강귀태
    • 한국전기전자재료학회논문지
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    • 제17권9호
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    • pp.967-972
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    • 2004
  • Hardness and surface property of coated gel materials are considerably different according to kinds(particle size/stabilized ion) of colloidal silica(CS), kinds of silanes, content ratio of silane versus CS, and reaction degree in sol solution. We report the properties of sol-gel coating materials in which the factors of reaction are kinds of CS, contents ratio of CS and MTMS, and reaction time of sol. The contact angles of the coated films obtained from the mixed CS system showed a little good relationship with MTMS content increase to those from HSA CS reaction system and the change of contact angle didn't have much effect on reaction time of sol. In the coating films obtained from HSA CS reaction system, the surface was much rough in case of that the content MTMS decreased and the reaction of sol kept long. The surface roughness of films obtained from the mixed CS reaction system showed similar tendency, though its degree was a little different. In synthesis of sol-gel coating materials, we could identify that choice of CS kinds and content ratio of CS and silane were important and it was desirable the reaction time of sol is not long.

The Comparison of the Bead Size Effect on the Two Wave Patterns Induced in One Reaction System

  • 허도성;김민석;조상준
    • Bulletin of the Korean Chemical Society
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    • 제22권8호
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    • pp.867-871
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    • 2001
  • We have studied the characteristic wave propagation in 1,4-CHD-Bromate-Ferroin reaction system and we have examined the bead size effect on the wave propagation of the system by adopting a half-divided Petri dish which is separated into two parts by the size of cation-exchange resin. It has been done to understand the reaction process inducing the characteristic wave behavior in the system. The characteristic wave behavior of the system is in the spontaneous induction of a revival wave with a long time lag. We have obtained a result that the revival wave is not affected by the size of catalyst-doped beads while the initially induced wave is influenced by the size of beads. It means that the two waves are induced by different reaction processes each other and the revival wave is induced by an uncatalyzed reaction process.

분쇄마찰매체 불균일상 효소반응계를 활용한 생전분을 당공여체로 하는 Cyclodextrin Glucanotransferase의 당전이 반응 (Transglycosylation Reaction of Cyclodextrin Glucanotransferase in the Attrition Coupled Reaction System using Raw Starch as a Donor)

  • 이용현;백승걸;박동찬;신현동
    • 한국미생물·생명공학회지
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    • 제21권5호
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    • pp.461-467
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    • 1993
  • Transglycosylation reaction of cyclodextrin glucanotransferase (CGTase) was analyzed in the attrition coupled heterogeneous reaction system using raw starch as a donor` and mono-, di-saccharide, and glycoside as acceptors. For transglycosylation reaction of stevioside, the transglycosylation rate was similar and the transglycosylation yield was increased compare with conventional process using liquefied starch as the donor. Also the accumulation of maltooligosaccharides in reaction mixture was minimized.

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ROBUST BOUNDARY CONTROL OF CHEMOTAXIS REACTION DIFFUSION SYSTEM

  • Ryu, Sang-Uk;Kang, Yong Han
    • Korean Journal of Mathematics
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    • 제16권4호
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    • pp.457-470
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    • 2008
  • This paper is concerned with the robust boundary control of the chemotaxis reaction diffusion system. That is, we show that the existence of the saddle point for the robust control problem when the control and the disturbance are given by the boundary condition.

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연구과제 평가에 대한 과제책임자의 반응과 그 영향요인에 관한 연구 (A Study on the Project Manager's Reaction to R&D Evaluation and Its Influencing Factors)

  • 김인철;한도희
    • 기술혁신학회지
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    • 제3권2호
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    • pp.48-60
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    • 2000
  • An effort has been made in this paper to measure the project manager's reaction to R&D project evaluation and present the useful information related to rebuilding an R&D evaluation system. Results of this study show that project manager's reaction is related to the selection of reasonable items for evaluation, the rater's expertise, the project manager's participation in evaluation process and so on. Accordingly, managers of the research institute have to set up the evaluation system after deeply considering these results.

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AN ERROR ESTIMATION FOR MOMENT CLOSURE APPROXIMATION OF CHEMICAL REACTION SYSTEMS

  • KIM, KYEONG-HUN;LEE, CHANG HYEONG
    • Journal of the Korean Society for Industrial and Applied Mathematics
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    • 제21권4호
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    • pp.215-224
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    • 2017
  • The moment closure method is an approximation method to compute the moments for stochastic models of chemical reaction systems. In this paper, we develop an analytic estimation of errors generated from the approximation of an infinite system of differential equations into a finite system truncated by the moment closure method. As an example, we apply the result to an essential bimolecular reaction system, the dimerization model.

모델시스템에 있어서 무지개 송어 지방질의 산화에 대한 Lipoxygenase의 영향 (Effect of Lipoxygenase on the Oxidation of Rainbow Trout Lipid in Model system)

  • 김혜경;엄수현;최홍식
    • 생명과학회지
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    • 제5권2호
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    • pp.70-75
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    • 1995
  • The effect of lipoxygenase (LOX) on the oxidation and co-oxidation of lipid fraction was studied in the model system of rainbow trout. For the reaction in model system 1 g of lipid fraction and 50mL of enzyme extract(LOX, 140 unit in 50mL phosphate buffer solution at pH 7, 4)), which were obtained from rainbow trout, were homoginized in the presence of Tween 20 and kept at 23$\circ$C for 3 days. The activity of LOX was decreased to 43% of initial level during the reaction in the model system. The initial composition of rainbow trout lipid was showed to be consisted of trigliceride(TG;82%) and free fatty acid(FFA;0.1%), while this converted to 59% of TG and 20% of FIFA, respectively after reaction in model system. Change of fatty acid composition was also observed and the content of linoleic acid, one of the major fatte acids, was decreased to 13% from 54% in the content of total fatty acids after reaction. The carotenoids in rainbow trout were composed of 0.4% $\alpha$-carotene, 1.6% $\beta$ -carotene, 80% canthaxanthin, 7% lutein and 11% zeaxanthin, thus the canthaxanthin was the major component. This canthaxanthin was the most degraded carotenoid by lipoxygenase catalyzed co-oxidation during the reaction. On the other hand the tocopherol isomers found in the rainbow trout were $\alpha$ and $\beta$ -tocopherol, and $\alpha$-tocopherol had a higher degradation rate by the lipoxygenase catalyzed co-oxidation than of $\beta$-tocopherol in the reaction of model system.

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동특성을 고려한 스프레더용 충격흡수기의 시스템 변화에 따른 최적설계 (The Optimum Design according to System Variation of Impact Absorbing System for Spreader Considering Dynamic Characteristic)

  • 안찬우;홍도관;김동영;한근조
    • 한국정밀공학회지
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    • 제20권6호
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    • pp.230-237
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    • 2003
  • On this study, we operated the dynamic response for impact load of impact absorbing system for spreader by the finite element analysis and showed respectively the spring constant and the damping coefficient which the reaction force by impact was the lowest value for three types impact absorbing system according to the change of system, also we presented the change of impact reaction force according to the spring constant and the damping coefficient. Additionally, among the three types impact absorbing system according to the change of system, the reaction force of model II was the lowest value and the next model which has higher value than model II was model Iand model III has the highest value in the three types.