• 제목/요약/키워드: Reaction rates

검색결과 1,362건 처리시간 0.032초

SiOC 절연박막 특성에 의존하는 ITO 투명박막의 전기적인 특성과 오믹접합의 효과 (Ohmic Contact Effect and Electrical Characteristics of ITO Thin Film Depending on SiOC Insulator)

  • 오데레사
    • 한국재료학회지
    • /
    • 제25권7호
    • /
    • pp.352-357
    • /
    • 2015
  • To research the characteristics of ITO film depending on a polarity of SiOC, specimens of ITO/SiOC/glass with metal-insulator-substrates (MIS) were prepared using a sputtering system. SiOC film with 17 sccm of oxygen flow rate became a non-polarity with low surface energy. The PL spectra of the ITO films deposited with various argon flow rates on SiOC film as non-polarity were found to lead to similar formations. However, the PL spectra of ITO deposited with various argon flow rates on SiOC with polarity were seen to have various features owing to the chemical reaction between ITO and the polar sites of SiOC. Most ITO/SiOC films non-linearly showed the Schottky contacts and current increased. But the ITO/SiOC film with a low current demonstrated an Ohmic contact.

BTMSM/$O_2$ 고유량으로 증착된 low-k SiOCH 박막의 전기적인 특성 (Electrical characteristics of low-k SiOCH thin film deposited by BTMSM/$O_2$ high flow rates)

  • 김민석;황창수;김홍배
    • 반도체디스플레이기술학회지
    • /
    • 제7권1호
    • /
    • pp.41-45
    • /
    • 2008
  • We studied the electrical characteristics of low-k SiOCR interlayer dielectric(ILD) films fabricated by plasma enhanced chemical vapor deposition (PECVD). The precursor bis-trimethylsilylmethane (BTMSM) was introduced into the reaction chamber with the various flow rates. The absorption intensities of Si-O-$CH_x$, bonding group and Si-$CH_x$, bonding group changed synchronously for the variation of precursor flow rate, but the intensity of Si-O-Si(C) responded asynchronously with the $CH_x$, combined bonds. The SiOCH films revealed ultra low dielectric constant around 2.1(1) and reduced further below 2.0 by heat treatments.

  • PDF

다양한 종류의 연소로 내 고체 연료의 연소 특성 고찰 (Investigation of Solid Fuel Combustion Characteristics in Various Types of Combustors)

  • 최진환;양원;이상득;최상민
    • 한국연소학회지
    • /
    • 제9권3호
    • /
    • pp.1-9
    • /
    • 2004
  • This study is aimed to characterize the combustion behavior of solid fuel in the various types of the combustors: stoker, rotary kiln and fluidized bed type combustors. Three different types of reduced-scale combustors are introduced, and temperatures and flue gas compositions are measured for various fuel sizes, water contents, initial temperature, and air flow rates. In case of the rotary kiln combustor, effects of rotating speed of the combustor are also investigated. Mean carbon conversion time (MCCT) and flame propagation rate (FPR) are used for the quantitative analysis. It is revealed that the reaction rates of the fuel are significantly influenced by the fuel characteristics, type of the combustors and air flow rate. Major design parameters for each type of the combustors are summarized through the reduced-scaled model analysis.

  • PDF

CHARACTERISTICS OF BIOHYDROGEN PRODUCTION AND MICROBIAL COMMUNITY AS A FUNCTION OF SUBSTRATE CONCENTRATION

  • Youn, Jong-Ho;Shin, Hang-Sik
    • Environmental Engineering Research
    • /
    • 제10권1호
    • /
    • pp.7-14
    • /
    • 2005
  • The feasibility of hydrogen production with a raw seed sludge through direct acclimation of feedstock was investigated at acidogenic stage, and methane was harvested at followed methanogenic stage in an anaerobic two-stage process. Hydrogen content was higher than 57% at all tested organic loading rates (OLRs) and the yield of hydrogen ranged from 1.5 to 2.4 mol H2/mol hexose consumed and peaked at 6 gVSl-1day-1. Normal butyrate and acetate were main volatile fatty acids (VFAs), whereas the concentration of propionate was insignificant. The hydrogen-producing bacteria, Clostridium thermosaccharolyticum, was detected with strong intensity at all tested organic loading rates (OLRs) by denaturing gradient gel electrophoresis (DGGE) of the polymerase chain reaction (PCR) analysis. From COD balance in the process, the fraction of the feed-COD converted to the hydrogen-COD at acidogenic stage ranged from 7.9% to 9.3% and peaked at 6 gVSl-1day-1, whereas the fraction of feed-COD converted to the methane-COD at methanogenic stage ranged from 66.2% to 72.3% and peaked at 3 gVSl-1day-1.

효소면역흡착법을 이용한 대구지역의 돼지폐렴에 대한 항체분포조사 연구 (Survey on the antibody distributions of swine pneumonia by ELISA in Daegu province)

  • 조유정;서동균;송동준;이춘식;배영찬
    • 한국동물위생학회지
    • /
    • 제25권3호
    • /
    • pp.237-243
    • /
    • 2002
  • The study was performed to investigate the antibody distributions of 4 swine respiratory disease including M hyopneumoniae, P multocida, A pleuropneumoniae serotype 2 and 5 in Daegu area by enzyme-linked immunosorbent assay(ELISA). 1. The overall sero-positive rates were 55.6% in June, 48.0% in August, 51.3% in October and 25.4% in November. 2. The positive reaction rates to M hyopneumoniae, P multocida, A pleuropneumoniae serotype 2 and 5 were found to be 50.0%, 36.5%, 55.0%, and 42.0% respectively. 3. The antibody titers were distributed on range 20~80 in M hyopneumoniae, 20~80 in P multocida, 160~640, 20~80 in A pleuropneumoniae serotype 2 and 5.

Rhodium(I) Complexes of 1,1$^\prime$-Bis(diphenylphosphino)-ferrocene as Efficient Catalysts in Regioselective Hydrogenation of Polynuclear Heteroaromatic Compounds

  • Kim, Tae-Jeong;Lee, Kyu-Chul
    • Bulletin of the Korean Chemical Society
    • /
    • 제10권3호
    • /
    • pp.279-282
    • /
    • 1989
  • Two rhodium(I) complexes of the types [Rh(BPPF)(NBD)]$ClO_4$ (10) and [Rh(BPPF)$Cl]_2$ (11) (BPPF = 1,1'-bis(diphenylphosphino)-ferrocene) have been prepared and investigated as catalysts for the regioselective hydrogenation of polynuclear heteroaromatic nitrogen and sulfur compounds such as quinoline (1), acridine (2), phenanthridine (3), 7,8-benzoquinoline (4), benzothiophene (5), isoquinoline (6), indole (7), pyridine (8), and thiophene (9). Both complexes 10 and 11, except for the cases of indole (7) and mononuclear heteroaromatics 8-9, are very efficient in the selective reduction under quite mild hydrogenation conditions to give the corresponding saturated nitrogen and sulfur heterocyclic analogues of 1-6 in fast conversion rates and in excellent yields. Relative rate studies revealed that the reduction depends significantly on the steric and electronic effects of the substrates. Of the two complexes 10-11, the dimeric species 11 gives faster reaction rates in all cases studied.

Effect of Flashing Light on Oxygen Production Rates in High-Density Algal Cultures

  • Park, Kyong-Hee;Kim, Dong-Il;Lee, Choul-Gyun
    • Journal of Microbiology and Biotechnology
    • /
    • 제10권6호
    • /
    • pp.817-822
    • /
    • 2000
  • A proper flashing light is expected to enhance microalgal biomass productivity and photosynthetic efficiency. The effect of flashing light on high-density Chlorella kessleri (UTEX 398) cultures was studied using light-emitting diodes. A frequency modulator was designed to flash LEDs, and the device successfully provided wide range of frequencies and various duty cycles of flashing. A relatively high frequencies of 10, 20 and 50 kHz were used in this study. These frequencies have very short flashing time ($2-50{\mu}s$), which corresponded to the time constant of the light reaction of photosynthesis. The specific oxygen production rates of photosynthesis under flashing light were compared with those under an equivalent continuous light in specially designed illumination cuvette. The specific oxygen production rates under flashing light were 5-25% higher than those under the continuous light. A range of cell concentration was discovered, where the benefit of flashing light was maximized. The photosynthetic efficiency was also higher under flashing light with frequencies of over 1 kHz, which was a clear indication of flashing light effect and the degree of mutual shading could by overcome by flashing lights, particularly at high-density algal cultures.

  • PDF

기상휘발법에 의한 이산화규소 나노와이어의 성장에 미치는 가스의 영향 (Effect of Ambient Gas to Growth of SiO2 Nanowires by Vapor Evaporation Method)

  • 노대호;김재수;변동진;이재훈;양재웅;김나리
    • 한국재료학회지
    • /
    • 제15권5호
    • /
    • pp.323-333
    • /
    • 2005
  • Effects of gases to growth of $SiO_2$ nanowires were characterized. $N_2$, Ar, and $O_2$ gas's effect were determined. $SiO_2$ nanowires growth scheme was varied by kind and flow rates of gases because of amounts of $O_2$. Flow rates of gases and kind of substrates affected nanowires' diameters, lengths and morphologies of grown nano wires. With increasing flow rates of gases, nanowire's diameter increased because of additional VS and SLS reactions. By TEM characterization, We knows that, grown $SiO_2$ nanowires on Si substrate showed two shell structures. These shapes of nanowires were formed by reaction of additional SLS growth. Grown $SiO_2$ nanowires showed blue luminescence by PL characterization These Blue luminescence was due to quantum confinement effect and oxygen vacancies in the nanowires.

산사(山楂)가 DNCB로 유발된 생쥐의 알레르기성 접촉피부염에 미치는 영향 (Effects of Crataegus Pinnatifida (CP) on Allergic Contact Dermatitis (ACD) Induced by DNCB in Mice)

  • 유수향;채중원
    • 대한한방소아과학회지
    • /
    • 제28권3호
    • /
    • pp.59-73
    • /
    • 2014
  • Allergic contact dermatitis (ACD) is a type IV delayed hypersensitivity reaction that results from exposures and subsequent sensitization to an environmental chemical. Crataegus Pinnatifida (CP) is commonly used to improve spleen function, remove retention of food, and promote blood circulation. This study is designed to investigate the effects of CP on ACD induced by 2,4-dinitrochlorobenzene (DNCB) in mice. In this experiment, the effects of CP on changes in body weights, ear and dorsum skin thicknesses, ear weights, clinical aspects on the dorsum skin, histopathological changes, spleen weights, cytokines were investigated. In addition, the effects on the proliferation rates of splenocytes were also investigated in vivo and vitro study. In results, CP spread (CPS) group and CP spread and administered (CPS+Adm) group showed decrease in spleen weights. In CPS+Adm group, dorsum skin thicknesses were decreased significantly compared to control group. CP treatment diminished erythema, desquamation and keratosis which were induced by repeated painting of DNCB. In histopathological observation, spongiosis and edema were diminished in CPS and CPS+Adm group. CP led to decrease in the proliferation rates of splenocytes in vivo and vitro. In conclusion, these data suggest that CP can decrease symptoms of ACD, so CP is useful to treat patient with ACD.

부식억제제에 의한 상수도관의 부식제어 (Corrosion control of drinking water pipes by corrosion inhibitor)

  • 황병기
    • 한국산학기술학회논문지
    • /
    • 제11권6호
    • /
    • pp.2306-2310
    • /
    • 2010
  • 상수도관의 부식은 수돗물이 공급되는 과정에서 관 표면의 금속과 물 사이의 일련의 복잡한 산화/환원 반응이다. 부식으로 인해 발생할 수 있는 1차적인 고려사항은 철, 납, 동과 같은 독성이 있는 중금속이 물속에 존재할 수 있다는 것이며, 이는 상수도관에 악영향을 미치며, 세탁물을 훼손하거나 맛을 낼 수 있는 심미적인 문제도 발생된다. 본 연구에서는 부식억제제가 상수도관의 부식도, 수돗물 중의 철 및 동의 용출 농도에 어떠한 영향을 미치는지에 대해서 평가하였다. 부식저감 효과는 인산염계 부식억제제와 큰 관련성이 있었다. 부식반응은 물과 관의 표면에서 이루어지는 일련의 전기화학적인 반응임을 고려하면 철의 용출농도와 부식도는 양(+)의 상관관계에 있다.