• Geomechanics and Engineering
• /
• v.28 no.1
• /
• pp.89-105
• /
• 2022

The behavior of the soil subgrade is complex and irregular against loads. When modeling, the soil is often replaced by a more straightforward system called a subgrade model. The Winkler method of linear elastic springs is a popular method of soil modeling in which the spring constant shows the modulus of subgrade reaction. In this research, the factors affecting the distribution of the modulus of subgrade reaction of elastoplastic subgrades are examined. For this purpose, critical theories about the modulus of subgrade reaction were examined. A square raft foundation on a sandy soil subgrade with was analyzed at different internal friction angles and Young's modulus values using ABAQUS software. To accurately model the actual soil behavior, the elastic, perfectly plastic constitutive model was applied to investigate a foundation on discrete springs. In order to increase the accuracy of soil modeling, equations have been proposed for the distribution of the subgrade reaction modulus. The constitutive model of the springs is elastic, perfectly plastic. It was observed that the modulus of subgrade reaction under an elastic load decreased when moving from the corner to the center of the foundation. For the ultimate load, the modulus of subgrade reaction increased as it moved from the corner to the center of the foundation.

• Journal of Powder Materials
• /
• v.30 no.1
• /
• pp.53-64
• /
• 2023

Atomic layer etching (ALE) is a promising technique with atomic-level thickness controllability and high selectivity based on self-limiting surface reactions. ALE is performed by sequential exposure of the film surface to reactants, which results in surface modification and release of volatile species. Among the various ALE methods, thermal ALE involves a thermally activated reaction by employing gas species to release the modified surface without using energetic species, such as accelerated ions and neutral beams. In this study, the basic principle and surface reaction mechanisms of thermal ALE?processes, including "fluorination-ligand exchange reaction", "conversion-etch reaction", "conversion-fluorination reaction", "oxidation-fluorination reaction", "oxidation-ligand exchange reaction", and "oxidation-conversion-fluorination reaction" are described. In addition, the reported thermal ALE processes for the removal of various oxides, metals, and nitrides are presented.

• Korean Journal of Materials Research
• /
• v.14 no.10
• /
• pp.725-730
• /
• 2004

Nickel ultrafine powder have been synthesized by chemical reduction of aqueous $NiSO_4$ with hydrazine at various reaction conditions. The effect of reaction conditions such as the amount of surfactant and reductor, and reaction temperature on the particle size and shape was investigated by the mean of XRD, SEM and SEM-PSA. Experiments showed that the ratio of $N_{2}H_4/Ni$ and the reaction temperature were affected on the particle size of the nickel powder. The average particle size of synthesized nickel powder increased with increasing reaction temperature regardless of the ratio of $N_{2}H_4/Ni$. Also the surfactant could influence the size and agglomeration of ultrafine powder with the reaction temperature.

• Korean Chemical Engineering Research
• /
• v.53 no.4
• /
• pp.463-467
• /
• 2015

We investigated catalytic activity of ion-exchange resins in acetalization of 1,2-propylene glycol with acetaldehyde. The impacts of reaction variables, such as temperature, reaction time, catalyst loading and feedstock composition, on the conversion of 1,2-propylene glycol were measured. The life of the catalyst was also studied. Furthermore, the reaction kinetics of 1,2-propylene glycol acetalization was studied. It was found that reaction rate followed the first-order kinetics to acetaldehyde and 1,2-propylene glycol, respectively. Therefore, overall acetalization reaction should follow the second-order reaction kinetics, expressed as. Key words: 1,2-propylene Glycol, 2,4-dimethyl-1,3-dioxolane, Ion-exchange Resin, Polyhydroxy Compounds, Acetalization $r=kC^{nA}_AC^{nB}_B=19.74e^{\frac{-6650}{T}}C^1_AC^1_B$.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.1
• /
• pp.112-116
• /
• 2013

Surface modification of montmorillonite (MMT) with 3-glycidoxypropyl trimethoxysilane (3GTO) in mild methanol/water mixture has been investigated in detail. The influence of reaction conditions (including silane concentration in feed, reaction time and reaction temperature) on the grafting amount and yield of silane, and further on the grafting pattern of silanes was studied by thermogravimetric analysis, elemental analysis, X-ray diffraction (XRD) and BET. Higher silane concentration, longer reaction time and higher reaction temperature are all benefit to higher grafting amount. When the grafting reaction was performed with 3 mmol/g silane concentration, at $90^{\circ}C$ for 24 h, the grafted amount and yield of silane reached 1.4443 mmol/g and 30%, respectively. Based on the XRD and BET data analysis, a speculation that the grafting pattern of silanes was concentration dependence was proposed.

• Bulletin of the Korean Chemical Society
• /
• v.24 no.11
• /
• pp.1632-1636
• /
• 2003

Palladium-catalyzed cross-coupling reactions of neopentyloxysulfonylphenyl bromides with arylboronic acids provided a variety of neopentyl biphenylsulfonates in good yields. 2-Bromo- and 4-bromobenzenesulfonates underwent the coupling reaction more rapidly than 3-bromobenzenesulfonate, while chlorobenzenesulfonate did not produce the coupling product under the standard reaction conditions.

• 한국연소학회:학술대회논문집
• /
• 2015.12a
• /
• pp.251-255
• /
• 2015

Unsteady Shock-Induced Combustion has been studied for the past few decades since it is considered as one of the potential ways to reach supersonic flights. Experimental observations of Unsteady SIC were observed as early as 1960's. But Lehr was the first to report in detail the mechanisms of Shock-Induced Combustion experimentally. Numerical Studies on SIC were helpful in explaining the insight into the oscillatory behaviour in the mid 90's to early 2000's. Detailed reaction mechanisms is required to prediction the SIC flowfield more in detail. However at that time, very few reaction mechanisms on hydrogen-oxidation were reported. In the last decade, various number of hydrogen reaction mechanisms were reported. In this study, an attempt has been made to analyze the effect of various reaction mechanisms in an unsteady mode of Shock-Induced Combustion.

• Journal of the Korean institute of surface engineering
• /
• v.32 no.3
• /
• pp.303-306
• /
• 1999

On the effect of substrate bias at first stage of diamond synthesis at lower substrate temperature(approximately 673K) using microwave plasma CVD and effect of reaction gas system for the bias enhanced nucleation were studied. The reaction gas was mixture of methane and hydrogen or carbon monoxide and hydrogen. The nucleation density of applied bias -150V using $CH_4-H_2$ reaction gas system, significantly higher than that of $C-H_2$ reaction gas system. When the $CH_4-H_2$ reaction was used, nucleation density was increased because of existence of SiC as a interface for diamond nucleation. By use of this negative bias effect for fabrication of CVD diamond film using two-step diamond growth without pre-treatment, fabrication of the diamond film consist of diamond grains $0.2\mu\textrm{m}$ in diameter was demonstrated

• Macromolecular Research
• /
• v.13 no.1
• /
• pp.68-72
• /
• 2005

A low-molecular-weight poly(lactic acid) was synthesized through the condensation reaction of L-lactic acid. The effects that the catalyst and temperature have on the reaction rate were studied to determine the optimum reaction conditions. The reaction kinetics increased with temperature up to $210^{\circ}C$, but no further increase was observed above this temperature. Among a few selective catalysts, sulfuric acid was the most effective because it maximized the polymerization reaction rate. Reduction of the pressure was another important factor that enhanced this reactions kinetics.

• Korean Chemical Engineering Research
• /
• v.56 no.5
• /
• pp.738-751
• /
• 2018

The effect of the reaction temperature and reaction time on the thermal oxidative purification quality of detonation nanodiamond (NDsoot) was investigated in a gas-solid fluidized bed reactor of a $0.10m-ID{\times}1.0m$-high stainless steel column with zirconia beads ($d_{SV}=99.2{\mu}m$). The carbon conversion increased with increasing the reaction temperature; however, when the reaction temperature was greater than 773 K, the carbon conversion did not increase. The content of $sp^3$-hybridized carbon at the reaction temperature of 703 K barely changed when the reaction time was more than 30 minutes, but at 773 K, the content decreased as preferred. At 703 K, the purification quality increased with the increasing reaction time; however, at 773 K, the purification quality increased up to 30 minutes and then decreased rapidly.