• Title/Summary/Keyword: Reaction System

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Numerical Verification of B-WIM System Using Reaction Force Signals

  • Chang, Sung-Jin;Kim, Nam-Sik
    • Journal of the Korean Society for Nondestructive Testing
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    • v.32 no.6
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    • pp.637-647
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    • 2012
  • Bridges are ones of fundamental facilities for roads which become social overhead capital facilities and they are designed to get safety in their life cycles. However as time passes, bridge can be damaged by changes of external force and traffic environments. Therefore, a bridge should be repaired and maintained for extending its life cycle. The working load on a bridge is one of the most important factors for safety, it should be calculated accurately. The most important load among working loads is live load by a vehicle. Thus, the travel characteristics and weight of vehicle can be useful for bridge maintenance if they were estimated with high reliability. In this study, a B-WIM system in which the bridge is used for a scale have been developed for measuring the vehicle loads without the vehicle stop. The vehicle loads can be estimated by the developed B-WIM system with the reaction responses from the supporting points. The algorithm of developed B-WIM system have been verified by numerical analysis.

The Effects of Zeolite Structure and Ion-exchange Material on NH3-SCR Reaction (제올라이트 종류 및 이온교환 물질에 따른 NH3-SCR 촉매 반응 특성)

  • Hwang, Inhye;Lee, Junho;Kim, Hongsuk;Jeong, Youngil
    • Transactions of the Korean Society of Automotive Engineers
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    • v.22 no.1
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    • pp.135-141
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    • 2014
  • $NH_3$-SCR has high NOx removal efficiency approximately 80~90%. Recently, the copper or iron ion-exchanged zeolite catalysts are widely used as automobile SCR catalysts. In this paper, the effect of the space velocity, temperature of reaction and $NO_2$ addition on the $NH_3$-SCR reaction were studied using various zeolite SCR catalysts. The test was conducted with small sized fresh catalysts in a laboratory fixed-bed flow reactor system using simulated gases. It is found that the activity of the BEA is better than MFI. It seems that three-dimensional framework and a wide pore entrance of BEA enhances the SCR activity. It is also found that low temperature activity of Cu-zeolites was better than Fe-zeolites. Once $NO_2$ was added, the NOx conversion activity of the Cu-zeolite was slightly enhanced, whereas remarkable improvement was achieved by Fe-zeolite.

Development of the Gas Charging Simulator for Reaction Control System of KSLV-I (KSLV-I RCS 충전모사 시스템 개발)

  • Jeon, Sang-Woon;Jung, Seul;Kim, Ji-Hun
    • Aerospace Engineering and Technology
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    • v.8 no.2
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    • pp.122-126
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    • 2009
  • KSLV(Korea Space Launch Vehicle)-I is designed as a launch vehicle to enter a 100 kg-class satellite to the LEO(Low-Earth Orbit). Attitude angles of the upper-stage, including roll, pitch and yaw are controlled by cold gas thruster system using nitrogen gas. To verify the flow rate of the gas charging system and to prepare a nitrogen gas charging scenario, the development of a gas charging simulator for RCS(Reaction Control System) is required. This paper describes the orifice design, development, and test of the gas charging simulator for RCS of KSLV-I.

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The Onset and Growth of the Buoyancy-driven Fingering Driven by the Irreversible A+B→C Reaction in a Porous Medium: Reactant Ratio Effect

  • Kim, Min Chan
    • Korean Chemical Engineering Research
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    • v.59 no.1
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    • pp.138-151
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    • 2021
  • The effect of a reactant ratio on the growth of a buoyancy-driven instability in an irreversible A+B→C reaction system is analyzed theoretically and numerically. Taking a non-stoichiometric reactant ratio into account, new linear stability equations are derived without the quasi-steady state assumption (QSSA) and solved analytically. It is found that the main parameters to explain the present system are the Damköhler number, the dimensionless density difference of chemical species and the ratio of reactants. The present initial grow rate analysis without QSSA shows that the system is initially unconditionally stable regardless of the parameter values; however, the previous initial growth rate analysis based on the QSSA predicted the system is unstable if the system is physically unstable. For time evolving cases, the present growth rates obtained from the spectral analysis and pseudo-spectral method support each other, but quite differently from that obtained under the conventional QSSA. Adopting the result of the linear stability analysis as an initial condition, fully nonlinear direct numerical simulations are conducted. Both the linear analysis and the nonlinear simulation show that the reactant ratio plays an important role in the onset and the growth of the instability motion.

Numerical Study on Correlation between Operating Parameters and Reforming Efficiency for a Methane Autothermal Reformer (천연가스 자열개질기를 위한 작동조건과 개질효율의 상관관계에 대한 수치해석 연구)

  • Park, Joon-Guen;Lee, Shin-Ku;Lim, Sung-Kwang;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.8
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    • pp.636-644
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    • 2008
  • The objective of this paper is to investigate characteristics of an autothermal reformer at various operating conditions. Numerical method has been used, and simulation model has been developed for the analysis. Pseudo-homogeneous model is incorporated because the reactor is filled with catalysts of a packed-bed type. Dominant chemical reactions are Full Combustion reaction, Steam Reforming(SR) reaction, Water-Gas Shift(WGS) reaction, and Direct Steam Reforming(DSR) reaction. Simulation results are compared with experimental results for code validation. Operating parameters of the autothermal reformer are inlet temperature, Oxygen to Carbon Ratio(OCR), Steam to Carbon Ratio(SCR), and Gas Hourly Space Velocity(GHSV). Temperature at the reactor center, fuel conversion, species at the reformer outlet, and reforming efficiency are shown as simulation results. SR reaction rate is improved by increased inlet temperature. Reforming efficiency and fuel conversion reached the maximum at 0.7 of OCR. SR reaction and WGS reaction are activated as SCR increases. When GHSV is increased, reforming efficiency increases but pressure drop from the increased GHSV may decrease the system efficiency.

Dynamics of Gas-phase Hydrogen Atom Reaction with Chemisorbed Hydrogen Atoms on a Silicon Surface

  • 임선희;이종백;김유항
    • Bulletin of the Korean Chemical Society
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    • v.20 no.10
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    • pp.1136-1144
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    • 1999
  • The collision-induced reaction of gas-phase atomic hydrogen with hydrogen atoms chemisorbed on a silicon (001)-(2×1) surface is studied by use of the classical trajectory approach. The model is based on reaction zone atoms interacting with a finite number of primary system silicon atoms, which then are coupled to the heat bath, i.e., the bulk solid phase. The potential energy of the Hads‥Hgas interaction is the primary driver of the reaction, and in all reactive collisions, there is an efficient flow of energy from this interaction to the Hads-Si bond. All reactive events occur on a subpicosecond scale, following the Eley-Rideal mechanism. These events occur in a localized region around the adatom site on the surface. The reaction probability shows the maximum near 700K as the gas temperature increases, but it is nearly independent of the surface temperature up to 700 K. Over the surface temperature range of 0-700 K and gas temperature range of 300 to 2500 K, the reaction probability lies at about 0.1. The reaction energy available for the product states is small, and most of this energy is carried away by the desorbing H2 in its translational and vibrational motions. The Langevin equation is used to consider energy exchange between the reaction zone and the bulk solid phase.

Distribution of elastoplastic modulus of subgrade reaction for analysis of raft foundations

  • Rahgooy, Kamran;Bahmanpour, Amin;Derakhshandi, Mehdi;Bagherzadeh-Khalkhali, Ahad
    • Geomechanics and Engineering
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    • v.28 no.1
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    • pp.89-105
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    • 2022
  • The behavior of the soil subgrade is complex and irregular against loads. When modeling, the soil is often replaced by a more straightforward system called a subgrade model. The Winkler method of linear elastic springs is a popular method of soil modeling in which the spring constant shows the modulus of subgrade reaction. In this research, the factors affecting the distribution of the modulus of subgrade reaction of elastoplastic subgrades are examined. For this purpose, critical theories about the modulus of subgrade reaction were examined. A square raft foundation on a sandy soil subgrade with was analyzed at different internal friction angles and Young's modulus values using ABAQUS software. To accurately model the actual soil behavior, the elastic, perfectly plastic constitutive model was applied to investigate a foundation on discrete springs. In order to increase the accuracy of soil modeling, equations have been proposed for the distribution of the subgrade reaction modulus. The constitutive model of the springs is elastic, perfectly plastic. It was observed that the modulus of subgrade reaction under an elastic load decreased when moving from the corner to the center of the foundation. For the ultimate load, the modulus of subgrade reaction increased as it moved from the corner to the center of the foundation.

Hydrothermal Kinetics and Mechanisms of Lime and Quartz Used Solid State Reaction Equations (고상반응식을 이용한 석회-석영의 수열반응속도와 반응메카니즘)

  • Lim, Going
    • The Journal of Engineering Research
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    • v.3 no.1
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    • pp.223-233
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    • 1998
  • The kinetic and mechanism of the hydrothermal reaction between lime and quartz used solid state reaction equations have been investigated. Hydrothermal reaction on the starting materials was carried out in an autoclave that quartz mixed with calcium hydroxide in CaO/$SiO_2$ ratio of 0.8-1.0 for 0.5-8 hour at saturated steam pressure of $180-200^{\circ}C$. The rate of reaction was given from the ratio of uncombined lime and quartz content to the total lime and quartz content. The rate of reaction was obtained the results by the Jander's equation $[1-(1-\alpha)^{1/3}]^N=Kt$. The reaction of lime is controlled mainly by the dissolution such as N=1, and the reaction of quartz is controlled mostly by the diffusion such as $N\risingdotseq2$. The rate of hydrothermal reaction in the calcium silicate hydrates system is suggested to be determined generally by the mass transfer through the product laver formed around the reactant particles. The rate equation for whole hydrothermal reaction is shown that it is converted into the rate determining step by the diffusion from the boundary reaction such as approximately $N=1-2$.

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Numerical Analysis of Steam-methane Reforming Reaction for Hydrogen Generation using Catalytic Combustion (촉매 연소를 열원으로 한 수증기-메탄개질반응 전산유체해석)

  • Lee, Jeongseop;Lee, Kanghoon;Yu, Sangseok;Ahn, Kookyoung;Kang, Sanggyu
    • Journal of Hydrogen and New Energy
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    • v.24 no.2
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    • pp.113-120
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    • 2013
  • A steam reformer is a chemical reactor to produce high purity hydrogen from fossil fuel. In the steam reformer, since endothermic steam reforming is heated by exothermic combustion of fossil fuel, the heat transfer between two reaction zones dominates conversion of fossil fuel to hydrogen. Steam Reforming is complex chemical reaction, mass and heat transfer due to the exothermic methane/air combustion reaction and the endothermic steam reforming reaction. Typically, a steam reformer employs burner to supply appropriate heat for endothermic steam reforming reaction which reduces system efficiency. In this study, the heat of steam reforming reaction is provided by anode-off gas combustion of stationary fuel cell. This paper presents a optimization of heat transfer effect and average temperature of cross-section using two-dimensional models of a coaxial cylindrical reactor, and analysis three-dimensional models of a coaxial cylindrical steam reformer with chemical reaction. Numerical analysis needs to dominant chemical reaction that are assumed as a Steam Reforming (SR) reaction, a Water-Gas Shift (WGS) reaction, and a Direct Steam Reforming(DSR) reaction. The major parameters of analysis are temperature, fuel conversion and heat flux in the coaxial reactor.

Adaptive Multimodal In-Vehicle Information System for Safe Driving

  • Park, Hye Sun;Kim, Kyong-Ho
    • ETRI Journal
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    • v.37 no.3
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    • pp.626-636
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    • 2015
  • This paper proposes an adaptive multimodal in-vehicle information system for safe driving. The proposed system filters input information based on both the priority assigned to the information and the given driving situation, to effectively manage input information and intelligently provide information to the driver. It then interacts with the driver using an adaptive multimodal interface by considering both the driving workload and the driver's cognitive reaction to the information it provides. It is shown experimentally that the proposed system can promote driver safety and enhance a driver's understanding of the information it provides by filtering the input information. In addition, the system can reduce a driver's workload by selecting an appropriate modality and corresponding level with which to communicate. An analysis of subjective questionnaires regarding the proposed system reveals that more than 85% of the respondents are satisfied with it. The proposed system is expected to provide prioritized information through an easily understood modality.