• Title/Summary/Keyword: Reaction System

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Antioxidative Characteristics of Fermented Soybean Sauce on the Oxidation of Fatty Acid Mixture (지방산의 산화(酸化)에 대한 양조간장의 항산화(抗酸化) 특성)

  • Cheigh, Hong-Sik;Lee, Jeong-Soo;Moon, Gap-Soon;Park, Kun-Young
    • Korean Journal of Food Science and Technology
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    • v.22 no.3
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    • pp.332-336
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    • 1990
  • Antioxidative characteristics of freeze dried soybean sauce powder (SSP) on the oxidation reaction of linoleic acid mixture(LA) were evaluated by the determinations of peroxide formation, synergistic property, hydrogen donation and lipoxygenase activity. SSP was found to possess a considerable potentiality of antioxidant activity on the formation of hydroperoxides in the LA oxidation reaction system at $50^{\circ}C$ for 144hrs. This antioxidative effect was increased by the concentration from 0.02% to 0.5% of SSP in the reaction system. Under the condition of presence of ferric chloride (10 ppm) in the reaction system. appreciable effect of SSP on the synergistic antioxidation were observed. On the other hand, hydrogen donation property of SSP onto ${\alpha},\;{\alpha}'-diphenyl-{\beta}-picrylhydrazyl$ was found and inhibitory ability of SSP on LA oxidation was also shown in the reaction system of lipoxygenase-catalized oxidation.

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In situ Photoacoustic Study of Water Gas Shift Reaction over Magnetite/Chromium Oxide and Copper/Zinc Oxide Catalysts

  • Byun, In-Sik;Choi, Ok-Lim;Choi, Joong-Gill;Lee, Sung-Han
    • Bulletin of the Korean Chemical Society
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    • v.23 no.11
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    • pp.1513-1518
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    • 2002
  • Kinetic studies on the water-gas shift reaction catalyzed by magnetite/chromium oxide and copper/zinc oxide were carried out by using an in situ photoacoustic spectroscopic technique. The reactions were performed in a closed-circulation reactor system using a differential photoacoustic cell at total pressure of 40 Torr in the temperature range of 100 to $350^{\circ}C.$ The CO2 photoacoustic signal varying with the concentration of CO2 during the catalytic reaction was recorded as a function of time. The time-resolved photoacoustic spectra obtained for the initial reaction stage provided precise data of CO2 formation rate. The apparent activation energies determined from the initial rates were 74.7 kJ/mol for the magnetite/chromium oxide catalyst and 50.9 kJ/mol for the copper/zinc oxide catalyst. To determine the reaction orders, partial pressures of CO(g) and H2O(g) in the reaction mixture were varied at a constant total pressure of 40 Torr with N2 buffer gas. For the magnetite/chromium oxide catalyst, the reaction orders with respect to CO and H2O were determined to be 0.93 and 0.18, respectively. For the copper/zinc oxide catalyst, the reaction orders with respect to CO and H2O were determined to be 0.79 and 0, respectively.

Reaction Condition Dependency of Propagating Behavior in the Polymerization Reaction by Thermal Front

  • Huh, Do-Sung;Choe, Sang-Joon;Lee, Burm-Jong
    • Bulletin of the Korean Chemical Society
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    • v.23 no.2
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    • pp.325-329
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    • 2002
  • In this study, the dependency of the behavior of propagating front on the reaction condition in frontal polymerization reaction has been studied. We have used some multifunctional acrylates as a monomer and ammonium persulfate as an initiator for the polymerization reactions. In frontal polymerization, a method of producing polymeric materials via a thermal front that propagates through the unreacted monomer/initiator solution, the behavior of self propagating front shows various dynamic patterns depending on the reaction condition. We have obtained some spin modes of propagating front in the number of 'hot spots' or 'spin heads' by changing the reaction condition. The effect of the reactor tube diameter on the mode of propagating front has also been studied by using some reactor tubes with different size of tube diameter and it has been examined in some detail by adopting an experimental method of two-tubes system.

Engineering Model Design and Implementation Proto Flight Model of Reaction Wheel Assembly Interface Unit for STSAT-2 (과학기술위성 2호 Reaction Wheel Assembly Interface Unit Proto Flight Model 개발)

  • Kim, Se-Il;Gang, Gyeong-In;Lee, Seong-Ho
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.5
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    • pp.88-92
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    • 2006
  • Proto Flight Model of Reaction Wheel Assembly Interface Unit(RIU) for STSAT-2 was developed. The RIU of STSAT2 has three major functions for interface between satellite system and RWAs. It has switches for RWA main power, communication Mux. and communication line driver.

Thermite Reaction Between CuO Nanowires and Al for the Crystallization of a-Si

  • Kim, Do-Kyung;Bae, Jung-Hyeon;Kim, Hyun-Jae;Kang, Myung-Koo
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.5
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    • pp.234-237
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    • 2010
  • Nanoenergetic materials were synthesized and the thermite reaction between the CuO nanowires and the deposited nano-Al by Joule heating was studied. CuO nanowires were grown by thermal annealing on a glass substrate. To produce nanoenergetic materials, nano-Al was deposited on the top surface of CuO nanowires. The temperature of the first exothermic reaction peak occurred at approximately $600^{\circ}C$. The released heat energy calculated from the first exothermic reaction peak in differential scanning calorimetry, was approximately 1,178 J/g. The combustion of the nanoenergetic materials resulted in a bright flash of light with an adiabatic frame temperature potentially greater than $2,000^{\circ}C$. This thermite reaction might be utilized to achieve a highly reliable selective area crystallization of amorphous silicon films.

Modeling of Reaction Wheel Using KOMPSAT-1 Telemetry (KOMPSAT-1 Telemetry를 활용한 반작용휠 모델링)

  • Lee, Seon-Ho;Choi, Hong-Taek;Yong, Gi-Ryeok;Oh, Si-Hwan;Rhee, Seung-U
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.3
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    • pp.45-50
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    • 2004
  • The design of reaction wheel control logic is critical to achieve the spacecraft attitude stabilization and performance requirements for the successful mission. Due to various uncertainties on orbit there exist limitation to obtain the model parameters through the ground tests and to design the associated control logic. Thus, the model parameter correction using on-orbit data is essential to the control performance on orbit. This paper performs the system identification using KOMPSAT-1 telemetry data and extracts the model parameters of the reaction wheel. Moreover, the reaction wheel is remodeled and compared with the ground test results.

Production of (R)-Ethyl-4-Chloro-3-Hydroxybutanoate Using Saccharomyces cerevisiae YOL151W Reductase Immobilized onto Magnetic Microparticles

  • Choo, Jin Woo;Kim, Hyung Kwoun
    • Journal of Microbiology and Biotechnology
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    • v.25 no.11
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    • pp.1810-1818
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    • 2015
  • For the synthesis of various pharmaceuticals, chiral alcohols are useful intermediates. Among them, (R)-ethyl-4-chloro-3-hydroxybutanoate ((R)-ECHB) is an important building block for the synthesis of L-carnitine. (R)-ECHB is produced from ethyl-4-chloro-3-oxobutanoate (ECOB) by a reductase-mediated, enantioselective reduction reaction. The Saccharomyces cerevisiae YOL151W reductase that is expressed in Escherichia coli cells exhibited an enantioselective reduction reaction toward ECOB. By virtue of the C-terminal His-tag, the YOL151W reductase was purified from the cell-free extract using Ni2+-NTA column chromatography and immobilized onto Ni2+-magnetic microparticles. The physical properties of the immobilized reductase (Imm-Red) were measured using electron microscopy, a magnetic property measurement system, and a zeta potential system; the average size of the particles was approximately 1 μm and the saturated magnetic value was 31.76 emu/g. A neodymium magnet was used to recover the immobilized enzyme within 2 min. The Imm-Red showed an optimum temperature at 45℃ and an optimum pH at 6.0. In addition, Bacillus megaterium glucose dehydrogenase (GDH) was produced in the E. coli cells and was used in the coupling reaction to regenerate the NADPH cofactor. The reduction/oxidation coupling reaction composed of the Imm-Red and GDH converted 20 mM ECOB exclusively into (R)-ECHB with an e.e.p value of 98%.

대구경 소켓경사반력말뚝의 인발거동에 관한 연구

  • 최용규;김상옥;정창규;정성기;김상일
    • Proceedings of the Korean Geotechical Society Conference
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    • 2000.11a
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    • pp.277-284
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    • 2000
  • Using the large diameter (D = 2,500mm, L = 40m) batter steel pipe piles, designed as compression piles but used as reaction piles during the static compression load test of socketed test piles (D = 1,000mm, L = 40m), static pile load tests for large diameter instrumented rock-socketed piles were performed. The reaction steel pipe piles were driven 20m into the marine deposit and weathered rock layer and then l0m socketed with reinforced concrete through the weathered rock layer and into hard rock layer. Steel pipe and concrete in the steel pile part, and concrete and rebars in the socketed parts were instrumented to measure strains in each part. The pullout amounts of reaction pile heads were also measured with LVDT. During the static pile load test, total compressional load of about 20MN was loaded on the head of test piles, but load above 20MN was not loaded due to lack of loading capacity of loading system. Over the course of the study, maximum pullout amount up to 7mm was measured in the heads of reaction piles when loaded op to 10MN and 1mm of pullout amount was measured. More than 85% of pullout load was transfered in the residual weathered rock layer and about 10% in the soft rock layer, which was somewhat different transfer mechanism in the static compressional load tests.

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Development of diagnostic method for human Astrovirus with rapid, specific and high sensitivity using loop-mediated isothermal amplification method

  • Lee, Jin-Young;Rho, Jae Young
    • Korean Journal of Agricultural Science
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    • v.47 no.1
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    • pp.173-182
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    • 2020
  • Human Astrovirus (HuAstV), known as a waterborne virus, is a group IV positive-sense single-stranded RNA that belongs to Astroviridae. The first outbreak of HuAstV was reported in England in 1975. HuAstV can exist not only among clinical patients but also in various water environments, such as water for agriculture and vegetables. For diagnosis of HuAstV from water samples, a polymerase chain reaction (PCR) system has been developed. However, the PCR-based diagnostic method has problems in field application, such as reaction time, sensitivity and specificity. For this reason, in this study we developed the loop-mediated isothermal amplification assay (LAMP) system, aimed specifically at HuAstV. Three prepared LAMP primer sets were tested by specificity, non-specificity and sensitivity; one LAMP primer set was selected with optimum reaction temperature. The developed LAMP primer set reaction conditions were confirmed at 62℃, and detection sensitivity was 1 fg/μL. In addition, restriction enzyme HaeIII (GG/CC) was introduced to confirm that the LAMP reaction was positive. As a result, selected LAMP primer set was 100 - 1000 times more specific, rapid, and sensitive than conventional-nested PCR methods. For verification of the developed LAMP assay, twenty samples of cDNA from groundwater samples were tested. We expect that the developed LAMP assay will be used to diagnose HuAstV from various samples.

Experimental Study on Effects of Speed Error Disturbance on Reaction Wheel Control (속도 오차 외란이 반작용 휠 제어에 미치는 영향에 관한 실험적 연구)

  • Kim, Jichul;Lee, Hyungjun;Yoo, Jihoon;Oh, Hwasuk
    • Journal of Aerospace System Engineering
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    • v.10 no.1
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    • pp.95-102
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    • 2016
  • There are many possible disturbance sources on such a spacecraft, but reaction wheel assembly (RWA) which is generally used for spacecraft attitude control is anticipated to be the largest. These effects on degradation of performance of spacecraft such as attitude stability. In reaction wheel, disturbance caused by imbalance and speed error. It is hard to emulate speed error disturbance because it is not coincide with wheel frequency. This paper concentrates on emulating and analyzing the speed error disturbance. Firstly, classify the causes that lead to speed error disturbance which generate RPM fluctuation. Secondly, simulated with disturbance driver module and reaction wheel assembly which are developed by Spacecraft Control Lab. Experimental investigations have been carried out to test the disturbance emulator module as a disturbance generator for RWA. Measurements and test have been conducted on various fault. Frequency analysis of test data show that speed error disturbance effects on wheel settling wheel speed or fluctuation type.