• Title/Summary/Keyword: Reaction Modulus

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A Study on the Method of Calculating the Deformation Coefficient According to the Horizontal Subgrade Reaction Modulus and Cohesion (수평지반반력계수와 점착력에 따른 지반변형계수 산정방법 연구)

  • Sungjae Jeon;Daeseock Jung
    • Journal of the Society of Disaster Information
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    • v.19 no.1
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    • pp.31-43
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    • 2023
  • Purpose: In this study, an analysis of the differences between the elastoplastic analysis and the numerical analysis and a study of the design ground constant recalculation method to derive similar trends in the analysis results were conducted. Method: The relational expression between the ground reaction force coefficient and the ground deformation coefficient at the time when the wall displacement becomes the same according to shallow excavation and deep excavation was derived. Result: Based on the measurement results, reverse analysis was performed to re-calculate the ground properties suitable for the site ground, and as a result of comparing and verifying the wall displacement using the derived formula and the literature formula, the proposed formula showed the most similar value. Conclusion: If the proposed formula is used, it will be helpful in practice because it is possible to infer the most similar ground properties to the actual at the time of design.

Hydrothermal Reaction Characteristics on the ALC of Pitchstone-Lime System (II) - Effect of the Various Gelling and Curing Conditions (송지암-석회계 ALC에 대한 수열반응 특성(II) - 겔화 및 양생조건에 따른 영향)

  • 최병현;김순환
    • Journal of the Korean Ceramic Society
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    • v.31 no.2
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    • pp.194-200
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    • 1994
  • Pitchstone(Volcanic ejecta) reacts with CaO in hot water and increases its sedimentary volume by forming Ca(OH)2 and calcium silicate hydrates. ALC was prepared from the various gelling and curing conditions using the ratio of pitchstone/CaO was 2(CaO/SiO2 mol ratio=0.81), and then the products, crystalline phases and physical properties of ALC with experimental conditions was investigated. The crystalline phase of tobermorite with laths and plate type and the porosity were increased, the thermal conductivity was decreased with increasing gelling temperature and time. But modulus of rupture has maximum value when gelling time was 2 hrs. Othwrwise the bulk density nearly unchanged with increasing curing temperature, but the modulus of rupture was increased.

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A Nonlinear Analysis on the Unit Model of Steel-Concrete Hybrid Deck for Bridges (교량용 강ㆍ콘크리트 합성 바닥판의 단위모델에 대한 비선형 해석)

  • 정광회;정연주;구현본;김정호;김병석
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2003.04a
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    • pp.85-91
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    • 2003
  • This paper presents a 3D nonlinear analysis with slip in steel-concrete hybrid deck. In this study, it was founded that the limit slip modulus could classify the states of steel-concrete hybrid deck into three parts as full-composite, partial-composite, and non-composite, considering the longitudinal behavior and end-slip as well as the yield load and ultimate load of it. Also, it proved that the stress of lower steel plate at the support was increased, because of frictional forces by reaction forces in the steel-concrete hybrid deck. The end-slip did not occur near the full-composite state, but it was largely increased as the slip modulus decreased. On the basis of the EC 4, the state of steel-concrete hybrid deck classified into brittle behavior and ductile one using the end-slip of it

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Measurement of Degree of Hydrolysis of a PA66/GF Composite using a py-GC/MS analysis

  • Lee, Jong-Young;Kim, Kwang-Jea
    • Elastomers and Composites
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    • v.52 no.1
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    • pp.59-68
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    • 2017
  • The effect on the hydrolysis resistance properties by the addition of maleic anhydride grafted EMDM (MA-g-EPDM) and PP (MA-g-PP) to a PA66/GF composite was investigated with respect to the mechanical properties, thermal properties, and morphology. The degree of hydrolysis of the PA66/GF composite was measured using py-GC/MS analysis. When compared to the PA66/GFcomposite in MEG/water solution, the composites where MA-g-EPDM and MA-g-PP were added to PA66/GF showed a higher degree of hydrolysis resistance, impact strength, and thermal properties, whereas their tensile strength, tensile modulus, flexural strength and flexural modulus decreased. As immersion time in the solution increases, the rate of tensile strength drop of the MA-g-PP added composite appeared lower than that of the PA66/MA-g-EPDM/GF and PA66/GF composites. The py-GC/MS analysis confirmed the formation of PA66 hydrolysis reaction by products such as carboxylic acid and alkylamine with increasing immersion time.

Reinforcement of Polychloroprene by means of Silia and Glass Fiber (Silica와 Glass Fiber에 의한 Polychloroprene의 보강(補强))

  • Yoo, Chong-Sun;Paik, Nam-Chul
    • Elastomers and Composites
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    • v.23 no.3
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    • pp.223-229
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    • 1988
  • The effect of triazine thiol derivative on the physical properties of silica-polychloroprene(CR) composites and glass fiber(MGF)-CR composites was investigated. Optimum cure time of the MGF composites filled with 2-dibuthylamino-4, 6-dithiol-s-triazine(DBT) was the fastest one, while maximum torque was the best in case of the silica composites filled with s-triazine-2,4,6-trithiol(TAT) on the Oscillating Disk Rheometer(ODR) test. Stress-strain curves of the composites showed that the physical properties such as 100% modulus, 300% modulus, tensile strength of the silica composites filled with DBT was very satisfactory and the silica composites filled with TAT was higher density of crosslinking than other crosslinked elastomer. In aging properties, elastomer filled DBT and TAT were progress post-curing reaction with increasing of aging time and it have been improved the tensile strength and crosslinking density.

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Curing Behaviors and Viscoelastic of UPE Resins with Different Glycol Molar Ratios (글리콜 몰비가 다른 불포화 폴리에스테르 수지의 경화거동 및 점탄성)

  • Lee, Sang-Hyo;Park, Yung-Hoon;An, Seung-Kook;Lee, Jang-Oo
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.15-24
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    • 2001
  • In this study, the effects of different glycol molar ratios of unsaturated polyester(UPE) resins on the curing behaviors were investigated. The cross linking process was checked or monitored by differential scanning calorimetry(DSC) and by viscoelastic properties of rigid-body pendulum model. The knife-edge from which the pendulum is suspended, is immersed in a reaction mixture, and the change of the viscoelastic behavior brings on those of the period(T) and logarithmic decrement(${\Delta}$) of the damped free oscillations of the pendulum. The values of T and ${\Delta}$ obtained are related to the dynamic modulus(E') and modulus loss(E'). The information on the viscoelastic behavior of unsaturated polyester(UPE) resins during the curing process are shown to illustrate the usefulness of the techniques. As the content of NPG in a propylene glycol(PG)/NPG glycol mixture increased, both the cycle time during cure and the change of damping during cure of UPE resin decreased.

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Effect of (Al, Nb) Co-Doping on the Complex Dielectric Properties and Electric Modulus of BaTiO3-Based Ceramics

  • Ziheng Huang;Ruifeng Niu; Depeng Wang;Weitian Wang
    • Korean Journal of Materials Research
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    • v.34 no.7
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    • pp.321-329
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    • 2024
  • In this work, a series of BaTiO3-based ceramic materials, Ba(Al0.5Nb0.5)xTi1-xO3 (x = 0, 0.04, 0.06, 0.08), were synthesized using a standard solid-state reaction technique. X-ray diffraction profiles indicated that the Al+Nb co-doping into BaTiO3 does not change the crystal structure significantly with a doping concentration up to 8 %. The doping ions exist in Al3+ and Nb5+ chemical states, as revealed by X-ray photoelectron spectroscopy. The frequency-dependent complex dielectric properties and electric modulus were studied in the temperature range of 100~380 K. A colossal dielectric permittivity (>1.5 × 104) and low dielectric loss (<0.01) were demonstrated at the optimal dopant concentration x = 0.04. The observed dielectric behavior of Ba(Al0.5Nb0.5)xTi1-xO3 ceramics can be attributed to the Universal Dielectric Response. The complex electric modulus spectra indicated the grains exhibited a significant decrease in capacitance and permittivity with increasing co-doping concentration. Our results provide insight into the roles of donor and acceptor co-doping on the properties of BaTiO3-based ceramics, which is important for dielectric and energy storage applications.

Estimation of Coefficient of Horizontal Subgrade Reaction by the Inverse Analysis on the Lateral Load Test Results (수평재하시험 역해석을 통한 수평지반반력계수 산정)

  • Ryu, Soo-Yong;Kwak, No-Kyung;Park, Min-Chul;Jeong, Sang-Guk;Lee, Song
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.8
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    • pp.15-24
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    • 2012
  • Even though decision of coefficient of horizontal subgrade reaction is important in analysis for pile under lateral load, the behavior of pile under lateral loading is estimated differently due to using established suggestion. Therefore this study estimates coefficient of horizontal subgrade reaction by using Chang's method or numerical inverse analysis method with the result of lateral load test. Then this study investigates the adequacy and reliability for coefficient of horizontal subgrade reaction. The analytical results of coefficient of horizontal subgrade reaction with lateral load test showed that coefficient of horizontal subgrade reaction with Chang's method was underestimated as compared with inverse analysis. Deformation modulus of foundation by Standard Specifications for Highway Bridges and Eo${\fallingdotseq}$1,400~1,600N showed similar range like range of coefficient of horizontal subgrade reaction with lateral load test.

A Study on the Surface Treatment of Spectra Fibers Using an ion Assisted Reaction Method (이온도움 반응법을 이용한 스펙트라 섬유의 표면처리에 대한 연구)

  • 이경엽;신동혁;지창헌
    • Journal of the Korean institute of surface engineering
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    • v.35 no.5
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    • pp.319-324
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    • 2002
  • It is known that ion-assisted reaction method is effective for the surface modification of polymers. The surface treatment of Spectra fibers using the ion-assisted reaction method was investigated in the present study The Spectra fibers were treated by $Ar^{+}$ / ion irradiation under oxygen environment. The treatment was carried out at different $Ar^{+}$ ion doses. The$ Ar^{+ }$ /ion doses used were $6$\times$10^{15}$ , $1$\times$10^{16}$ , $5$\times$10^{16}$ , $1$\times$10^{17}$ / ions/$\m^2$. Optimal $Ar^{+}$ ion dose in the treatment of Spectra fibers was determined by measuring the tensile strength and modulus of Spectra/vinylester composites as a function of ion dose. It was found that the optimal ion dose was $1$\times$10^{16}$ions/$\m^2$. It was also found from the scanning electron microscope examination that the surface-treatment improved adhesion between fibers and vinylester resin.

Effects of Equivalent Weight of Epoxy Resins and Content of Catalyst on the Curing Reaction in Cationic Catalyst/Epoxy Cure System (양이온 촉매/에폭시 경화계에서 에폭시 수지의 당량 및 촉매 함량이 경화반응에 미치는 영향)

  • Kim, Youn Cheol;Park, Soo-Jin;Lee, Jae-Rock
    • Applied Chemistry for Engineering
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    • v.8 no.6
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    • pp.960-966
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    • 1997
  • The effects of epoxy resins and content of catalyst on the cure characteristics were studied by FT-IR, DSC and dynamic viscometer for the thermal properties and rheological properties of the catalytic (N-Benzylpyrazinium hexafluoroantimonate, BPH) epoxy thermosetting system. Compared with DSC results of DEGBF containing 0.5wt% BPH, the DSC thermograms of DGEBA containing 0.5wt% BPH indicated that the reaction was faster than that of DGEBF/BPH and the conversion rate of DGEBA/BPH was high in the initial stage of the reaction. As the concentration of BPH increases, the reaction and conversion rates show similar value in both the cases. The influence of hydroxyl group of epoxy resin on gel point defined from the crossover point of storage modulus (G') and loss modulus (G") could be explained by the formation of 3-dimensional network in the initial stage owing to the curing reaction between epoxides and hydroxyl groups of epoxy resin. This was consistent with the gel point obtained from DSC, FT-IR and moduli crossover. The activation energy (Et) obtained from the crossover point (G'/G"=1) are $31-39kJ.mol^{-1}$ for various BPH compositions in case of two epoxy systems.

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