• Title/Summary/Keyword: Reaction Modulus

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Application of Weifull강s Theory to Evaluation of Strength for Ceramic Fibers (Ceramic 섬유의 강도 평가에 대한 Weibll 이론의 적용)

  • 이지환;김현수;한상훈
    • Journal of the Korean Ceramic Society
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    • v.27 no.8
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    • pp.1043-1049
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    • 1990
  • In this work, strength of ceramic fibers and monofilament composites were evaluated on the basis of Weibull's theory. The fibers used were β-SiC and γ-Al2O3 monofilament composites was fabricated by coating Al on the fiber surface by the use of vacuum evaporation method. Average tensile strength of ceramic fibers showed the tendency to linearly decrease with increasing gauge length. Also, Weibull moduli of ceramic fibers were decreased with increasing gauge length, Weibull modulus of β-SiC was 3.5 for 6-50mm, 2.8 for 100-200mm. Weibull modulus of γ-Al2O3 was 6.5 for 20-50mm, 6 for 100mm. Fibers in monofilament retained their original as-produced strength to exposure temperature of 400℃. However, tensile strength of both monofilament composites approved to remarkably degrade due to interfacial reaction-induced flaws on the fiber surface after thermal exposure of 600℃. In this case, Weibull modulus of monofilament composites was 2.7 for β-SiC and 5.2 for γ-Al2O3 respectively.

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Viscoelastic Properties of MF/PVAc Hybrid Resins as Adhesive for Engineered Flooring by Dynamic Mechanical Thermal Analysis

  • Kim, Sumin;Kim, Hyun-Joong;Yang, Han-Seung
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.2
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    • pp.37-45
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    • 2006
  • The viscoelastic properties of blends of melamine-formaldehyde (MF) resin and poly(vinyl acetate) (PVAc) for engineered flooring used on the Korean traditional ONDOL house floor heating system were investigated by dynamic mechanical thermal analysis (DMTA). Because MF resin is a thermosetting adhesive, the effect of MF rein was shown across all thermal behaviors. The addition of PVAc reduced the curing temperature. The DMTA thermogram of MF resin showed that the storage modulus (E') increased as the temperature was further increased as a result of the cross-linking induced by the curing reaction of the resin. The storage modulus (E') of MF resin increased both as a function of increasing temperature and with increasing heating rate. From isothermal DMTA results, peak $T_{tan{\delta}}$ values, maximum value of loss modulus (E") and the rigidities (${\Delta}E$) of MF/PVAc blends at room temperature as a function of open time, peak $T_{tan{\delta}}$ and maximum loss modulus (E") values were found to increase with blend MF content. Moreover, the rigidities of the 70:30 and 50:50 MF/PVAc blends were higher than those of the other blends, especially of 100% PVAc or MF. We concluded that blends the MF/PVAc blend ratios correlate during the adhesion process.

Applicability Estimation Compaction Method of Embankment using LWDT and Geogauge (LWDT와 Geogauge를 이용한 성토지반의 다짐관리 현장적용성 평가)

  • Lim, Seong-Yoon;Song, Ho-Sung;Ryu, Hee-Ryong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.58 no.4
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    • pp.85-95
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    • 2016
  • PBT (Plate Bearing Test) is a commonly used compaction estimation used to provide basal support for embankments. This study presents the results from experimental evaluations PBT, LWDT (Light Drop Weight Tester) test and Geogauge test with embankment materials which consist in sandy soil, crushed stone and rock. The results of this study indicate that the regression analyze results (r) from test results between Young's modulus and $k_{30}$, $E_v$ are 0.385 and 0.111~0.496, estimated very lack of correlation. The Geogauge is frequency vibration from machine to underground. Geogauge can not measure to accuracy test results when it is used on ground of the rock or crushed stone. The regression analyze results (r) from $E_v$ and Dynamic modulus are 0.502~0.847, different estimated by calculate method, as it were, when calculate $E_v$, least square method are appeared more accuracy than gradient of secant.

Measurement of Shear Modulus Increment Ratio of Magneto-rheological Elastomer based on Silicon Matrix due to Induced Magnetic field (Silicon Matrix MRE 의 인가자기장에 따른 전단계수 증가율 측정)

  • Oh, Jae-Eung;Roh, Jeong-Joon;Lee, Sun-Hoon;Kim, Jin-Su;Jeong, Un-Chang
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2014.10a
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    • pp.288-291
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    • 2014
  • MRE(Magneto-rheological Elastomer) is a material which shows reversible and various modulus in magnetic field. Comparing to conventional rubber vibration isolator, MREs are able to absorb broader frequency range of vibration. These characteristic phenomena result from the orientation of magnetic particle (i.e., chain-like formation) in rubber matrix. In this study, Silicon was used as a matrix in order to manufacture MREs. Magnetic reactive powder(MRP), having rapid magnetic reaction, was selected as a magnetic particle to give magnetic field reactive modulus. The mechanical properties of manufactured MREs were measured with the application of magnetic field. The analysis of MR effect was carried out by FFT analyzer with various induced magnetic field. As the addition of CIP and induced magnetic field intensity increased, increment of MR effect was observed.

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Evaluation of Field Nonlinear Modulus of Subgrnde Soils Using Repetitive Static Plate Bearing Load Test (반복식 평판재하시험을 이용한 노상토의 현장 변형계수 평가)

  • Kim Dong-Soo;Seo Won-Seok;Kweon Gi-Chul
    • Journal of the Korean Geotechnical Society
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    • v.21 no.6
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    • pp.67-79
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    • 2005
  • The field plate load test has a good potential for determining modulus since it measures both plate pressure and settlement. Conventionally the modulus has been assumed to be a constant secant value defined from the settlement of the plate at a given load intensity. A constant modulus (modulus of subgrade reaction, k), however, may not be a representative value of subgrade soil under working load. Field strain(o. stress)-dependent modulus characteristics of subgrade soils, at relatively low to intermediate strains, are important in the pavement design. In this study, the field strain dependent moduli of subgrade soils were obtained using cyclic plate load test. Testing procedure and data reduction method are proposed. The field crosshole and laboratory resonant column tests were also performed to determine field nonlinear modulus at $0.001\%\;to\;0.1\%$ strains, and the modulus values and nonlinear trends are compared to those obtained by cyclic plate load tests. Both modulus values match relatively well when the different state of stress between two tests was considered, and the applicability of field cyclic plate load test for determining nonlinear modulus values of subgrade soils is verified.

The Effects of Blend Composition and Blending Time on the Ester Interchange Reaction and Tensile Properties of PLA/LPCL/HPCL Blends

  • Yoon, Cheol-Soo;Ji, Dong-Sun
    • Fibers and Polymers
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    • v.4 no.2
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    • pp.59-65
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    • 2003
  • PLA/LPCL/HPCL blends composed of poly(lactic acid) (PLA), low molecular weight poly($\varepsilon$-caprolactone) (LPCL), and high molecular weight poly($\varepsilon$-caprolactone) (HPCL) were prepared by melt blending for bioabsorbable fila-ment sutures. The effects of blend composition and blending time on the ester interchange reaction by alcoholysis in the PLA/LPCL/HPCL blends were studied. Their thermal properties and the miscibility due to the ester interchange reaction were investigated by $^1{H-NMR}$, DSC, X-ray, and UTM analyses. The hydroxyl group contents of LPCL in the blends decreafed by the ester interchange reaction due to alcoholysis. Thus, the copolymer was formed by the ester interchange reaction at $200^{\circ}C$ for 30-60 minutes. The thermal properties of PLA/LPCL/HPCL blends such as melting temperature and heat of fusion decreased with increasing ester interchange reaction levels. However, the miscibility among the three poly-mers was improved greatly by ester interchange reaction. Tensile strength and modulus of PLA/LPCL/HPCL blend fibers increased with increasing HPCL content, while the elongation at break of the blend fibers increased with increasing LPCL content.

Thermal Characteristics of SiC Whisker Reinforced $Al_2$O$_3$-SiC Composite (SiC 휘스커 보강 $Al_2$O$_3$-SiC 복합체의 열간특성)

  • 김윤주;나용한
    • Journal of the Korean Ceramic Society
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    • v.35 no.1
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    • pp.1-4
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    • 1998
  • SiC whisker reinforced Al2O3-SiC composite was fabricated by reaction synthesis method whish is cost ef-fective and allows good dispersion of whiskers. Fracture strength at room temperature showed the highest value with 150$0^{\circ}C$ reaction temperature because a lot of SiC whiskers was formed. Fracture strength at 135$0^{\circ}C$ did not show big differences with reaction temperature due to agglomeration of whiskers and formation of sil-icon oxynitride during hot MO(modulus of rupture) test probably promoting grain boundary sliding.

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Reaction Rates for the Oxidation of Pitch based Carbon Fibers in Air and Carbon Dioxide Gas

  • Roh, Jae-Seung
    • Carbon letters
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    • v.4 no.4
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    • pp.185-191
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    • 2003
  • Two types of carbon fiber based high modulus- and isotropic-pitch were exposed to isothermal oxidation in air and $CO_2$ gas and the weight change was measured by TGA apparatus. The kinetic equation was introduced $f=1-{\exp}(-at^b)$ and the constant b was obtained in the range of 1.02~1.68 for the isotropic fiber and obtained 0.91~1.93 for the high modulus fiber respectively. In considering the effect of the atmosphere for isothermal oxidation, the value of the constant b obtained in the carbon dioxide was higher than that obtained in the air. Therefore, it was found that the pitch based carbon fiber shows sigmoidal characteristic when it is oxidized in the carbon dioxide. In addition, it was also found that $k_f = 0.5$, which was reaction constant at f = 0.5, was a very useful parameter for evaluation of the oxidation reactivity of pitch based carbon fibers. According to the consideration, it is suggested that the conversion-time curves of the pitch based carbon fibers are correlated by normalized equation $f=1-{\exp}(-A{\tau}^B)$, where ${\tau}=t/t_f= 0.5$.

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