• 한국자동차공학회논문집
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• 제6권6호
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• pp.218-225
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• 1998

FTIR spectroscopy, useful technology for simultaneous and continuous measurement of the various components of the automotive exhaust gas, is utilized to investigate catalytic reaction charactristics of methane and a few unregulated exhaust emissions of NGV. Major findings are (1) catalytic reaction characteristics of methane measured in unsteady states of varying temperature are similar to those measured in steady states, (2) about 24 % of NO was oxidized to $NO_2$ as soon as they encounter catalysts, (3) study of formaldehyde suffers from difficulties in measurement due to the proximity in wavenumber of formaldehyde and methane, and requires an analyzer of higher resolution and accuracy than used in this study.

• 분석과학
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• 제19권3호
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• pp.203-210
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• 2006

Octopole reaction cell inductively coupled plasma mass spectrometer (ORC-ICP-MS)를 이용하여 우유 분말시료 중 극미량의 셀레늄(Se)을 정량하였다. 반응가스로 $H_2$를 사용함으로써 극미량 측정에서 발생되는 다원자 이온 종들과 공존 원소에 의해 발생되는 분자들의 방해를 현저하게 제거하였다. Normal mode에 비해서 $H_2$ cell gas mode는 정확성과 정밀성을 크게 향상시켰으며, 우유 표준시료의 보증 값에 비해 정량한 결과는 평균 102.7%로 약간 높게 나타났고, 5회 정량한 값에 대한 상대표준편차는 7.6%이었다.

• 한국가스학회지
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• 제21권3호
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• pp.1-8
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• 2017

이 연구의 목적은 회분식 반응기에서 반응폭주에 의하여 2상(기상-액상)에서 적용가능한 파열판의 크기를 설계하는 방안을 제시하는 것이다. 반응폭주의 정의는 제어가 되지 않은 냉각수 투입불가 또는 운전조건의 이탈에 의한 비정상적으로 발열반응을 말한다. 이 결과로 반응기의 온도는 급격히 증가하게 된다. 반응폭주의 원인은 크게 자기과열반응과 지연반응으로 구분한다. 일반적인 안전밸브나 파열판의 내경 크기로는 폭주반응시에는 적절하게 압력을 해소할 수 없다. 폭주반응 시 반응온도 및 압력이 급격하게 증가하기 때문에 안전밸브로 분출되는 내용물은 2상이다. 이 연구에서는 최근 회분식 반응기의 폭주반응으로 인하여 사고사례의 원인을 분석하고, 2 상으로 분출현상 및 특징을 설정하고, 이에 적절한 파열판의 크기를 설계하여 적용하는 방안을 제시하고자 한다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.91.1-91.1
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• 2010

The Reforming system is an effective method to generate hydrogen which uses for fuel cell system. The purpose of this study is to present characteristics of an autothermal reformer at various operating conditions and to investigate ideal conditions for reforming efficiency. Dominant chemical reactions are Full Combustion, Steam Reforming reaction, Water-Gas Shift reaction and Direct Steam Reforming reaction. Operating parameters of the autothermal reformer are inlet temperature, Oxygen to Carbon Ratio, Steam to Carbon Ratio and Gas Hourly Space Velocity. Autothermal reformer is filled with catalysis of a packbed-bed type. Using numerical approach, we have investigated on various reaction conditions.

• 한국지하수토양환경학회:학술대회논문집
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• 한국지하수토양환경학회 2001년도 추계학술발표회
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• pp.103-106
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• 2001

A remediation technology consisting of biodegradation and a modified Fenton reaction was developed to degrade mixtures of polycyclic aromatic hydrocarbons (PAHs) at a former manufactured gas plant (MGP) site. The original Fenton reaction (i.e., $H_2O$$_2$ + Fe$^{2+}$) was modified to be biocompatible by using ferric ions and chelating agents such as catechol and gallic acid. The modified reaction was effective in degrading PAHs at near neutral pH and thus was compatible with biodegradation. By the combined treatment of the modified Fenton reaction and biodegradation, more than 98% of 2- or 3-ring hydrocarbons and between 70 and 85% of 4- or 5-ring compounds were degraded in the MGP soil, while maintaining its pH about 6.6.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2011년도 춘계학술대회 초록집
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• pp.156.2-156.2
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• 2011

본 연구에서는 일단 수성가스전이반응 (Single stage water gas shift reaction)을 위해 높은 활성을 가진 백금 담지 촉매를 함침법 (Incipient wetness impregnation method)으로 제조하여 높은 공간 속도 (Gas hourly space velocity) $45,515h^{-1}$에서 담체에 따른 촉매 활성을 평가하였다. 담체는 $CeO_2$, $ZrO_2$, MgO, MgO-$Al_2O_3$ (MgO = 30 wt%) 그리고 $Al_2O_3$를 사용하였으며 백금의 담지량은 1 wt%로 고정하였다. BET, XRD, TPR, CO-chemisorption 분석을 통하여 담체의 구조적 특성이 촉매 활성에 미치는 영향에 대하여 조사하였다.

• Environmental Engineering Research
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• 제10권3호
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• pp.122-130
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• 2005

Gasification of carbonaceous wastes such as shredded tire, waste lubricating oil, plastics, and powdered coal initiates a single-stage reforming reactor(reformer) Without catalyst and a syngas burner. Syngas is combusted with $O_2$ gas in the syngas burner to produce $H_2O\;{and}\;CO_2$ gas with exothermic heat. Reaction products are introduced into the reforming reactor, reaction heat from syngas burner elevates the temperature of reactor above $1,200^{\circ}C$, and hydrogen gas fraction reaches 65% of the product gas output. Reactants and heat necessary for the reaction are provided through the syngas burner only. Neither $O_2$ gas nor steam is injected into the reforming reactor. Multiple syngas burners may be connected to the reforming reactor in order to increase the syngas output, and the product syngas is recycled into syngas burner.

• 한국수소및신에너지학회논문집
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• 제34권4호
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• pp.327-333
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• 2023

The water gas shift reaction was carried out using the commercial catalyst pellet and the simulated gases expected to occur from waste plastic gasification. In the water gas shift reaction, the high temperature shift reaction and the low temperature shift reaction were continuously performed with CO:H₂O ratio of 1:2, 1:2.5, and 1:3, and the CO conversion and H₂ increase rate were evaluated. The H₂ increase rate increased in order to CO:H₂O ratio of 1:3 > CO:H₂O ratio of 1:2.5 > CO:H₂O ratio of 1:2. The CO conversion showed a high value of more than 97% at each CO:H₂O ratio. The water gas shift reaction at a CO:H₂O ratio of 1:3 showed the highest H2 increase rate and CO conversion.

• 대한인간공학회지
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• 제31권3호
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• pp.463-467
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• 2012

This study aims to empirically investigate population stereotype of burner-control linkage of four-stove gas range for Koreans. Background: The previous studies' results for gas range stereotypes were different depending upon methods adopted, i.e., whether using questionnaires, computer simulation or physical models. It is known that the physical model experiment should not be methodologically replaced by the computer simulation or paper-and-pencil tests. Stereotype of gas range for Koreans was surveyed based on questionnaires, but has not been dealt with by using physical models. Method: An experiment was conducted to investigate stereotype of four-burner gas range, in which 32 subjects participated and a real gas range available in the market was bought and used. Four types of burner-control linkage were used as independent variable, and reaction time as dependent variable. Results: ANOVA revealed that four types of burner-control linkage and subjects' gender were not significant on reaction time. Duncan's multiple range test showed that reaction times for type III was significantly lower than those for the other three types of burner-control linkage(${\alpha}$=0.05). Conclusion: It is concluded based on the results of this study that stereotype of gas range for Koreans is type III. This is in agreement with results of existing studies using questionnaire survey, while different from those based on physical models. Application: The results of this study would be useful as an ergonomic guideline when designing gas ranges or similar equipments for minimizing operation errors.

• 항공우주기술
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• 제8권2호
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• pp.122-126
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• 2009

KSLV-I은 100kg급 소형 인공위성을 지구 저궤도에 진입시키는 임무를 수행하여야 하며, 이를 위해 상단의 3축 자세제어를 위한 자세제어 시스템이 요구된다. 추력기 노즐을 통해 질소가스를 방출함으로써 발생하는 작용 반작용 모멘트를 제어모멘트로 사용하는 냉가스 추력기 자세제어 시스템을 KSLV-I 상단의 3축 자세제어 시스템으로 선정하였다. 충전 시스템의 유량 검증 및 충전 시나리오 작성을 위해 지상 충전 시스템 개발 전단계로 충전모사 시스템의 개발이 필요하다. 본 논문에서는 KSLV-I 충전 모사 시스템의 오리피스 설계, 시스템 개발, 충전 시험에 관한 것이다.