• 제목/요약/키워드: Reaction Dynamics

검색결과 389건 처리시간 0.025초

불가사리 채집용 4절 링크 매니퓰레이터의 최적 설계 (Optimal Design of a Four-bar Linkage Manipulator for Starfish-Capture Robot Platform)

  • 김지훈;진상록;김종원;서태원;김종원
    • 한국정밀공학회지
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    • 제30권9호
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    • pp.961-968
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    • 2013
  • In this paper, we propose an optimal design for starfish capturing manipulator module with four-bar linkage mechanism. A tool link with compliance is attached on the four-bar linkage, and the tool repeats detaching starfish from the ground and putting it into the storage box. Since the tool is not rigid and the manipulator is operating underwater, the trajectory of the tool tip is determined by its dynamics as well as kinematics. We analyzed the trajectory of the manipulator tool tip by quasi-static analysis considering both kinematics and dynamics. In optimization, the lengths of each link and the tool stiffness are considered as control variables. To maximize the capturing ability, capturing stroke of the four-bar manipulator trajectory is maximized. Reaction force and reaction moment, and other kinematic constraints were considered as inequality constraints.

발전용 대형 엔진 적용을 위한 천연가스-디젤 혼소에 대한 수치 해석적 연구 (Numerical Study on Co-Combustion in Diesel Engine for Heavy-Duty Power Generation)

  • 서동균;허광범;정연태;김의현
    • 한국수소및신에너지학회논문집
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    • 제26권4호
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    • pp.369-376
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    • 2015
  • Recently KEPCO, KOGAS and other institutions are jointly conducting an R&D for the development and demonstration of the power generation system based on a natural gas/diesel engine on an island. As a preliminary study, co-combustion in the dual fuel engine, which is expected to produce a few mega-watts of electricity, was modeled and calculated using computational fluid dynamics (CFD). The applied key assumptions are 2-dimensional axisymmetric, transient and static volume chemical reaction. Based on the selected blending ratio, which is the key operating condition, natural gas is substituted instead of diesel fuel (basis of high heating value). Results showed that as the blending ratio increases, the reaction rate of the combustion increases and thus maximum temperature is reached more rapidly. For the optimal performance, various geometric or operational studies will further be conducted.

Dynamics of Hydrogen Molecules Priduced on a Graphite Surface

  • Ko, Yoon-Hee;Ree, Jong-Baik;Kim, Yoo-Hang;Shin, Hyung-Kyu
    • Bulletin of the Korean Chemical Society
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    • 제23권12호
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    • pp.1737-1743
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    • 2002
  • We have studied the dynamics of energy-rich hydrogen molecules produced on a graphite surface through H(g) + H(ad)/C(gr) → $H_2$ + C(gr) at thermal conditions mimicking the interstellar medium using a classical trajectory procedure. The recombination reaction of gaseous H atom at 100 K and the adsorbed H atom on the interstellar graphite grains at 10 K efficiently takes place on a subpicosecond time scale with most of the reaction exothermicity depositing in the product vibration, which leads to a strong vibrational population inversion. The molecules produced in nearly end-on geometry where H(g) is positioned below H(ad) rotate clockwise and are more highly rotationally excited. but in low-lying vibrational levels. The rotational axis of most of the molecule rotating clockwise is tilted from the surface normal by more than 30°, the intensity peaking at 35°. The molecules produced when H(ad) is close to the surface rotate counter-clockwise and are weakly rotationally excited, but highly vibrationally excited. These molecules tend to align their rotational axes parallel to the surface. The number of molecules rotating clockwise is eight times larger than that rotating counter-clockwise.

Time-resolved Anisotropy Study on the Excited-State Intramolecular Proton Transfer of 1-Hydroxyanthraquinone

  • Choi, Jun-Rye;Jeoung, Sae-Chae;Cho, Dae-Won
    • Bulletin of the Korean Chemical Society
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    • 제24권11호
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    • pp.1675-1679
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    • 2003
  • The photodynamics of excited-state intramolecular proton transfer reaction of 1-hydroxyanthraquinone (1-HAQ) and 1-deuterioanthraquinone was investigated in toluene with time-resolved emission and femtosecond transient transmittance techniques at room temperature. The temporal profiles of transient transmittance of 1-HAQ could be well described with multi-decaying time constants. The ultrafast time constant within ca. 260 fs reflects the dynamics of proton transfer. The decay component of 2 ps is assigned to an additional proton translocation process induced by the intramolecular vibrational relaxation, whereas the decay component of 18 ps is assigned to the vibrational cooling process, while the long component (200 ps) can be explained in terms of the relaxation from excited-state keto-tautomer to its ground state. Time-resolved anisotropy decay dynamics and isotope effects on the photodynamics reveals that the ESIPT from enol-tautomer to keto-one of 1-HAQ is barrierless reaction and coupled to a vibrational relaxation process.

다공성 분리판을 적용한 고분자 전해질 연료전지의 유동 분포에 관한 전산해석 연구 (Numerical Study on Flow Distribution in PEMFC with Metal foam Bipolar Plate)

  • 송명호;김경연
    • 한국수소및신에너지학회논문집
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    • 제27권1호
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    • pp.29-35
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    • 2016
  • It is important to uniformly supply the fuel gas into the reaction activity area in polymer electrolyte membrane fuel cell (PEMFC). Recent studies have shown that the cell performance can be significantly improved by employing metal foam gas distributor as compared with the conventional bipolar plate types. The metal foam gas distributor has been reported to be more efficient to fuel transport. In this study, three-dimensional computational fluid dynamics (CFD) simulations have been performed to examine the effects of metal foam flow field design on the fuel supply to the reaction site. Darcy's law is used for the flow in the porous media. By solving additional advection equation for fluid particle trajectory, the gas transport has been visualized and examined for various geometrical configuration of metal foam gas distributor.

Evaluation of Structural Safety of Electro-Mechanical Linear Actuator and Load Simulator with Plate Spring

  • Kim, Dong-Hyeop;Kim, Young-Cheol;Kim, Sang-Woo;Lee, Jong Whan
    • 항공우주시스템공학회지
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    • 제14권6호
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    • pp.18-25
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    • 2020
  • This study investigated the structural behaviors and safety of an electro-mechanical linear actuator and a load simulator with a plate spring. The material and dimensions of the plate spring were determined by theoretically calculating the stress and torsional angle for the rating load of the actuator. Thereafter, a flexible multibody dynamics (FMBD) analysis was conducted on the linear actuator and load simulator to confirm the performance of the load simulator and acquire the reaction forces acting on the actuator and simulator. The structural safety of the linear actuator and load simulator was evaluated via finite element analysis using the aforementioned reaction forces. Consequently, the proposed linear actuator and load simulator were determined to be structurally safe; however, the safety factors for the actuation rod and the housing on the actuator were excessively high. Therefore, the weight and cost must be reduced to improve their design parameters in the future.

Computational Analysis on Calcium Dynamics of Vascular Endothelial Cell Modulated by Physiological Shear Stress

  • Kang, Hyun-Goo;Lee, Eun-Seok;Shim, Eun-Bo;Chnag, Keun-Shik
    • International Journal of Vascular Biomedical Engineering
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    • 제3권2호
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    • pp.1-9
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    • 2005
  • Flow-induced dilation of blood vessel is the result of a series of bioreaction in vascular endothelial cells(VEC). Shear stress change by blood flow in human artery or vein is sensed by the mechanoreceptor and responsible for such a chain reaction. The inositol(1,4,5)-triphophate($IP_3$) is produced in the first stage to elevate permeability of the intercellular membrane to calcium ions by which the cytosolic calcium concentration is consequently increased. This intracellular calcium transient triggers synthesis of EDRF and prostacyclin. The mathematical model of this VEC calcium dynamics is reproduced from the literature. We then use the Computational Fluid Dynamics(CFD) technique to investigate the blood stream dictating the VEC calcium dynamics. The pulsatile blood flow in a stenosed blood vessel is considered here as a part of study on thrombogenesis. We calculate the pulsating shear stress (thus its temporal change) distributed over the stenosed artery that is implemented to the VEC calcium dynamics model. It has been found that the pulsatile shear stress induces larger intracellular $Ca^{2+}$ transient plus much higher amount of EDRF and prostacyclin release in comparison with the steady shear stress case. It is concluded that pulsatility of the physiological shear stress is important to keep the vasodilation function in the stenosed part of the blood vessel.

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기포 유동층 반응기내 목질계 바이오매스의 급속열분해 특성 (THE FAST PYROLYSIS CHARACTERISTICS OF LIGNOCELLULOSIC BIOMASS IN A BUBBLING FLUIDIZED BED REACTOR)

  • 최항석
    • 한국전산유체공학회지
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    • 제16권2호
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    • pp.94-101
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    • 2011
  • The fast pyrolysis characteristics of lignocellulosic biomass are investigated for a bubbling fluidized bed reactor by means of computational fluid dynamics (CFD). To simulate multiphase reacting flows for gases and solids, an Eulerian-Eulerian approach is applied. Attention is paid for the primary and secondary reactions affected by gas-solid flow field. From the result, it is scrutinized that fast pyrolysis reaction is promoted by chaotic bubbling motion of the multiphase flow enhancing the mixing of solid particles. In particular, vortical flow motions around gas bubbles play an important role for solid mixing and consequent fast pyrolysis reaction. Discussion is made for the time-averaged pyrolysis reaction rates together with time-averaged flow quantities which show peculiar characteristics according to local transverse location in a bubbling fluidized bed reactor.

반작용 휠의 외란에 의한 STSAT-3 지터 분석 (Analysis of STSAT-3 Jitter due to the Reaction Wheel Disturbance)

  • 김동훈;전동익;오화석;이상철;방효충;이승우
    • 항공우주시스템공학회지
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    • 제1권3호
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    • pp.32-36
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    • 2007
  • When the reaction wheel rotates, the disturbance occurs mainly due to the mass imbalance. It is necessary to predict the effect of disturbance on the attitude stability of the satellite. The disturbance forces and torques are identified and the attitude jitter of the satellite is analyzed depending on the configuration of the wheels. On the analysis the equation of the satellite motion is combined with the translational and rotational dynamics of the wheels. The accuracy of analysis is verified by simulation of STSAT-3 satellite.

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Mapping Between Models for Pathway Dynamics and Structural Representations of Biological Pathways

  • Yavas, Gokhan;Ozsoyoglu, Z. Meral
    • 한국생물정보학회:학술대회논문집
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    • 한국생물정보시스템생물학회 2005년도 BIOINFO 2005
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    • pp.415-420
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    • 2005
  • Mathematical modeling and simulation of biochemical reaction networks gained a lot of attention recently since it can provide valuable insights into the interrelationships and interactions of genes, proteins and metabolites in a reaction network. A number of attempts have been made for modeling and storing biochemical reaction networks without their dynamical properties but unfortunately storing and efficiently querying of the dynamic (mathematical) models are not yet studied extensively. In this paper, we present a novel nested relational data schema to store a pathway with its dynamic properties. We then show how to make the mapping between this dynamic pathway schema with the corresponding static pathway representation.

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