• Title/Summary/Keyword: Reacting Flow

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Catalytic Combustion Characteristics of Hydrogen-Air Premixture in a Millimeter Scale Monolith Coated with Platinum (밀리미터 스케일 촉매 연소기에서의 수소-공기 예혼합 가스의 촉매 연소 특성)

  • Choi, Won-Young;Kwon, Se-Jin
    • Journal of the Korean Society of Combustion
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    • v.10 no.1
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    • pp.20-26
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    • 2005
  • In the present study, catalytic combustion of hydrogen-air premixture in a millimeter scale monolith coated with Pt catalyst was investigated. As the combustor size decreases, the heat loss increases in proportion with the inverse of the scale of combustion chamber and combustion efficiency decreases in a conventional type of combustor. Combustion reaction assisted by catalyst can reduce the heat loss by decreasing the reaction temperature at which catalytic conversion takes place. Another advantage of catalytic combustion is that ignition is not required. Platinum was coated by incipient wetness method on a millimeter scale monolith with cell size of $1{\times}1mm$. Using this monolith as the core of the reaction chamber, temperatures were recorded at various locations along the flow direction. Burnt gas was passed to a gas chromatography system to measure the hydrogen content after the reaction. The measurements were made at various volume flow rate of the fuel-air premixture. The gas chromatography results showed the reaction was complete at all the test conditions and the reacting species penetrated the laminar boundary layer at the honeycomb and made contact with the catalyst coated surface. At all the measuring locations, the record showed monotonous increase of temperature during the measurement duration. And the temperature profile showed that the peak temperature is reached at the point nearest to the gas inlet and decreasing temperature along the flow direction.

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Numerical Study on the Effect of Volume Change of Light-Off Catalyst on Light-Off Performance (저온활성촉매변환기의 체적변화가 활성화 성능에 미치는 영향에 관한 수치적 연구)

  • 정수진;김우승
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.6
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    • pp.87-100
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    • 2000
  • HC and CO emissions during the cold start contribute the majority of the total emissions in the legislated driving cycles. Therefore, in order to minimize the cold-start emissions, the fast light-off techniques have been developed and presented in the literature. One of the most encouraging strategies for reducing start-up emissions is to place the light-off catalyst, in addition to the main under-body catalyst, near the engine exhaust manifold. This study numerically consider three-dimensional, unsteady compressible reacting flow in the light-off and under body catalyst to examine the impact of a light-off catalyst on thermal response of the under body catalyst and tail pipe emission. The effect of flow distribution on the temperature distribution and emission performance have also been examined. The present results show that flow distribution has a great influence on the temperature distribution in the monolith at the early stage of warm-up process and the ultimate conversion efficiency of light-off catalyst is severly deteriorated when the space velocity is above $100,000hr^{-1}$.

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Numerical Design of Auto-Catalyst Substrate for Improved Conversion Performance Using Radially Variable Cell Density (변환효율 향상을 위한 횡방향 가변 셀밀도법을 사용한 자동차용 촉매변환기의 수치적 설계)

  • Jeong, Su-Jin;Kim, U-Seung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.24 no.12
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    • pp.1596-1607
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    • 2000
  • The optimal design of auto-catalyst needs a good compromise between the pressure drop and flow uniformity in the substrate. One of the effective methods to achieve this goal is to use the concept of radially variable cell density. But this method has not been examined its usefulness in terms of chemical behavior and conversion performance. In this work, two-dimensional performance prediction of catalyst coupled with turbulent reacting flow simulation has been used to evaluated the benefits of this method n the flow uniformity and conversion efficiency. The results showed that two cell combination of 93cpsc and 62 cpsc was the most effective for improved pressure drop and conversion efficiency due to balanced space velocity and efficient usage of geometric surface area of channels. It was also found that large temperature difference between the bricks in case that the edge of the frontal face of brick has too much lower cell density(less than 67% of cell density of the center of the brick). This study has also demonstrated that the present computational results show the better prediction accuracy in terms of CO, HC and NO conversion efficiencies compared to those of conventional 1-D adiabatic model by comparison with experimental results.

A Large-scale Structural Mixing Model applied to Blowout of Turbulent Nonpremixed Jet Flames in a Cross Jet Flow (횡분류(流)(橫噴流)에서 난류 비예흔합 화염의 화염날림에 대한 거대 와(渦)구조 혼합 모텔 적용)

  • Lee, Kee-Man;Park, Jeong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.1
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    • pp.133-140
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    • 2002
  • This article presents an application of a large-scale structural mixing model(Broadwell et at. 1984) to the blowout of turbulent reacting cross flow jets. Experimental observations, therefore, aim to identify the existence of large-scale vortical structure exerting an important effect upon the flame stabilization. In the analysis of common stability curve, it is seen that the phenomenon of blowout are only related to the mixing time scale of the two flows. The most notable observation is that the blowout distance is traced at a fixed positions according to the velocity ratio at all times. Measurements of the lower blowout limits in the liftable flame are qualitatively in agreement with the blowout parameter $\xi$, proposed by Broadwell et al. Good agrement between the results calculated by a modified blowout parameter $\xi$'and the present experimental results confirms the important effect of large-scale structure in the stabilization feature of blowout.

Structure and Characteristics of Diffusion Flaame behind a Bluff-body in a Divergent Flow(II) (확대유로내의 Bluff-Body 후류확산화염의 구조 및 특성 2)

  • ;;Lee, Joong Sung
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.11
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    • pp.2981-2994
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    • 1995
  • In order to elucidate the effects of positive pressure gradient on flame properties, structure and stabilization, an experimental study is made on turbulent diffusion flame stabilized by a circular cylinder in a divergent duct flow. A commercial grade gaseous propane is injected from two slits on the rod as fuel. In this paper, stabilization, characteristics and flame structure are examined by varying the divergent angle of duct. Temperature, ion current and Schlieren photographs were measured. It is found that critical divergent angle is expected to be about 8 ~ 12 degree through blow-off velocity pattern to divergent angle and the positive pressure gradient influences the flame temperature, intensity of ion current and eddy structure behind the rod. With the increase of divergent angle, typical temperature of recirculation zone is low but intensity of ion current is high in shear layer behind rod. Energy distributions of fluctuating temperature and ion current signals turn up low frequency corresponding to large scale eddies but high frequency corresponding to small scale eddies as well as low with the increase of divergent angle. Therefore the flame structure becomes a typical distributed-reacting flame.

Combustion Stability and the Properties of Methane/Air Mixture Subjected to Unsteady Flow Fluctuations (비정상 유동의 메탄/공기 혼합기 반응안정성 효과 연구)

  • Lee, Eui-Ju;Oh, Chang-Bo
    • Journal of the Korean Society of Safety
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    • v.26 no.5
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    • pp.1-6
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    • 2011
  • Flame extinction and the chemistry of stoichiometric methane/air mixture were investigated numerically in the PSR(perfectly stirred reactor). For the study, PSR code was modified to be possible to unsteady calculation, and the sinusoidal fluctuation was subjected to the residence time. In the region of residence time far from the extinction limit, combustion mode was strongly dependent on the frequency. The low frequency excitation provided the quasi-steady behavior on the temperature and the concentrations of related species, but small variation of temperature was observed under high frequency. In the region of residence time near the extinction limit, the mixture subjected above 1 KHz was still reacting even though extinction had to be occurred under quasi-steady concept. The attenuation of extinction limit resulted from that chemical time was comparable to the flow time. The mean mole fractions of both NO and CO were almost same regardless of imposed frequency. However, the average mole fraction of $C_2H_2$ was decreased as increasing frequency, which implies that soot yield might be reduced at the higher frequency of flow excitation. The result provides the basic concept for flame stabilization, and it will be used to design a mild combustor.

Analysis of the Thermal Processes in the Iron-Making Facility - Modeling Approach (제선 설비의 열공정 해석 모델링 접근 방법)

  • Yang, Won;Ryu, Chang-Kook;Choi, Sang-Min;Choi, Eung-Soo;Ri, Deok-Won;Huh, Wan-Wook
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.7
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    • pp.747-754
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    • 2004
  • Thermo-fluid characteristics in coke oven, sintering machine and blast furnace in iron-making facility are key processes related to the quality and productivity of the pig iron. Solid material in the processes usually forms a bed in a gas flow. For simulation of the processes by mathematical model, the solid beds are idealized to be a continuum and a reacting solid flow in the gas flow. Governing equations in the form of partial differential equations for the solid material can be constructed based on this assumption. Iron ore sintering bed is simulated and limited amount of parametric study have been performed. The results have a good agreement with the experimental results or physical phenomena, which shows the validity and applicability of the model.

Chemical Reacting Flow Analysis of the 30 tonf - class KARl LRE Nozzle (KARI 30톤급 액체로켓엔진 노즐 유동 화학 반응 해석)

  • Lee, Dae-Sung;Kang, Ki-Ha;Cho, Duck-Rae;Choi, J.Y.;Choi, H.S.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.105-109
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    • 2007
  • Three methods of nozzle flow analysis, frozen-equilibrium, shifting-equilibrium and non-equilibrium approaches, were used to rocket nozzle flow, those were coupled with the methods of computational fluid dynamics code. For a design of high temperature rocket nozzle, chemical equilibrium analysis which shares the same numerical characteristics with frozen flow analysis can be an efficient design tool for predicting maximum thermodynamic performance of the nozzle. In this study, shifting-equilibrium flow analysis was carried out for the 30 $ton_f$-class KARl liquid rocket engine nozzle together with frozen flow. The performance evaluation based on the 30 $ton_f$-class KARl LRE nozzle flow analyses will provide an understanding of the thermochemical process in the nozzle and performances of nozzle.

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Characteristics of the Transverse Fuel Injection into a Supersonic Crossflow using Various Injector Geometries (분사구 형상에 따른 초음속 유동장 내 수직 연료 분사 특성)

  • Kim, Seihwan;Lee, Bok Jik;Jeung, In-Seuck;Lee, Hyoungjin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.3
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    • pp.53-64
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    • 2018
  • In this study, computational simulation was performed to investigate the characteristics of air/fuel mixing according to the shape of the injector exit when the transverse jet was injected into a supersonic flow. Non-reacting flow simulation was conducted with fixed mass flow rate and the same cross-sectional area. To validate the results, free stream Mach number and jet-to-crossflow memetum ratio are set to 3.38 and 1.4, respectively, which is same as the experimental condition. Further, separation region, structure of the under-expended jet, jet penetration height, and flammable region of hydrogen for five different injectors compared.

Numerical Study for the Reacting Characteristics of Orimulsion Gasification (오리멀젼의 가스화 반응 특성에 관한 수치해석 연구)

  • 나혜령;이진욱;윤용승
    • Journal of Energy Engineering
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    • v.8 no.2
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    • pp.309-316
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    • 1999
  • A numerical study for the turbulent reacting flow in an orimulsion gasifier has been carried out to analyze the characteristics of chemical reaction by orimulsion droplets. In this study, our interest has been focused on the effect of oxidizer to orimulsion ratio, which is one of the key parameters of gasification operation, as well as on the distribution of chemical species. In addition, we have conducted numerical calculations to understand the effect of droplet size, spray angle and injection velocity of fuel so as to acquire the basic information on the operating range of orimulsion gasifier. The result of numerical calculations showed that the gas composition of CO and H$_2$concentrations was the highest when the oxidizer to orimulsion ratio was about 0.88 and the reactivity of orimulsion increased as the droplet size reduced with proper spray angle. Also, we have carried out the analysis on the orimulsion gasification in the 100 ton/day-scale gasifier based upon the prior study in order to obtain the basic data for the proper operating condition using orimulsion feed.

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