• Title/Summary/Keyword: Rb-Sr

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Geochronology and Cooling history of the Mesozoic Granite Plutons in the Central Part of the Ogcheon Fold Belt, South Korea (남한 습곡대 중앙부의 중생대 화강암 질암의 생선년대와 냉각사)

  • Myung-Shik JIN
    • The Journal of the Petrological Society of Korea
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    • v.4 no.2
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    • pp.153-167
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    • 1995
  • Emplacement ages for the granite plutons of the Jurassic and the Cretaceous times in the central Ogcheom Fold Belt were determined by Rb-Sr whole rock and mineral isocheon methods. In addition mineral ages for the plutons were determined by K-Ar and fission track methods. In turn, thermal histories and uplifting rates of the granitic bodies are elucidated from the isotopic ages. The Jecheon(~203 Ma) and Mungyeong(at lest~200 Ma) granites of the Jurassic and the Muamsa, Wolagsan and Daeyasan granites(~110 Ma) of the Cretaceous show high strontium initial ratios [$(^{87}Sr/^{86}Sr)_1$0.7100],suggesting that the granitic magmas have been generated by partial melting of crustal materials (S-type), or by mixing of mantle and crustal materials. Only mineral ages of the Sogrisan and Hyeongjebong granites (~90 Ma) were determined by K-Ar method, and petrogenesis of them were not defined yet. The two Jurassic granite plutons were cooled rapidly down to $300^{\circ}C$, right after the plutons were slowly cooled down since then, due to their deep emplacment. During the Middle Cretaceous period, the Jurassic Mungyeong granitic pluton was intruded and thermally affected much by the surrounding Wolagsan and Daeyasan granites. Accordingly the Rb-Sr mineral age, K-Ar hornblende and biotite ages of the Mungyeong granite appear to be reduced or reset due to the thermal effects above their blocking temperatures. All the cretaceous granites have been cooled much ore simply and rapidly down than the Jurassic ones below $300^{\circ}C$, owing to their shallow emplacement.

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Precambrian Kyeonggin gneiss complex (선캠브리아 경기육괴 중 대리암의 연대측정에 대한 예비연구)

  • 박계헌;정창식
    • The Journal of the Petrological Society of Korea
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    • v.2 no.2
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    • pp.130-138
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    • 1993
  • Kyeonggi Gneiss complex forming Korean Precambrian basement is mainly composed of high-grade metasedimentary rocks, which are generally difficult to determine their absolute ages. We examined the feasibility of successive absolute age determination method for the marbles from this basement. We used hydrochloric acid for the selective dissolution of carbonate minerals from the marbles. Trace element analysis shows that most of Zr and Rb are concentrated in the residues. U in the residue is more abundant than that in HC1-dissolved parts. Pb, Sr, Sm, and Nd are somewhat evenly distributed between HC1-dissolved parts and the residues. }Th shows rather complex behavior. Sr isotopic compositions of the HC1-dissolved parts reveal mixing with Sr from non-carbonate minerals having much higher $^{87}Sr/^{86}Sr$ ratios. We suggest that the most reliable method in the age determination for the marbles of this area is measuring Pb isotopic ratios of the pieces of pure marbles.

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Effects of Castration and Injection Time of rbST on Dry Matter and Nutrient Intake in Holstein Bulls (거세와 rbST 투여 시기가 Holstein 수소의 건물 및 영양분 섭취량에 미치는 영향)

  • 권응기;김현섭;윤상기;강우성;김병완;김종복;홍병주
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.18 no.1
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    • pp.61-68
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    • 1998
  • This research was canied out to investigate the effect of castration and injection time of sustained release recombinant bovine somatotropin(SR-rbST) on dry matter intake(DM1) and nutrient intake of surgically castrated 32 Holstein young bulls by growth stage. The main results were as follows: 1. DM intakes were not different between in bull and steer groups, but those in rbSTl and rbST2 were 7.88 and 7.65kg respectively, which were lower 6-9% compared to bull and steer groups. 2. Actual DM intake to DM requirement of Beef cattle(NRC) was 88.5~97.7%, while net energy intake was sufficient for NE requirement in all groups during all growth stage except rbST group during fmishing stage. 3. Overall mean concentrate intake to body weight in steer group was the highest as 1.94%, and then those in rbST groups were 1.87~1.89% which were higher 0.07~0.09% unit than in bull group. 4. Feed conversion ratios(DM) in bull, rbSTl and rbST2 groups were 8.29, 8.18 and 7.60kg respectively, which were improved 12.4, 13.9 and 22.6%, respectively, compared to steer group.

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Rb-Sr Whole-rock Isochron Age and Petrology of the Mt. Geumjeong Granite, Busan (부산 금정산화강암체의 암석학 및 Rb-Sr 전암 등시선 연대)

  • Yun Sung-Hyo;Koh Jeong-Seon;Park Kwang-Sun;Ahn Hyo-Chan;Kim Young-Il;Yoo Sung-Hyeon;Lee Dong-Han;Yun Gi-Young
    • The Journal of the Petrological Society of Korea
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    • v.14 no.1
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    • pp.61-72
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    • 2005
  • The granitoids in the Mt. Geumjeong, Busan can be divided into granodiorite, hornblende granite, adamellite, tonalite, biotite granite and micrographic granite. The geochemical characteristics of the Mt. Geumjeong granites indicate that they were crystallized from a calc-alkaline series and that they belong to Ⅰ-type granitic rocks which evolved from granodioritic magma into hornblende granite, adamellite, biotitie granite, and finally micrographic granite through fractional crystallization of plagioclase. The crystallization pressures and temperatures of the minimum melt compositions of the granitic rocks were estimated to about 1∼5 kbar and 720∼700℃. The trace element composition and REE patterns, characterized by a high LILE/HFSE ratio and enrichments in LREE, indicate typical continental margin arc calc-alkaline rocks produced in the subduction environment. The Rb-Sr isotopic data for the Mt. Geumjeong granites define a well-defined isochron yielding as age of 69.6±1.9 Ma with an initial Sr isotopic ratio of 0.70503.

Comparisons of Incompatible Element Contents between the Perilla frutescens var. japonica and Sesamum indicum in Keumsan Area (금산 지역 들깨와 참깨의 비호정성 원소 함량 비교)

  • Song, Suck-Hwan;Kim, Ill-Chool
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.54 no.1
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    • pp.61-79
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    • 2009
  • This study is for incompatible element contents of Perilla frutescens and Sesamum indicum from the Keumsan: biotite granite, phyllite and shale areas. In the soils, high elements are shown in the granite and phyllite areas, and in the areas of the Perilla frutescens. Positive correlations are distinctive within the granite for the Perilla frutescens, but the shale for the Sesamum indicum. These relationships can be explained with relative propositions of minerals containing the incompatible element. In the plants, high elements are shown in the shale and the Sesamum indicum are high in the comparisons of the same soil types. The low parts are mainly high. Regardless of the soil types, the lower and upper parts, respectively, are high in the Y, Zr and Rb contents for the Perilla frutescens, but, Ta, Nb, Th and U contents for the Sesamum indicum. Positive correlations are distinctive within plants of the phyllite. Comparing with the soil types, all HFS and Cs contents of the LFS in the plants are low with differences of several to hundred times, but high in the Sr contents with differences of several times. In the comparisons between plants and soil types, Y, Zr, Hf, Ta, Nb, Rb, and Sr of the phyllite and Th, U, Ba and Cs of the shale for the Perilla frutescens as well as Y, Zr, Hf, Rb, Sr, Ba and Cs of the phyllite and Ta, Nb, Th and U of the shale for the Sesamum indicum are chemically similar to the soils. In the comparisons of the each parts for the plant types, differences with the soils are big in the granite.

Petrochemical Characteristics and Review on Petrogenesis on Cretaceous to Tertiary Volcanic Rocks in the Kyongsang Basin (경상분지 백악기~제3기 화산암류의 암석화학적 특징과 암석 성인 고찰)

  • Sung, Jong-Gyu;Kim, Jin-Seop
    • The Journal of the Petrological Society of Korea
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    • v.21 no.2
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    • pp.217-233
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    • 2012
  • Major elements abundances of Cretaceous to Tertiary volcanic rocks in Kyongsang basin are similar with Southern Volcanic Zone (SVZ) in Andes. Sr, K, Rb, $Ba{\pm}Th$ abundances, which have low ionic charge, are selectively fertile, on the other hand Ta, Nb, Ce, P, Zr, Hf, Sm, Ti, Y, Yb, Sc, Cr abundances are low. K, Sr, Th show characteristic spikes and Nb show remarkable trough on trace elements spider diagram. Trace elements abundances are higher than that of Andes which is supposed to mantle sources of Kyongsang basin volcanic rocks are produced lower degree of partial melting than SVZ in Andes.

Petrology of the Igneous Rocks in the Goseong area, Gyeongsang Basin II. Trace Element Geochemistry and Rb-Sr Radiometric Age (경상분지 고성지역의 화성암류에 대한 암석학적 연구 II. 미량원소 지구화학과 Rb-Sr 방사성 연대)

  • Jwa, Yong-Joo
    • Economic and Environmental Geology
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    • v.31 no.6
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    • pp.473-483
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    • 1998
  • The igneous rocks in the Goseong area are composed of the volcanic rocks (andesitic lapilli tuff and rhyodacite), Bulgugsa granites (Hornblende-biotite granite and two pyroxene granite) and intrusive andesites. In the variation diagrams of the trace and rare earth element contents and elemental ratios as well as the REE patterns, the three igneous rock types show different variational trends and patterns. The geochemical features represent that the igneous rocks in the area were formed from three different magmatic pulses. Two independently carried out Rb-Sr isotope experiments for the Goseong granites show that the whole rock ages and Sr initial ratios of the granites are $66.4{\pm}6.2Ma$, $0.70517{\pm}22(2{\sigma})$ and $71.3{\pm}6.8Ma$, $0.70506{\pm}18(2{\sigma})$, respectively. These results suggest that the granites magma originated from the lower crustal materials of igneous origin intruded into the area during the late Cretaceous period. Masan hornblende-biotite granite emplaced at the vicinity of the Goseong area is very similar to the Goseong granite in its mineral compositions, major, trace and rare earth element contents and patterns. The intruding age (100 Ma) of the Masan granite is order than that of the Geseong granite, however. The similarity of the geochemical natures but the contrast of the intruding ages between the Masan and Goseong granites possibly indicate that the magma generation from the same source materials occurred at a temporal interval of ca. 30 Ma.

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Sorption and Ion Exchange Characteristics of Chabazite: Competition of Cs with Other Cations (차바자이트의 흡착 및 이온 교환 특성: Cs 및 다른 양이온과의 경쟁)

  • Baek, Woohyeon;Ha, Suhyeon;Hong, Sumin;Kim, Seonah;Kim, Yeongkyoo
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.2
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    • pp.59-71
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    • 2016
  • To investigate the sorption characteristics of Cs, which is one of the major isotopes of nuclear waste, on natural zeolite chabazite, XRD, EPMA, EC, pH, and ICP analysis were performed to obtain the informations on chemical composition, cation exchange capacity, sorption kinetics and isotherm of chabazite as well as competitive adsorption with other cations ($Li^+$, $Na^+$, $K^+$, $Rb^+$, $Sr^{2+}$). The chabazite used in this experiment has chemical composition of $Ca_{1.15}Na_{0.99}K_{1.20}Mg_{0.01}Ba_{0.16}Al_{4.79}Si_{7.21}O_{24}$ and its Si/Al ratio and cation exchange capacity (CEC) were 1.50 and 238.1 meq/100 g, respectively. Using the adsorption data at different times and concentrations, pseudo-second order and Freundlich isotherm equation were the most adequate ones for kinetic and isotherm models, indicating that there are multi sorption layers with more than two layers, and the sorption capacity was estimated by the derived constant from those equations. We also observed that equivalent molar fractions of Cs exchanged in chabazite were different depending on the ionic species from competitive ion exchange experiment. The selectivity sequence of Cs in chabazite with other cations in solution was in the order of $Na^+$, $Li^+$, $Sr^{2+}$, $K^+$ and $Rb^+$ which seems to be related to the hydrated diameters of those caions. When the exchange equilibrium relationship of Cs with other cations were plotted by Kielland plot, $Sr^{2+}$ showed the highest selectivity followed by $Na^+$, $Li^+$, $K^+$, $Rb^+$ and Cs showed positive values with all cations. Equilibrium constants from Kielland plot, which can explain thermodynamics and reaction kinetics for ionic exchange condition, suggest that chabazite has a higher preference for Cs in pores when it exists with $Sr^{2+}$ in solution, which is supposed to be due to the different hydration diameters of cations. Our rsults show that the high selectivity of Cs on chabazite can be used for the selective exchange of Cs in the water contaminated by radioactive nuclei.

Lithogeochemistry on the Dukum and Jeonjuil gold - silver deposits in Southern - western part of Korea (한국(韓國) 남서부(南西部)의 덕음(德蔭)과 전주(全州)-금은광상(金銀鑛床)에 대(對)한 암석지구화학적(岩石地球化學的) 연구(硏究))

  • Yoon, Chung Han;John, Yong Won;Chon, Hyo Taek
    • Economic and Environmental Geology
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    • v.21 no.4
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    • pp.389-400
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    • 1988
  • Minor elements such as Ag, As, Au, Bi, Cd, Cu, Co, Ni, Pb, Rb, Sb, Sr and Te were analyzed by atomic absorption spectrophotometry and induced coupled plasma spectrophotometry in order to investigate pathfinders for gold in quartz porphyry, granite porphyry and vein materials in Jeonjuil gold - silver mine, and in altered biotite granites and vein materials in Dukum gold - silver mine. In Dukum gold - silver mine, it is observed that Au contents have positive relation with As, Co, and Rb contents, but negative relation with Bi contents in altered biotite granites. Au contents have positive relation with Ag, As, Co and Te contents in vein materials. In Jeonjuil gold - silver mine, it is observed that Cd, Rb, Sr and Te are enriched near ore vein in quartz porphyry and granite porphyry. Au contents have positive relation with As, Cd, Cu, $Fe_2O_3$ and $K_2O$ in vein materials.

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