• Title/Summary/Keyword: Rate Law

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A Study on the Creep Deformation Characteristic of AZ31 Mg Alloy at High Temperature (AZ3l 마그네슘 합금의 고온 크리이프 변형특성에 관한 연구)

  • An Jungo;Kang Daemi;Koo Yang;Sim Sungbo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.3
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    • pp.186-192
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    • 2005
  • The apparent activation energy Qc, the applied stress exponent n, and rupture life have been determined from creep test results of AZ31 Mg alloy over the temperature range of 200$^{\circ}C$ to 300$^{\circ}C$ and the stress range of 23.42 MPa to 93.59 MPa, respectively, in order to investigate the creep behavior. Constant load creep tests were carried out in the equipment including automatic temperature controller with data acquisition computer. At the temperature of $200^{\circ}C{\sim}220^{\circ}C$ and under the stress level of 62.43~93.59 MPa, and at around the temperature of $280^{\circ}C{\sim}300^{\circ}C$ and under the stress level of 23.42~39.00 MPa, the creep behavior obeyed a simple power-law relating steady state creep rate to applied stress and the activation energy fur the creep deformation was nearly equal to that of the self diffusion of Mg alloy including aluminum From the above results, at the temperature of $200^{\circ}C{\sim}220^{\circ}C$ the creep deformation for AZ31 Mg alloy seemed to be controlled by dislocation climb but controlled by dislocation glide at $280^{\circ}C{\sim}300^{\circ}C$ .And relationship beween rupture time and stress at around the temperature of $200^{\circ}C{\sim}220^{\circ}C$ and under the stress level of 62.43~93.59 MPa, and again at around the temperature of $280^{\circ}C{\sim}300^{\circ}C$ and under the stress level of 23.42~39.00 MPa, respectively, appeard as fullow; log$\sigma$=-0.18(T+460)(logtr+21)+5.92, log$\sigma$ = -0.25(T+460)(logtr+21)+8.02 Also relationship beween rupture time and steady state creep rate appears as follow; ln$\dot$ =-0.881ntr-2.45

Treatment of decomposition of Aqueous 2,4-Dichlorophenol Solution by Ultrasonic Irradiation (초음파 검사에 의한 수중의 2,4-Dichlorophenol 분해처리)

  • 손종렬;문경환;김영환;우완기
    • Journal of environmental and Sanitary engineering
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    • v.14 no.3
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    • pp.54-62
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    • 1999
  • 2,4-Dichlorophenol was known pollutants caused by the endocrine disruptor into the refractory substances of environment and this is difficult to be degradable by conventional methods. Therefore, a considerable interest has been devoted to developing new process where 2,4-Dichlorophenol can easily decomposed. In this study, the series of ultrasonic irradiation for removal of 2,4-Dichlorophenol has been selected as a model reaction in the batch reactor system in order to obtain the basic data investigate the influence of various experimental parameters such as concentration, pH, reaction temperature, acoustic intensity. The products obtained form the ultrasonic irradiation were analysed by GC/MS and HPLC. The formation of $H_2O_2$, a well-known the strong oxidant was found proportionally to increase with irradiation time. The intermediates of ultrasonic irradiation of 2,4-Dichlorophenol were identified as HCl, catechol, hydroquinone, o,p-benzoquinone, muconic acid, and maleic acid. The final products of this was $CO_2$ and $H_2O$. As the decomposition of 2,4-Dichlorophenol proceeds by the ultrasonic irradiation, the pH of 2,4-Dichlorophenol containing aqueous solution increases slowly, The decomposition of 2,4-Dichlorophenol was found to be occured fast in the basic medium. In general, the rate of reaction is proportional to the reaction temperature obeying the Arrhenius' law. However, in the ultrasonic irradiation, this suggests as the reaction temperature increase the decomposition rate of the reactant decreases. This result meant that the increase of reaction temperature due to the increase of vapor pressure of water accelerated the decrease of acoustic intensity which was can be proportional to the decomposition rae of these compounds. It was found that more than 80% of phenol solution was removed within hours in all reaction conditions. The reaction order in the degradation of the 2,4-Dichlorophenol compounds was verified as the Pseude-first order. From the fore-mentioned results, it can be concluded that the refractory organic compounds caused by endocrine disruptor as 2,4-dichlorophenol could be removed by the ultrasonic irradiation with radicals, such as $H{\;}{\cdot}{\;}and{\;}OH{\;}{\cdot}$ radical causing the high increase of pressure and temperature. Finally, it apeared that the technology using ultrasonic irradiation can be applied to the treatment of refractory substances caused by endocrine disruptor which are difficult to be decomposed by the conventional methods.

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Vertical Buoyant Jet in Tidal Water -Crossflowing Environment- (흐름 수역(水域)에서 연직상향부력(鉛直上向浮力)?)

  • Yoon, Tae Hoon;Cha, Young Kee;Kim, Chang Wan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.1
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    • pp.11-22
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    • 1987
  • A plane buoyant jet discharged vertically upward into a crossflow is analyzed by numerical solution of the governing equations of continuity, momentum and constituent transport. The turbulent transport is modelled by the Prandtl's mixing length theory. In the numerical solution procedure, the governing equations are transformed by stream function and vorticity transport, non-dimensionalyzed by discharge velocity, slot width, and parameters representing flow characteristics, and solved by Gauss-Seidel iteration method with successive underrelaxation. The numerical experiments were performed for the region of established flow of buoyant jet in the range of discharge densimetric Froude number of 4 to 32 and in the range of velocity ratio of 8 to 15, which is the ratio of discharge velocity to crossflow velocity. Variations of velocities and temperatures, flow patterns and vorticity patterns of receiving water due to buoyant jet were investigated. Also investigated are the effects of velocity ratio and discharge densimetric Froude number on the trajectories of buoyant jet. Computed are velocities, temperatures and local densimetric Froude numbers along the trajectory of the buoyant jet. Spreading rate and dispersion ratio were analyzed in terms of discharge densimetric Froude number, local densimetric Froude number and distance from the source along the jet trajectory. It was noted that the similarity law holds in both the profiles of velocity and temperatures across the jet trajectory and the integral type analysis of Gaussian distribution is applicable.

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Indoor Rearing Method of Diving Beetles: Cybister japonicus, Cybister tripunctatus orientalis, Cybister brevis (물방개류 실내 사육법)

  • Kim, NamJung;Hong, Seong-Jin;Kim, Seong-Hyun;Park, Hae-Chul
    • Journal of Sericultural and Entomological Science
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    • v.50 no.1
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    • pp.27-32
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    • 2012
  • The aim of this study is to develop indoor-rearing methods of the diving beetles. In nature, both the adult diving beetle and its larvae are voracious aquatic predators. The larvae beetles hunt relatively bigger size of tadpoles and small fish for food source. However, due to difficulties of the food supplement for rearing diving beetles at indoor-condition further motivated us to develop new artificial food. Three separate experiments were performed. In the first experiment, adult beetles were provided with one of the several food choice treatments to self-compose their preferred foods that are affordable on the market at lower price. The second experiment was also to develop artificial diet that is possible for rearing larvae beetle under indoor condition. The larvae beetles were restricted to raw squid, artificial food source and mosquito larvae as a control at the first stadium and small fish and raw squid during second to third stadium duration. According to our result, adult beetles selected a food that made of boiled squid and dead small fish while, the young larvae consumed small fish, mosquito larvae and raw squid. Although, the larval food restriction on law squid caused noticeable decrease in survival, the result still supported the possible survival rate of keeping larvae at indoor condition. Moreover, pupation rate experiments, in which groups of larvae were placed at different mats, natural soil and fermented sawdust, showed that 80% of diving beetles pupated on the sawdust. This result indicates that female beetle preferentially selected to oviposit along soft and moist area.

Electrokinetic Studies on Nylon and Wool/Acid Dye System (나일론과 양모/산성염료계에 대한 계면동전위적 연구)

  • 박병기;김진우;김찬영
    • Textile Coloration and Finishing
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    • v.1 no.1
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    • pp.19-25
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    • 1989
  • In past, dye diffusion and dyeing rate in fibers have been emphasized in dyeing phenomena. However, in the light of the properties of colloids in the surface of disperse phase and dispersion, there exist specific characters such as adsorption or electric double layer, which seems to play important roles in determining the physiochemical properties in the dyeing system. Electrostatic bonding, hydrogen bonding and Van der Waals adsorption are common in dyeing as well as covalent bonding. Particularly, electrostatic bonding is premised on the existance of ionic radicals in fibers. The present study was aimed to clarify the electrokinetic phenomena of dyeing through the role of electric double layer by ion in amphoteric fibers with different ionic effects under different pH. Spectrophotometric analysis method was used to compare dyeing condition of surface, which can be detected by electrokinetic phenomena and the inner of fibers after deceleration of dyed fibers. Nylon and wool, the typical amphoteric fibers were dyed with monoazo acid dyes such as C.I. Acid Orange 20, and C.I. Acid Orange 10. Various combinations were prepared by combining pH, temperature and dye concentration, in order to generate streaming electric potential which were measured by microvolt meter and specific conductivity meter. The results were transformed to zeta potential by Helmholtz-Smoluchowski formular and to surface electric charge density by Suzawa formular, surface dye amount, and effective surface area of fibers. The amount of dyes of inner fibers were also measured by the Lambert-Beer’s law. The main results obtained are as follows. 1. By measuring zeta pontential, it was possible to detect the dyeing mechanism, surface charge density, surface dye amount and effective surface area concerning dye adsorption of the amphoteric fibers. 2. Zeta pontential increases in negative at low pH and high dye concentration in the process of dyeing. This implied that there existed ionic bond formation in the dyeing mechanism between acid dyes and amphoteric fibers. 3. Dibasic acid dye had little changing rate in zeta potential due to the difference in solubility of dye and in number of dissociated ions per dye molecule to bond with amino radicals of amphoteric fibers. The dye adsorption of mono basic acid dye was higher than that of dibasic acid dye. 4. The effective surface areas concerning dyeing were $6.3E+05\;cm^2/g$ in nylon, $1.6E+07\;cm^2/g$ in wool fiber being higher order of wool then nylon.

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Study on Discomfort of Vertical Whole-body Shock Vibration Having Various Magnitudes, Frequencies and Damping (다양한 크기와 주파수 그리고 감쇠를 갖는 상하방향 전신 충격진동에 대한 불편함 연구)

  • Ahn, Se-Jin;Griffin, Michael J.;Yoo, Wan-Suk;Jeong, Weui-Bong
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.2
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    • pp.50-57
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    • 2007
  • Shocks are excited by impulsive forces and cause discomfort in vehicles. Current standards define means of evaluating shocks and predicting their discomfort, but the methods are based on research with a restricted range of shocks. This experimental study was designed to investigate the discomfort of seated subjects exposed to a wide range of vertical shocks. Shocks were produced from the responses of one degree-of-freedom models, with 16 natural frequencies (from 0.5 to 16 Hz) and four damping ratios (0.05 0.1, 0.2 and 0.4), to a hanning-windowed half-sine force inputs. Each type of shock was presented at five vibration dose values in the range $0.35\;ms^{-1.75}$ to $2.89\;ms^{-1.75}$. Fifteen subjects used magnitude estimation method to judge the discomfort of all shocks. The exponent in Stevens' power law, indicating the rate of growth in discomfort with shock magnitude, decreased with increasing fundamental frequency of the shocks. At all magnitudes, the equivalent comfort contours showed greatest sensitivity to shocks having fundamental frequencies in the range 4 to 12.5 Hz. At low magnitudes the variations in discomfort with the shock fundamental frequency were similar to the frequency weighting $W_b$ in BS 6841, but low frequency high magnitudes shocks produced greater discomfort than predicted by this weighting. At some frequencies, for the same unweighted vibration dose value, there were small but significant differences in discomfort caused by shocks having different damping ratios. The rate of increase in discomfort with increasing shock magnitude depends on the fundamental frequency of the shock. In consequence, the frequency-dependence of discomfort produced by vertical shocks depends on shock magnitude. For shocks of low and moderate discomfort, the current methods seem reasonable, but the response to higher magnitude shocks needs further investigation.

A Study on the Environmental Radiation Dose Measurement in the Nuclear Medicine Department (핵의학과에서 환경방사선량 측정에 대한 연구)

  • Kang, Bo-Sun;Lim, Chang-Seon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.11 no.6
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    • pp.2118-2123
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    • 2010
  • Korean individual occupational exposure control is focused on the retrospective service to the over-exposed person by the reading of personal dosimeter. Since the radiophamaceuticals using in the nuclear medicine department are uncontained radiation sources, the potential exposure at working environment is very high. Moreover, a patient remains radioactive for hours or even days after the administration of a radiopharmaceutical for diagnosis or treatment. Thus, the proper working environmental exposure control must be established and executed to protect not only the affiliated employees, but also guardians accompanying patients and temporarily visiting public from the exposure by the patients. Japanese radiation protection law regulates working environmental radiation exposure by regularly measuring and filing the environmental dose for years. This study was aimed at measuring working environmental radiation dose in the nuclear medicine department of an university hospital located in Daejeon, Korea. We measured the accumulation radiation dose in air at 8 locations in the nuclear medicine department by using the same method as in Japan with glass dosimeters. The highest dose rate, 0.23 mSv per month, was measured at the waiting room, and the second one is at reception desk. Even though the doses were lower than the Korean constraint dose rate (0.3 mSv/week) at the boundary of the radiation controlled area, it was over the dose limit of public (1 mSv/y) and environment (0.25 mSv/y). Conclusionally, it was found that the new or additional procedure was necessary to less the exposure dose to the receptionist and guardians by the environmental radiation dose in the nuclear medicine department.

Analysis of Ordinance in a Local Government for the Improvement of the Preferential Purchasing System of Products Manufactured by Disabled (장애인생산품 우선구매제도 활성화를 위한 지방자치단체 조례분석)

  • Park, Ju-Young
    • The Journal of the Korea Contents Association
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    • v.16 no.5
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    • pp.732-745
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    • 2016
  • This study aims to analyze ordinance in a local government for the improvement of the preferential purchasing system of products manufactured by disabled. So, This study analyze 44 ordinance of a local government. The results of this study were as follows. First, 44 local governments enacted the ordinance(rate was 18.1%). Second, Most of the local governments suggest purpose of ordinance, agency of application, establishment of support plan, request of purchase cooperation, duty of purchase promotion. But there are not suggest other items in many ordinance. In particular, Duty of local government president is specified only 30(rate was 68.1%). Third, The municipal ordinance conflicting with the upper laws and regulation. Forth, The Council for the promotion of the preferntial purchasing system of products made by disabled upgrade to an advisory organization including professor, expert, disabled. Fifth, The sales routes of products need to be extended from the public agency to private companies for Preferential purchasing in affirmative action. In order that the Preferential purchasing system will not be a nominal law, the government should show active willingness about monitoring of local government.

Study on the Use of Bracketed Summations of the Peak Ground-motion Acceleration Per Second for Rapid Earthquake Alert Notifications (신속 지진피해통보를 위한 지반가속도의 초당 최대값 구간적산 방법의 활용에 관한 연구)

  • Yun, Kwan-Hee
    • Journal of the Earthquake Engineering Society of Korea
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    • v.16 no.1
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    • pp.37-45
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    • 2012
  • In an effort to further exploit the peak ground-motion acceleration (PGA) information per second available in real time by the enacted law, bracketed summations of the PGA per second ($BSPGA_k$) for 30 seconds based on the records with a rate of 100 samples were compared with the cumulative absolute velocity (CAV) and earthquake intensities based on a worldwide database of records from small-to-large earthquakes. The CAV, currently in use as an earthquake damage indicator for nuclear power plants due to its strong correlation with the earthquake intensity, has the disadvantage of requiring a massive amount of digital data with a rate of more than 100 samples per second. The comparative study shows that the $BSPGA_k$ is well correlated with the CAV over the wide range of strong ground-motion levels, which suggests that the $BSPGA_k$ is one of the new promising ground-motion parameters especially useful for rapid earthquake alert notifications through an earthquake monitoring network. Based on the domestic database of records from small-to-moderate earthquakes with felt reports, it is also observed that the $BSPGA_k$ is comparable to the CAV and better than the PGA in predicting the intensity by using the correlation relation.

Performance Evaluation and Offset Time Decision for Supporting Differential Multiple Services in Optical Burst Switched Networks (광 버스트 교환 망에서 차등적 다중 서비스 제공을 위한 offset 시간 결정 및 성능 평가)

  • So W.H.;im Y.C.K
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.41 no.1
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    • pp.1-12
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    • 2004
  • In this paper, we take advantage of the characteristics of optical burst switching (OBS) to support service-differentiation in optical networks. With the offset time between control packet and burst data, the proposed scheme uses different offset time of each service class. As contrasted with the Previous method, in which the high Priority service use only long offset time, it derives the burst loss rate as a QoS parameter in consideration of conservation law and given service-differential ratios and decides a reasonable offset time for this QoS finally Firstly proposed method classifies services into one of high or low class and is an algorithm deciding the offset time for supporting the required QoS of high class. In order to consider the multi-classes environment, we expand the analysis method of first algorithm and propose the second algorithm. It divides services into one of high or low group according to their burst loss rate and decides the offset time for high group, and lastly cumulates the offset time of each class. The proposed algorithms are evaluated through simulation. The result of simulation is compared with that of analysis to verify the proposed scheme.