• Title/Summary/Keyword: Rare earth oxides

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Structural and temperature coefficient of resistance characteristics of colossal magnetoresistance Mn oxides prepared by RF sputtering

  • Choi, Sun-Gyu;Ha, Tae-Jung;Reddy, A.Sivasankar;Yu, Byoung-Gon;Park, Hyung-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.361-361
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    • 2007
  • A lot of efforts have been paid to develop infrared imaging systems in last decades. Bolometer has a wide range of applications from military to commercial, such as military night vision, medical imaging system and so on. Bolometer is a resistive sensor that detects temperature changes through resistance change. To improve detecting ability, bolometer should have a good resistive film which has high temperature coefficient of resistance (TCR) value. Colossal magnetoresistance (CMR) $L_{1-x}A_xMnO_3$ (where L and A are trivalent rare-earth ions and divalent alkaline earth ions, respectively.) are received attention to apply bolometer resistive film because it has a high TCR property which was discovered in the metal to semiconductor phase transition temperature region. In this work, CMR films were deposited on various substrates in relative low substrate temperature by RF magnetron sputtering. The influence of deposition parameters such as substrate temperature, gas partial pressure, and so on have been studied. The structural and TCR properties of the films were also investigated for applying to microbolometer.

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Crystal growth of yttrium vanadate by the EFG technique

  • Kochurikhin, V.V.;Ivanov, M.A.;Suh, S.J.;Yoon, D.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.5
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    • pp.203-206
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    • 2001
  • The applicability of shaped growth of yttrium orthovanadate was approved by successful growth of rod-like single crystals with the rectangular shape. Nd-doped single crystals with content of $Nd^{3+}$ ions of 1,2,3,5 atomic % in the starting melt were grown by the EFG technique with the size up to $10^{*}10mm$ in section and up to 85 mm in length. For the testing of the multiple growth of the orthovanadates, two and three Nd-and Yb-doped $YVO_{4}$ single crystals were grown by the EFG technique simultaneously up to 110 mm in length.

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Grain Size Dependence of Ionic Conductivity of Polycrystalline Doped Ceria

  • Hong, Seong-Jae
    • The Korean Journal of Ceramics
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    • v.4 no.2
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    • pp.122-127
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    • 1998
  • Conductivities of polycrystalline ceria doped with several rare earth oxides were measured by AC admittance and DC four probe method. The conductions were separated into grain and grain boundary contributions using the complex admittance technique as well as grain size dependence of conductivity. The grain size dependence of polycrystalline conductivity, which can be adequately described by the so-called brick layer model, appears to give a more reliable measure of the grain conductivity compared to the complex admittance method. Polycrystalline resistivity(1/conductivity) increases linearly with the reciprocal of grain size. The intercept of resistivity vs. inverse grain size plot gives a measure of the grain resistivity and the slope gives a measure of the grain boundary resistivity. It was also noted that errors involved in the analysis of experimental data may be different between the complex admittance method and the impedance method. A greater resolution of the spectra was found in the complex admittance method, insofar as the present work is concerned, suggesting that the commonly used equivalent circuit may require re-evaluation.

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Nonlinear Properties of ZnO Varistors Doped with Rare earth Oxides (희토류 산화물이 첨가된 ZnO 바리스터의 비직선 특성)

  • Park, Jong-Ah;Lee, Hong-Hee;Kim, Myung-Jun;Ryu, Jung-Sun;Nahm, Choon-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.747-750
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    • 2003
  • The microstructure and nonlinear properties of ZPCMR-based varistors were investigated with various additives. The density of varistors were gradually decreased for the same R in order of NiO, MgO, and $Cr_2O_3$, respectively. The ZPCR-based varistors were not affected by NiO and MgO additives in nonlinear properties, whereas greatly affected by $Cr_2O_3$. Among the ZPCCR-based varistors, ZPCCD varistor exhibited the highest nonlinear properties, in which the nonlinear exponent is in the range of $40.5{\sim}67.4$ and the leakage current is in the range of $1.2{\sim}2.7{\mu}A$.

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Capacitance Aging Behavior of Acceptor-Doped BaTiO3 under DC Electrical Field (직류 전계에 의한 Acceptor 첨가 BaTiO3의 유전특성 열화 현상)

  • Hahn, Dong-Woo;Han, Young-Ho
    • Journal of the Korean Ceramic Society
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    • v.46 no.2
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    • pp.219-223
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    • 2009
  • Effects of MgO or $R_2O_3$(R:Dy, Ho, Yb) on the capacitance aging behavior of multilayer ceramic capacitors (MLCCs) based on $BaTiO_3$ dielectrics under DC electrical fields has been studied. At a DC field of 1 $V{/\mu}m$, the capacitance of MLCC specimens dropped immediately in a very short period (<10 s, the first stage) and then decreased continuously with time (the second stage). Mn doping significantly increased the aging rate in the second stage. The addition of MgO or $R_2O_3$ notably decreased the second stage aging rate of Mn-doped specimens. Yb doping gives rise to the lowest aging rate in the second stage, which is due to the larger population of defect dipoles associated with oxygen vacancies.

Zinc Oxide Varistors with Praseodymium Oxide (Praseodymium계 ZnO 바리스터의 제조 및 미세구조 연구)

  • Soh, J.J.;Han, S.W.;Kim, H.S.;Cho, H.G.;Kim, I.S.
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1342-1344
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    • 1997
  • Zinc oxide varistors which contain rare earth metal oxides have been developed. These Varistors are widely used for low voltage surge-protection devices and high voltage arresters for electric power stations. The characteristics of varistors with praseodymium oxide as a principal additive are discussed. A two-phase microstructure with an intergranular phase between the ZnO grains.

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Characteristics of Cryolite as an Electrolyte for Reduction of Nd$_2$O$_3$ (네오디뮴 산화물의 전해환원시 전해질로서 빙정석의 특성)

  • 남상욱;백영현
    • Journal of Surface Science and Engineering
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    • v.26 no.2
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    • pp.82-86
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    • 1993
  • An attempt was made to reduce directly Nd2O3 in a cryolited based fluoride bath. Neodymium metal was electrodeposited on the iron cathode to produce the Fe-Nd eutectic alloy in a liquid state at 90$0^{\circ}C$. Graphite was adopted for the anode and pure iron for the cathode. Electrolyte was composed of Na3AlF6 50wt.%. AlF3 34wt.% and Nd2O3 16wt.%. Analysis of typical alloy product showed Al 63.4wt.% Fe 26.9wt.% and Nd 7.0 wt.% The enrichment of neodymium in the alloy couldn't be obtained because aluminum codeposited with ne-odydmium. Experimental results proved that the cryolited based electrolyte was unstable for the electrolysis of rare earth oxides even though their prominent solubilities.

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Growth of $GdVO_4$ composite single-crystal rods by the double-die edge-defined film-fed growth technique

  • Furukawa, Y.;Matsukura, M.;Nakamura, O.;Miyamoto, A.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.1
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    • pp.1-4
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    • 2008
  • The growth of composite-structured Nd:$GdVO_4$ single crystal rods by the double die EFG method is reported. Two crucibles are combined with an outer and inner die for ascending of different melt. The composite-structured Nd:$GdVO_4$ single crystal rods with a length of 50 mm and an outer diameter of 5 mm including of inner Nd-doped core region with diameter 3 mm were grown successfully. Nd distribution in the, radial direction has graded profile from result of EPMA. Absorption coefficient in the core region at 808 nm was $42cm^{-1}$. Finally, we demonstrated the laser oscillation using our composite crystal and 2-W output was obtained.

Flux Pinning Enhancement in $(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_{2}Cu_{3}O_y$ Oxides by Zone Melt Growth Process

  • Kim So-Jung
    • KIEE International Transactions on Electrophysics and Applications
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    • v.5C no.6
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    • pp.251-256
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    • 2005
  • Directionally melt-textured high $T_c\;(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_{2}Cu_{3}O_y$ [(YNS)-123] superconductor was systematically investigated by the zone melt growth process in air. A sample prepared by this method showed well-textured microstructure, and $(Y_{0.5}Nd_{0.25}Sm_{0.25})_{2}BaCuO_5$[(YNS)211] inclusions were uniformly dispersed in large $(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_{2}Cu_{3}O_y$ [(YNS)123] matrix. High irreversibility field and magnetization hysteresis loop of the zone melt-textured (YNS)-123 sample exhibited the enhanced flux pinning, compared with $YBa_{2}Cu_{3}O_y$ (Y-123) sample without RE(rare earth). Critical current density of (YNS)-123 sample was $2.5{\times}10^4\;A/cm^2$ at 2 T and 77 K.

Allanite Mineralization in the Mt. Eorae Area (어래산지역(御來山地域)의 갈렴석광상(褐簾石鑛床))

  • Oh, Mihn-Soo
    • Economic and Environmental Geology
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    • v.22 no.2
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    • pp.151-166
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    • 1989
  • A study of rare-earth mineralization in Kyemyungsan metasedimentary formation of Precambrian Ogcheon Group was carried out in the Mt. Eore Area near Choongju City based on the thorium (Th) and uranium (U) count data of geophysical airborne survey. This rare-earth mineralization was found in the magnetite-bearing banded quartizite which contains diagnostically some amounts of the metamict allanite. The brown colored allanites are distributed as aggregates of fine grains and sometimes banded structures with magnetite (inter growth) along the banding. The ore bed is displaced by the small faults and granite intrusions, and separated 5 ore blocks. The dimensions of the outcrop are 50-80 m in width, 1,500 m in length with the strike of $N70-80^{\circ}E$ and dip of $50-80^{\circ}NW$. In the field, the values of total gamma ray count of GR-101A scintillometer were able to measure more than 400 cps and maximum 1,500 cps, which data are coincided with the values of GR-310 gamma ray spectrometer and the gamma ray count of well logging data. The chemical compositions of the allanites from EPMA data are ranged from$\sum^{TR_2O_3}$ 18.57% to 26.00%, and the cerium oxides ($Ce_2O_3$) of allanite are positive relation with $La_2O_3$, MgO, FeO, MnO and negative relation with $SiO_2$, $Al_2O_3$, $Nd_2O_3$. The result of Neutron Activation Analysis (N.A.A.), Multi-Channel Analysis (M.C.A.) and wet chemistry of 25 outcrop samples for the elements of REE, Zr, U, Th shows strong anomalies. The good correlation elements with the thorium (Th) are the elements of La, Ce, LREE, $TR_2O_3$, Pr, Sm, Yb, Lu by the increasing order.

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