• Title/Summary/Keyword: Rare Metal

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Optimization of Metal Powder Particle Size Distribution for Powder Bed Fusion Process via Simulation (금속 Powder Bed Fusion 적층제조 기술의 분말 입도 최적화를 위한 시뮬레이션)

  • Lee, Hwaseon;Kim, Dae-Kyeom;Kim, Young Il;Nam, Jieun;Son, Yong;Kim, Taek-Soo;Lee, Bin
    • Journal of Powder Materials
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    • v.27 no.1
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    • pp.44-51
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    • 2020
  • Powder characteristics, such as density, size, shape, thermal properties, and surface area, are of significant importance in the powder bed fusion (PBF) process. The powder required is exclusive for an efficient PBF process. In this study, the particle size distribution suitable for the powder bed fusion process was derived by modeling the PBF product using simulation software (GeoDict). The modeling was carried out by layering sintered powder with a large particle size distribution, with 50 ㎛ being the largest particle size. The results of the simulation showed that the porosity decreased when the mean particle size of the powder was reduced or the standard deviation increased. The particle size distribution of prepared titanium powder by the atomization process was also studied. This study is expected to offer direction for studies related to powder production for additive manufacturing.

Phase Evolution and Thermo-physical Properties of Rare-earth Oxides for Thermal Barrier Systems (열차폐용 희토류 산화물의 상형성과 열물성)

  • Shim, Byung-Chul;Kwak, Kil-Ho;Lee, Sung-Min;Oh, Yoon-Suk;Kim, Hyung-Tae;Jang, Byung-Koog;Kim, Seong-Won
    • Journal of Powder Materials
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    • v.17 no.2
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    • pp.148-153
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    • 2010
  • Thermal barrier systems have been widely investigated over the past decades, in order to enhance reliability and efficiency of gas turbines at higher temperatures. Yttria-stabilized zirconia (YSZ) is one of the most leading materials as the thermal barriers due to its low thermal conductivity, thermodynamic stability, and thermal compatibility with metal substrates. In this work, rare-earth oxides with pyrochlore phases for thermal barrier systems were investigated. Pyrochlore phases were successfully formed via solid-state reactions started from rare-earth oxide powders. For the heat-treated samples, thermo-physical properties were examined. These rare-oxide oxides showed thermal expansion of $9{\sim}12{\times}10^{-6}/K$ and thermal conductivity of 1.2~2.4 W/mK, which is comparable with the thermal properties of YSZ.

A Study on the Separation of Long-lived Radionuclides and Rare Earth Elements by a Reductive Extraction Process (환원추출에 의한 장수명핵종과 희토류 원소의 분리 연구)

  • 권상운;안병길;김응호;유재형
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2003.11a
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    • pp.421-425
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    • 2003
  • The reductive extraction process is an important step to refine the TRU product from the electrorefining process for the preparation of transmutation reactor fuel. In this study, it was studied on the reductive extraction between the eutectic salt and Bi metal phases. The solutes were zirconium and the rare earth elements, where zirconium was used as a surrogate for the transuranic(TRU) elements. All the experiments were performed in a glove box filled with a argon gas. Li-Bi alloy was used as a reducing agent to reduce the high chemical activity of Li. The reductive extraction characteristics were examined using ICP, XRD and EPMA analysis. The reduction reaction was equilibrated within 3 hours after the Li addition. Three eutectic salt systems were compared and Zr was successfully separated from the rare earth elements in all the three salt systems.

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Effect of mixed alkaline earth doping on phosphorence properties of $BaAl_2O_4:Eu^{2+}$, $Dy^{3+}$

  • Singh, B.K.;Ryu, R.J.
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2006.10a
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    • pp.22-25
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    • 2006
  • Long lasting phosphor materials are in great demand for their applications in the area of light emitting diodes (LEDs), commercial displays and warning signals. After glow longevity, brightness, photo-resistance and chemical and environment stability are most important qualities that are desired for these materials. Alumina as host lattice with various rare earth elements has been found to be good at the same time inexpensive material for the synthesis of the phosphor materials. This communication explored the effect of mixed rare earth metal on the luminescence properties of these materials for the first time. Various permutations and combinations of $Sr^{2+}$ and $Ba^{2+}$ have been investigated in order to achieve robust and high luminescence characteristics in the tailored phosphor materials.

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Delayed Diaphragmatic Injury with Massive Hemothorax Due to Lower Rib Fracture (하부늑골 골절에 의한 지연성 대량혈흉을 동반한 횡격막 손상)

  • Kim, Woo-Shik;Kim, Joong-Suck
    • Journal of Trauma and Injury
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    • v.28 no.2
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    • pp.79-82
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    • 2015
  • Simple rib fracture is one of most common injury after blunt thoracic trauma found in approximately 7% to 40% of cases. Delayed traumatic diaphragmatic injury with massive hemothorax after rib fracture is rare but a potentially life-threatening condition. We present a rare case of a 79-year-old male with delayed diaphragmatic injury with massive hemothorax due to fracture of the lower ribs. Under thoracoscopy, hemothorax was evacuated, diaphragmatic rupture was identified and repaired, and the lower ribs were fixed with metal plate (s). Although simple lower rib fractures may be the only clinical finding, close observation and monitoring are required because of the possibility of diaphragmatic and/or intraabdominal organ injury.

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Luminescence behaviour of rare earth doped alkaline earth aluminates synthesized by combustion method (연소법에 의한 rare earth doped doped alkaline earth aluminates 형광체의 발광특성)

  • Jung, Young-Ho;Park, Jin-Won;Park, Jo-Yong;Khatkar, S.P.;Taxak, V.B.;Myung, Kwang-Shik;Han, Sang-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.581-584
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    • 2002
  • A new method for the preparation of lanthanide ions activated strontium aluminates phosphor by combustion method has been proposed. Combustion method consist of the redox reactions between the respective metal nitrates and urea in a preheated funace at $500^{\circ}C$. The luminescence behavior of the phosphor was studied and compared with corresponding phosphor prepared by conventional method. Effect of $Mg^{2+}$ ion concentration in strontium aluminate phosphor was investigated and the maximum luminescence of about $100cd/m^2$ was obtained. This method gave better brightness and small size to the phosphor than made by conventional method.

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Dynamic Analysis of Spatial Multiscale Models (공간적 멀티스케일 모델의 동적 해석)

  • Kim, Sung-Youb;Park, Jong-Youn;Cho, Young-Sam;Jun, Suk-Ky;Im, Se-Young
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.547-550
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    • 2004
  • We present a multiscale scheme which describes the dynamic pictures of atoms in the multiple length-scale systems. Large-scale atomic systems are reduced to coarse grained system by the quasicontinuum, of which the dynamic pathways are rendered by the action-derived molecular dynamics proved effective for multiple time-scale problems such as rare events. Adatom diffusions on the metal (001) surface are selected for our numerical examples. The energy barriers of the diffusions and the real dynamic trajectories of the adatoms are calculated.

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Electronic structure studies of CoFeRO (R=Hf,La,Nb) thin films by X-ray absorption spectroscopy

  • Song, J.H.;Gautam, S.;Chae, K.H.;Asokan, K.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.378-378
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    • 2010
  • We report the electronic structure of CoFeO-R (R=Hf, La, Nb) thin films studied by x-ray absorption spectroscopy (XAS). These ferrites thin films were prepared by pulsed laser deposition method and characterized by XAS measurements at O K-, Co and Fe L-edges. The O K-edge spectra suggest that there is a strong hybridization between O 2p and 3d electrons of transition metal cations and Fe $L_{3,2}$-edge spectra indicate that Fe-ions exist in $Fe^{2+}$ with tetrahedral site of the spinel structure. Divalent Co ions is also distributed in tetrahedral site with rare earth ions goes to octahedral sites of spinel structure. X-ray magnetic circular dichroism (XMCD) is also used to explain the symmetry and magnetic nature dependence on rare-earth ions.

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EDTA-functionalized KCC-1 and KIT-6 mesoporous silicas for Nd3+ ion recovery from aqueous solutions

  • Ravi, Seenu;Zhang, Siqian;Lee, Yu-Ri;Kang, Kyoung-Ku;Kim, Ji-Man;Ahn, Ji-Whan;Ahn, Wha-Seung
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.210-218
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    • 2018
  • Ethylenediaminetetraacetic acid (EDTA)-functionalized KIT-6 and KCC-1 mesoporous silicas were prepared via post-synthesis grafting and examined for their ability to promote the recovery of rare earth metal ions such as $Nd^{3+}$ from an aqueous medium. The obtained adsorption isotherms were fitted to the Langmuir model, which gave a maximum adsorption of $Nd^{3+}$ ions of 109.8 and 96.5 mg/g for KIT-6-EDTA and KCC-1-EDTA, respectively, at $25^{\circ}C$ and pH 6. The adsorption kinetic profile of KIT-6 was faster than KCC-1. KIT-6 was also proved to be more stable against desorption under acidic regeneration conditions.

Urban Mine Resources and Metals Recycling Industries in Japan (일본(日本)의 도시광산(都市鑛山)(사용후제품) 자원(資源)과 금속(金屬) 재자원화산업(再資源化産業))

  • Oh, Jae-Hyun;Kim, Joon-Soo;Moon, Suk-Min;Min, Ji-Won
    • Resources Recycling
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    • v.19 no.6
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    • pp.11-26
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    • 2010
  • In order to review the recycling status of urban mine resources in Japan, metal consumption, metal recycling rate and metal recycling industry such as iron scrap, end of life vehiclcs(ELV), waste home appliances and spent IT equipments were surveyed. Japan took rank of top class in the world on the metal consumption and urban mine stock reserve. Metal recycling industries in Japan have been developed through excellent technologies for mineral processing and non-ferrous smelting. On the other hand, the technologies for recycling of rare metals are being developed now. Recycling rate of EL V, waste home appliances and personal computer are higher than the guidelines of the legislative standard.