Journal of Industrial and Engineering Chemistry

  • Volume 67
  • /
  • Pages.210-218
  • /
  • 2018
  • /
  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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EDTA-functionalized KCC-1 and KIT-6 mesoporous silicas for Nd3+ ion recovery from aqueous solutions

  • Ravi, Seenu (Department of Chemical Engineering, Inha University) ;
  • Zhang, Siqian (Department of Chemical Engineering, Inha University) ;
  • Lee, Yu-Ri (Department of Chemical Engineering, Inha University) ;
  • Kang, Kyoung-Ku (Department of Chemical Engineering and Applied Chemistry, Chungnam National University) ;
  • Kim, Ji-Man (Department of Chemistry, Sungkyunkwan University) ;
  • Ahn, Ji-Whan (Korea Institute of Geoscience and Mineral Resource (KIGAM)) ;
  • Ahn, Wha-Seung (Department of Chemical Engineering, Inha University)
  • Received : 2018.04.17
  • Accepted : 2018.06.24
  • Published : 2018.11.25
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Abstract

Ethylenediaminetetraacetic acid (EDTA)-functionalized KIT-6 and KCC-1 mesoporous silicas were prepared via post-synthesis grafting and examined for their ability to promote the recovery of rare earth metal ions such as $Nd^{3+}$ from an aqueous medium. The obtained adsorption isotherms were fitted to the Langmuir model, which gave a maximum adsorption of $Nd^{3+}$ ions of 109.8 and 96.5 mg/g for KIT-6-EDTA and KCC-1-EDTA, respectively, at $25^{\circ}C$ and pH 6. The adsorption kinetic profile of KIT-6 was faster than KCC-1. KIT-6 was also proved to be more stable against desorption under acidic regeneration conditions.

Keywords

Acknowledgement

Supported by : National Research Foundation of Korea (NRF)

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