• Title/Summary/Keyword: Rare Earth

검색결과 975건 처리시간 0.028초

남한의 중생대 화강암중의 가스성분과 유체포유물 연구 (Gas Composition and Fluid Inclusion Studies of the Mesozoic Granitic Rocks in South Korea)

  • 김규한;박성숙;류이치 스기사키
    • 자원환경지질
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    • 제29권4호
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    • pp.455-470
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    • 1996
  • Mesozoic granitic rocks in the Korean peninsula contain $H_2$, $CH_4$, CO and rare $C_2H_6$. The Jurassic Daebo granites mostly belonging to the ilmenite series are predominated in $CH_4$. Meanwhile, the magnetite series Bulguksa granites of Cretaceous age in the Kyongsang basin and Okchon zone are relatively enriched in $CO_2$. The older granites have a wide variation of $CH_4/CO_2$ ratios (0.1~1.0) compared to those of the younger ones (0.1~0.5). This characteristics of gas compositions suggest that the Jurassic granites are principally derived from the partial melting of metasedimentary rocks with much reducing materials in the lower continental crust. On the other hand, the mantle source granitic magmas might be responsible for the Cretaceous granites characterized by dominant and homogeneous $CO_2$ gas compositions. Liquid-vapor homogenization temperatures of quartz in the Jurassic and Cretaceous granites range from 108 to $539^{\circ}C$ (av. $324^{\circ}C$) and 160 to $556^{\circ}C$ (av. $358^{\circ}C$), respectively. Their salinities are between 0.2 and 16.3 wt.% NaCl for the Jurassic granites and 0.4, and 15.6 wt.% NaCl for the Cretaceous ones. Fluid inclusions with solid daughter minerals lying on or near the halite equilibrium curve represent inclusion fluids from the magmatic stage. The type I and II fluid inclusions which are plotted apart from the equilibrium curve are considered to trap in late hydrothermal alteration stage with a increasing influx of metedric water.

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열 반응을 이용한 나노사이즈 마크형성 (Manometer Scale Mark Formation using Thermal Reaction For Storage Application)

  • 정문일;김주호;황인오;김현기;배재철;박인식;마사시 구와하라;준지 토미나가
    • 정보저장시스템학회논문집
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    • 제1권2호
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    • pp.127-131
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    • 2005
  • We report a nanometer scale mark formation using a $PtO_x$ thin film or a TbFeCo rare-earth transition metal film and the mechanism. The multi-layer samples($ZnS-SiO_2/PtOx/ZNS-SiO_2,\;ZnS-SiO_2/TbFeCo/ZnS-SiO_2$) were prepared with a magnetron sputtering method on a polycarbonate or a glass substrate. By laser irradiation of approximately a few nanoseconds, nanometer scale marks were fabricated. During the fabrication process, the thin films were thermally reacted or inter-diffused during the laser irradiation. 75 nm bubble marks in the PtOx multi-layer sample by an approximately 4-ns laser irradiation. Inside the bubble mark, Pt particles with a few nanometer sizes are distributed. The $50{\sim}100$ nm bubble marks in the TbFeCo multi-layer sample by a few nanosecond laser irradiations. We will report the detail structure of the samples, the bubble mark formation process and the mechanism.

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Enhanced Microbial, Functional and Sensory Properties of Herbal Yogurt Fermented with Korean Traditional Plant Extracts

  • Joung, Jae Yeon;Lee, Ji Young;Ha, Young Sik;Shin, Yong Kook;Kim, Younghoon;Kim, Sae Hun;Oh, Nam Su
    • 한국축산식품학회지
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    • 제36권1호
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    • pp.90-99
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    • 2016
  • This study evaluated the effects of two Korean traditional plant extracts (Diospyros kaki THUNB. leaf; DK, and Nelumbo nucifera leaf; NN) on the fermentation, functional and sensory properties of herbal yogurts. Compared to control fermentation, all plant extracts increased acidification rate and reduced the time to complete fermentation (pH 4.5). Supplementation of plant extracts and storage time were found to influence the characteristics of the yogurts, contributing to increased viability of starter culture and phenolic compounds. In particular, the increase in the counts of Streptococcus thermophilus and Lactobacillus delbrueckii subsp. bulgaricus was highest (2.95 and 1.14 Log CFU/mL respectively) in DK yogurt. Furthermore, supplementation of the plant extracts significantly influenced to increase the antioxidant activity and water holding capacity and to produce volatile compounds. The higher antioxidant activity and water holding capacity were observed in NN yogurt than DK yogurt. Moreover, all of the sensory characteristics were altered by the addition of plant extracts. Addition of plant extracts increased the scores related to flavor, taste, and texture from plain yogurt without a plant extract, as a result of volatile compounds analysis. Thus, the overall preference was increased by plant extracts. Consequently, supplementation of DK and NN extracts in yogurt enhanced the antioxidant activity and physical property, moreover increased the acceptability of yogurt. These findings demonstrate the possibility of using plant extracts as a functional ingredient in the manufacture of herbal yogurt.

평행방향/할박 자화 영구자석을 갖는 마그네틱 기어의 설계변수에 따른 토크특성 해석 및 비교 (Comparison and Torque Analysis for Magnetic Gear with Parallel/Halbach Magnetized PMs according to Design Parameters)

  • 홍상아;최장영
    • 한국자기학회지
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    • 제24권5호
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    • pp.152-159
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    • 2014
  • 마그네틱 기어는 두 개 이상의 분리된 장치들 사이에서 기계적인 접촉 없이 토크를 전송한다. 특히, 희토류계 영구자석을 사용한 마그네틱 기어는 고 출력으로 인해 다양한 산업에 적용된다. 따라서 마그네틱 기어는 일반적인 기어를 대체할 수 있다. 본 논문에서는 이차원 유한요소해석을 이용해 평행방향과 할박 자화 마그네틱 기어의 기어비를 선정하고, 내측과 외측 영구자석 두께, 철심 각도, 할박 세그먼트 개수, 내측과 외측 영구자석 자화 패턴과 같은 설계 변수에 따라 토크 해석을 수행하였다. 해석 결과, 개선된 설계변수를 갖는 모델이 초기 설계 모델과 비교해 더 높은 토크를 가짐을 확인하였다.

수소저항합금을 이용한 150ℓ급 수소저장용기의 제작과 특성에 관한 연구 (Fabrication and Characteristics of 150ℓ Class Hydrogen Tank Using Hydrogen Storage Alloy)

  • 강길구;강세선;권호영;이임렬
    • 한국수소및신에너지학회논문집
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    • 제13권2호
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    • pp.110-118
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    • 2002
  • The hydrogen storage vessel having a good heat conductivity along with a simple structure and a low cost for these alloys was designed and manufactured, and then its characteristic properties were studied in this study. The various parts in hydrogen storage vessel consisted of copper pipes and stainless steel of 250 mesh reached the setting temperature after 4~5 minutes, which indicated that storage vessel had a good heat conductivity that was required in application. And also the storage vessel had a good property of hydrogen transport considering that the reaction time between hydrogen and rare-earth metal alloys in storage vessel was found to be within 10 min at $18^{\circ}C$ under 10 atmospheric pressure. It showed that the average capacity of discharged hydrogen volume was found to be $120{\ell}$ for $MmNi_{4.5}Mn_{0.5}$ under discharging conditions of $40^{\circ}C{\sim}80^{\circ}C$ at a constant flow rate of $5{\ell}$/min. It was found that the optimum discharging temperature for obtaining an appropriate pressure of 3atm was determined to be $60^{\circ}C$ for $MmNi_{4.5}Mn_{0.5}$ hydrogen storage alloy.

Optical imaging methods for qualification of superconducting wires

  • Kim, Gracia;Jin, Hye-Jin;Jo, William
    • 한국초전도ㆍ저온공학회논문지
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    • 제16권4호
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    • pp.21-25
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    • 2014
  • In order to develop 2nd generation (2G) high-temperature superconducting (HTS) wires as commercial products, it is necessary to perform a high speed investigation of their superconducting performance. Room-temperature and non-contact optical scanning tools are necessary to verify the microstructure of the superconducting materials, the current flow below the critical temperature, and the critical current density. In this paper, we report our results of an inspection of the electrical transport properties of coated conductors. The samples that we used in our study were highly qualified rare-earth based coated conductors produced via co-evaporation, and $SmBa_2Cu_3O_{7-y}$ (SmBCO) was the superconducting materials used in our studies. A film grown on IBAD-MgO templates shows larger than 400 A/cm at 77 K and a self-field. The local transport properties of the films were investigated by room-temperature imaging by thermal heating. The room-temperature images show structural inhomogeneities on the surface of the films. Bolometric response imaging via low-temperature bolometric microscopy was used to construct the local current mapping at the surface. These results indicate that the non-uniform regions on the surface disturb the current flow, and laser scanning images at room-temperature and at a low-temperature suggest a correlation between the structural properties and transport properties. Thus this method can be effective to evaluate the quality of the coated conductors.

융제법에 의한 RIG 단결정 육성 (Growth of RIG Single Crystals by Flux Technique)

  • 김성현;이석희;정수진
    • 한국세라믹학회지
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    • 제26권4호
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    • pp.459-470
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    • 1989
  • Single crystals of rare-earth iron garnets were grown from solutions of molten lead oxide, lead fluoride, baric oxide, iron oxide, and the oxides of yttrium, samarium orgadolinium. The crystals were grown by slow cooling technique. A convenient composition was 41.8mol% PbO, 20.59mol% PbF2, 8.23mol% B2O3, 20.00mol% Fe2O3 and 10.00mol% R2O3 where R is Y, Sm or Gd. For this experiment, platinum crucibles of size 20, 30cc and a vertical siliconit tube furnace were used. The precipitation temperature of YIG was observed in the range of 115$0^{\circ}C$-112$0^{\circ}C$ and the optimum growth conditions in this experiment were determined. The nucleation rate was controlled by the holding time after the fast colling, the growth rate by the slow cooling conditiions. The form of the grown YIG crystals showed a combination of {110} and {211}, and the size of the crystals grown in this experiment was up to about 9mm under the conditions of holding time 16hour, cooling rate 2$^{\circ}C$/hr. and temperature range 115$0^{\circ}C$-90$0^{\circ}C$. The precipitatin temperature of SmIG was observed in the range of 105$0^{\circ}C$-98$0^{\circ}C$ and the size of the crystals grown in this experiment was up to about 5mm under the conditiions of holding time 16hours, cooling rate 2$^{\circ}C$/hr. and temperature range 100$0^{\circ}C$-80$0^{\circ}C$.

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VTE 처리된 강유전 LiNbO3 단결정 내의 Nd3+와 Er3+ 초미세 구조의 비등방성 (Anisotropic Hyperfine Structures of Nd3+ and Er3+ in VTE-Treated Ferroelectric LiNbO3 Crystals)

  • 박일우;조성호;김영미;전웅;김상수;김원정;김봉구;손재민
    • 한국자기학회지
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    • 제15권2호
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    • pp.118-124
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    • 2005
  • 용융상태의 조성비와 동일하게 성장된 $LiNbO_3$(CLN) 단결정은 많은 내부결함으로 인하여 예리한 전자스핀 공명신호를 관측하기가 어려운데, VTE(Vapor Transport Equilibrium) 처리로 내부결함의 농도를 감소시켜주면 공명신호가 좀 더 날카롭게 관측되어 더 정밀한 스핀 하밀톤 함수의 매개상수를 결정할 수 있다. 본 연구에서는 성장된 CLN에서 알아보기 힘들었던 $Nd^{3+}$$Er^{3+}$의 초미세 구조를 VTE 방법으로 처리한 시료로 액체헬륨 온도에서 관측하고, 실험적으로 얻은 스펙트럼의 비등방성에서 자성이온 주위의 국소구조에 대하여 논의하였다. 분석 결과로부터 $Nd^{3+}$$Er^{3+}$ 희토류 이온은 $LiNbO_3$결정 내에서 Li 자리를 선호한다는 것을 제안한다.

Ni/Fe(001)의 자성과 자기이방성에 대한 제일원리계산 (Magnetism and Magnetocrystalline Anisotropy of Ni/Fe(001) Surface: A First Principles Study)

  • 권오룡;홍순철
    • 한국자기학회지
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    • 제25권4호
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    • pp.101-105
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    • 2015
  • 희토류 금속이나 4d/5d 전이금속을 포함하지 않은 3d 전이금속 Fe와 Ni 원소만을 적절하게 배열해도 강한 수직 자기이방성을 가질 수 있음을 예측한 이론 계산 결과가 최근 보고된 바 있다. 그 계산에서는 Fe 층을 표면으로 하는 계만을 고려하였는데 본 논문에서는 Ni가 표면일 때의 자기이방성 에너지를 제일원리계산 방법으로 계산하여 자기이방성을 조절할 수 있는 방안이 있을 수 있는지를 알아 보았다. Fe(001) 표면에 Ni 원소 한 층이 덮였을 때[Ni/Fe(001)]의 자성과 자기이방성을 제일원리계산 방법으로 VASP과 FLAPW 방법을 상호 보완적으로 사용하면서 계산 결과를 비교해 보았다. VASP에 의한 결과는 FLAPW 방법으로 얻은 결과와 큰 차이가 없었고, Fe와 Ni의 강한 띠 혼합으로 Fe와 Ni의 자기모멘트가 모두 증가하였으며 Ni/Fe(001)은 수평 자기이방성을 가지는 것으로 계산되었다. 원자 별 자기이방성 기여도 계산에 의하면 자기이방성에 결정적인 역할을 하는 것은 Ni표면 층임을 알 수 있었다.

Temperature Dependent Cation Distribution in Tb2Bi1Ga1Fe4O12

  • Park, Il-Jin;Park, Chu-Sik;Kang, Kyoung-Soo;Kim, Chul-Sung
    • Journal of Magnetics
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    • 제13권3호
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    • pp.110-113
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    • 2008
  • In this study, heavy rare earth garnet $Tb_2Bi_1Ga_1Fe_4O_{12}$ powders were fabricated by a sol-gel and vacuum annealing process. The crystal structure was found to be single-phase garnet with a space group of Ia3d. The lattice constant $a_0$ was determined to be 12.465 ${\AA}$. From the analysis of the vibrating sample magnetometer (VSM) hysteresis loop at room temperature, the saturation magnetization and coercivity of the sample are 7.64 emu/g and 229 Oe, respectively. The N$\acute{e}$el temperature($T_N$) was determined to be 525 K. The M$\ddot{o}$ssbauer spectrum of $Tb_2Bi_1Ga_1Fe_4O_{12}$ at room temperature consists of 2 sets of 6 Lorentzians, which is the pattern of single-phase garnet. From the results of the M$\ddot{o}$ssbauer spectrum at room temperature, the absorption area ratios of Fe ions on 24d and 16a sites are 74.7% and 25.3%(approximately 3:1), respectively. These results show that all of the non-magnetic Ga atoms occupy the 16a site by a vacuum annealing process. Absorption area ratios of Fe ions are dependent not only on a sintering condition but also on the temperature of the sample. It can then be interpreted that the Ga ion distribution is dependent on the temperature of the sample. The M$\ddot{o}$ssbauer measurement was carried out in order to investigate the atomic migration in $Tb_2Bi_1Ga_1Fe_4O_{12}$.