• Title/Summary/Keyword: Rare Earth

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Magnetostrictive Properties of Polymer-Bonded Fe-Co Based Alloy Composites

  • S. M. Na;S. J. Suh;K. H. Shin;Lee, Y. S.;S. H. Lim
    • Proceedings of the Korean Magnestics Society Conference
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    • 2002.12a
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    • pp.138-139
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    • 2002
  • Polymer-bonded magnetostrictive composites have some distinct advantages over conventional type materials in being cost effective and suitable for high frequency applications due to high electrical resistivity. Composites of rare earth based alloys were reported to show good magnetostrictive characteristics both in static and dynamic conditions [1]. It was originally thought that the application of the polymer-bonding technique to transition metal alloys is straightforward. (omitted)

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Rare earths from secondary sources: profitability study

  • Innocenzi, Valentina;De Michelis, Ida;Ferella, Francesco;Veglio, Francesco
    • Advances in environmental research
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    • v.5 no.2
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    • pp.125-140
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    • 2016
  • The paper is focused on the economic analysis of two hydrometallurgical processes for recovery of yttrium and other rare earth elements (REEs) from fluorescent phosphors of spent lamps. The first process includes leaching with sulphuric acid and precipitation of a mixture of oxalates by oxalic acid, the second one includes leaching with sulphuric acid, solvent extraction with D2EHPA, stripping by acid and recovery of yttrium and traces of other rare earths (REs) by precipitation with oxalic acid. In both cases the REEs were recovered as oxides by calcination of the oxalate salts. The economic analysis was estimated considering the real capacity of the HydroWEEE mobile's plant ($420kg\;batch^{-1}$). For the first flow-sheet the cost of recycling comes to $4.0{\euro}kg^{-1}$, while the revenue from the end-product is around $5.40{\euro}kg^{-1}$. The second process is not profitable, as well as the first one, taking into account the composition of the final oxides: the cost of recycling comes to $5.2{\euro}kg^{-1}$, while the revenue from the end-product is around $3.56{\euro}kg^{-1}$. The process becomes profitable if the final RE oxide mixture is sold for nearly $50{\euro}kg^{-1}$, a value rather far from the current market prices but not so unlikely since could be achieved in the incoming years, considering the significant fluctuations of the Res' market.

Allanite Mineralization in the Mt. Eorae Area (어래산지역(御來山地域)의 갈렴석광상(褐簾石鑛床))

  • Oh, Mihn-Soo
    • Economic and Environmental Geology
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    • v.22 no.2
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    • pp.151-166
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    • 1989
  • A study of rare-earth mineralization in Kyemyungsan metasedimentary formation of Precambrian Ogcheon Group was carried out in the Mt. Eore Area near Choongju City based on the thorium (Th) and uranium (U) count data of geophysical airborne survey. This rare-earth mineralization was found in the magnetite-bearing banded quartizite which contains diagnostically some amounts of the metamict allanite. The brown colored allanites are distributed as aggregates of fine grains and sometimes banded structures with magnetite (inter growth) along the banding. The ore bed is displaced by the small faults and granite intrusions, and separated 5 ore blocks. The dimensions of the outcrop are 50-80 m in width, 1,500 m in length with the strike of $N70-80^{\circ}E$ and dip of $50-80^{\circ}NW$. In the field, the values of total gamma ray count of GR-101A scintillometer were able to measure more than 400 cps and maximum 1,500 cps, which data are coincided with the values of GR-310 gamma ray spectrometer and the gamma ray count of well logging data. The chemical compositions of the allanites from EPMA data are ranged from$\sum^{TR_2O_3}$ 18.57% to 26.00%, and the cerium oxides ($Ce_2O_3$) of allanite are positive relation with $La_2O_3$, MgO, FeO, MnO and negative relation with $SiO_2$, $Al_2O_3$, $Nd_2O_3$. The result of Neutron Activation Analysis (N.A.A.), Multi-Channel Analysis (M.C.A.) and wet chemistry of 25 outcrop samples for the elements of REE, Zr, U, Th shows strong anomalies. The good correlation elements with the thorium (Th) are the elements of La, Ce, LREE, $TR_2O_3$, Pr, Sm, Yb, Lu by the increasing order.

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Properties of Glass-Ceramic in ${Nd_2}{O_3}-{Al_2}{O_3}-{SiO_2}$System (${Nd_2}{O_3}-{Al_2}{O_3}-{SiO_2}$ 계의 결정화유리의 물성)

  • Choi, Woo-Hyeong;Kim, Hyeong-Sun
    • Korean Journal of Materials Research
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    • v.11 no.7
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    • pp.545-549
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    • 2001
  • Glass-ceramics were prepared and evaluated for the properties to expand the scope of application of the rare earth aluminosilicate glasses, A glass-ceramic added with $TiO_2$as a nucleating agent, which was crystallized internally and it was characterized for physical, thermal and mechanical properties of crystal and residual glass in the glass-ceramic, X-ray diffractometer reveals an unknown crystal as $Nd_{4.6}Si_{7.6}Al_{4.0}Ti_{2.4}O_{32}$ which was found in surface and internal crystals dependent on composition and heat treatments. The thermal expansion coefficients of glass-ceramics were $5.4~6.2{\times}10^{-6}/^{\circ}C$, which increased with increasing crystal growth. Considering that the hardness and the elastic constant of crystal in glass-ceramics are 12GPa and 220GPa, respectively, the application of the glass-ceramics would be applicable for structural materials at elevated temperature.

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Cytotoxicity and DNA Damage in Human Lung Cells Treated with Lanthanum Oxide and Neodymium Oxide (산화란타늄, 산화네오디뮴이 세포독성 및 DNA손상에 미치는 영향)

  • Kim, Jong Kyu;Kim, Soo Jin;Kang, Min Gu;Chung, Young Hyun
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.23 no.2
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    • pp.50-56
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    • 2013
  • Objectives: The present study investigated cytotoxicity and DNA damage in human lung cells in vitro. Methods: Neodymium oxide and lanthanum oxide were dispersed by ultrasonic treatments. The assay was performed with MRC-5 (Human male fetus lung cell). Cytotoxicity and comet assay of lanthanum oxide and neodymium oxide were measured after 24 and 48 hours incubation. Results: After 24 hours of exposure to rare earth metals, the cytotoxicities of lanthanum oxide in more than $1{\mu}M$ concentration groups were significantly increased when compared to the control group, but the cytotoxicities of neodymiun oxide in more than $100{\mu}M$ concentration groups were statistically increased. After 48 hours exposure, cytotoxicities of both materials were statistically increased in $100,000{\mu}M$ concentration groups. Olive tail moments of the lanthanum oxide treated group were significantly increased when compared to the control group. Conclusions: The cytotoxicity of lanthanum oxide was higher than that of neodymium oxide. The DNA of MRC-5 cells treated with lanthanum oxide for 48 hours were significantly damaged.

Recovery of Rare Earth Elements from Nd Magnet Scrap Using PVC (PVC에 의한 네오디뮴 자석 스크랩으로부터 희토류 회수)

  • Lee, So-Yeong;Park, Sung-Hun;Son, Injoon;Sohn, Ho-Sang
    • Resources Recycling
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    • v.27 no.1
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    • pp.38-44
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    • 2018
  • A large amount of Nd-Fe-B magnet scraps are generated during magnet manufacture process. In this study, selective chlorination of the rare earth elements by hydrogen chloride gas which obtained from the pyrolysis of polyvinyl chloride (PVC) was investigated. In thermogravimetric analysis, drastic weight loss was occurred at about 500 K and 710 K. At the isothermal experiments, the weight loss reaches about 30% above 673 K. XRD patterns characterized that after each experiments, ${\alpha}$-Fe, Nd oxychloride, Nd chloride, and Fe chlorides were formed, and the leaching residues remain only ${\alpha}$-Fe. The yields of Nd, Dy, and Fe for the isothermal experiment were increased with temperature and peaked at 873 K. As PVC ratio increased, the yields of Nd, Dy and Fe were also increased.