• 한국수소및신에너지학회논문집
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• 제34권2호
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• pp.205-211
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• 2023

Hydrogen gas is light and diffuses very quickly. Therefore, when a leakage accident occurs, the damage is great, so a technology that can quickly measure the leakage in the air at a long distance is needed. In order to develop hydrogen gas leaked in the atmosphere in a non-contact manner, an experiment was performed to measure hydrogen gas using a lidar technology using the Raman effect. Hydrogen Raman signals were detected using a UV LED light source, which is a Raman light source, and a spectrometer in the ultraviolet region including an optical filter in the 400-430 nm band. To develop this, a Raman lidar optical structure was designed to measure the hydrogen Raman signal at a certain distance, and the hydrogen Raman spectrum was confirmed using a standard gas to evaluate the performance of this optical structure. The linearity was found to be 0.99 using hydrogen standard gas (10, 50, 100, 500, 1,000 ppm). Accordingly, a Raman lidar capable of measuring hydrogen gas rapidly diffusing in the air in an open state was developed to improve the limitations of existing hydrogen sensors.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 춘계학술대회 논문집
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• pp.366-369
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• 1999

Synthetic diamond films have been deposited on the silicon(100) surface and molybdenum substrates using an microwave plasma enhanced vapor deposition (MWPECVD) method. The effect of deposition time, surface morphology, X-ray diffraction pattrm, infrared transmittance and Raman Scattering have been studied, The diamond film deposited on Mo substrate for (100) hours at 40 torr H$_2$-CH$_4$O$_2$ gas system have been shown 1${\mu}{\textrm}{m}$/h of growth rate and good crystallization

• Bulletin of the Korean Chemical Society
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• 제34권6호
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• pp.1668-1672
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• 2013

We developed a standoff Raman detection system for explosive molecules (EMs). Our system was composed of reflective telescope with 310 mm diameter lens, 532 nm pulse laser, and Intensified Charge-Coupled Device (ICCD) camera. In order to remove huge background noise coming from ambient light, laser pulses with nanosecond time width were fired to target sample and ICCD was gated to open only during the time when the scattered Raman signal from the sample arrived at ICCD camera. We performed standoff experiments with military EMs by putting the detector at 10, 20 and 30 m away from the source. The standoff results were compared with the confocal Raman results. Based on our standoff experiments, we were able to observe the peaks in the range of 1200 and $1600cm^{-1}$, where vibrational modes of nitro groups were appeared. The wave numbers and shapes of these peaks may serve as good references in detecting and identifying various EMs.

• 대한방사선기술학회지:방사선기술과학
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• 제27권2호
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• pp.45-50
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• 2004

방사선검출기에 사용되는 다이아몬드는 그 비저항이 $10^{12}[{\Omega}m]$로 매우 크기 때문에 고전압 하에서도 누설전류가 매우 작아 실리콘과 달리 p-n접합을 하지 않고 바로 고전압을 걸 수 있는 이점이 있다. 또한 절연파괴 전압이 매우 크기 때문에 이동속도가 포화되는 전압까지 올릴 수 있다. 이 결과 다이아몬드 내에서의 전하 이동속도는 실리콘의 최대속도보다 약 20배 정도 빠르다. $200[{\mu}m]$ 두께의 박막을 통해 전하가 모두 수집되는 시간은 불과 1[ns] 정도이다. 이상과 같이 독특한 다이아몬드의 성질을 이용하여 방사선검출기에 사용되는 물질로 파고계수형 전리조나 분광계, 열형광선량계, 형광검출기 그리고 핵방사선검출기 등에 사용된다. 본 연구에서는 마이크로파 플라즈마 CVD법으로 $CH_4-H_2-O_2$계로부터 몰리브덴기판 위에 100시간 동안 성장시킨 결과 약 $100[{\mu}m]$의 두께를 가진 결정성이 좋은 방사선검출기용 다이아몬드막을 성장시킬 수 있었고, X-선 방사선량에 따른 방사선검출기의 전류파형을 측정한 결과 방사선량에 따라 전류가 증가됨을 알 수 있었다.

• 한국군사과학기술학회지
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• 제24권4호
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• pp.374-381
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• 2021

Raman spectrometers are studied and developed for the military purposes because of their nondestructive inspection capability to capture unique spectral features induced by molecular structures of colorless and odorless chemical warfare agents(CWAs) in any phase. Raman spectrometers often suffer from random noise caused by their detector inherent noise, background signal, etc. Thus, reducing the random noise in a measured Raman spectrum can help detection algorithms to find spectral features of CWAs and effectively detect them. In this paper, we propose a denoising autoencoder for Raman spectra with a loss function for sample efficient learning using noisy dataset. We conduct experiments to compare its effect on the measured spectra and detection performance with several existing noise reduction algorithms. The experimental results show that the denoising autoencoder is the most effective noise reduction algorithm among existing noise reduction algorithms for Raman spectrum based standoff detection of CWAs.

• 한국지능시스템학회:학술대회논문집
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• 한국퍼지및지능시스템학회 2006년도 춘계학술대회 학술발표 논문집 제16권 제1호
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• pp.203-207
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• 2006

본 논문에서는 공초점 라만 스펙트럼을 이용하여 기저세포암종(basal cell carcinoma, BCC)를 검출하는 문제에 대하여 다룬다. 특히, 라만 스펙트럼 측정시 발생하는 잡음 성분 및 변별력이 없는 성분을 제거하기 위한 방법으로 Fisher의 척도를 활용한 스펙트럼 필터링 방법을 제안한다. 특징벡터의 차원을 줄이기 위하여 주축분석방법을 사용하였고, 분류방법으로는 MAP(maximum a posteriori) 방법을 이용하였다. 실험결과 제안한 방법이 특징벡터의 차원을 줄일 수 있을 뿐만 아니라, 검출 결과도 향상됨을 확인하였다

• 한국전기전자재료학회논문지
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• 제25권6호
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• pp.439-444
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• 2012

For the application of photo-detector as active layer, we have studied how to deposit SiGe thin film using an independent Si target and Ge target, respectively. Both targets were synthesized by purity of 99.999%. Plasma generators were generated by radio frequency (rf, 13.56 MHz) and direct current (dc) power. When Ge and Si targets were sputtered by dc and rf power, respectively, we could observe the growth of highly crystalline Ge thin film at the temperature of $400^{\circ}C$ from the result of raman spectroscopy and X-ray diffraction method. However, SiGe thin film did not deposit above method. Inversely, we changed target position like that Ge and Si targets were sputtered by rf and dc power, respectively. Although Ge crystalline growth without Si target sputtering deteriorated considerably, the growth of SiGe thin film was observed with increase of Si dc power. SiGe thin film was evaluated as microcrystalline phase which included (111) and (220) plane by X-ray diffraction method.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2003년도 추계학술발표회초록집
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• pp.54-54
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• 2003

DLC films were deposited on Si(100) substrates by inductively coupled plasma (ICP) assisted chemical vapor deposition (CVD). A mixture of acetylene (C$_2$H$_2$) and argon (Ar) gases was used as the precursor and plasma source, respectively. The structure of the films was characterized by the Raman spectroscopy. Results from the Raman spectroscopy analysis indicated that the property change of the DLC films is due to the sp$^3$ and sp$^2$ ratio in the films under various conditions such as ICP power, working pressure and RF substrate bias. The hydrogen content in the DLC films was determined by an electron recoil detector (ERB). The roughness of the films was measured by atomic force microscope (Am). A microhardness tester was used for the hardness and elastic modulus measurement. The DLC film showed a maximum hardness of 37㎬. In this work, the relationship between deposition parameters and mechanical properties were discussed.

• 한국화재소방학회논문지
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• 제30권4호
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• pp.27-38
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• 2016

본 논문은 현재 국외기술에 의존하고 있는 광센서 선형감지기를 이용한 화재감지시스템인 분산온도감지(DTS) 시스템을 국산화 기술로 개발하기 위한 연구이다. 이에 본 연구에서는 광섬유 내에서 발생되는 빛의 역산란광 중 온도감지에 주로 사용되는 라만산란광의 전기적 신호파형을 오실로스코프를 이용하여 분석하였다. 측정결과 Stokes 신호파형은 온도가 상승해도 변화량이 거의 없었으나, 온도에 민감한 anti-Stokes 신호파형은 상대적으로 그 값이 증가하는 것을 확인할 수 있었다. 그리고 라만산란광을 이용하여 화재를 감지할 수 있는 광중계기 및 광수신기로 구성된 광센서 선형 화재감지시스템인 K-DTS 시스템을 개발하였다. 개발된 K-DTS 시스템에 대하여 차동식 및 정온식 감도시험기를 이용하여 차동식 및 정온식 감지기로서의 감도시험을 진행해 본 결과 형식승인 기준을 만족하고 있는 것을 확인할 수 있었다. 또한, 개발된 K-DTS 시스템의 성능평가를 위해 국외에서 수입되어 가장 많이 사용되고 있는 S-DTS 시스템과 성능비교실험을 진행하였다. 모형터널을 이용한 성능실험결과 화재감지위치 및 화재온도 측정에서 유사한 성능을 나타내는 것을 확인할 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제13권5호
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• pp.520-526
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• 1992

The intramolecular fundamental vibrations of $CH_3CN$ trapped in solid argon matrix have been reinvestigated by means of FT-IR spectroscopy in the spectral range of 4000-500 $cm^{-1}$. By employing a quantum detector, infrared spectra could be obtained at matrix to solute ratio of 10000, allowing the clarification of the peaks due to monomeric species more clearly. Temperature controlled diffusion was initiated to identify the dimeric and polymeric species in terms of difference spectra. The assignments of monomeric and dimeric species are found, in general, to agree with the earlier work performed at higher concentration (Ar/$CH_3CN$ = 1500) using a dispersive spectrometer. Nonetheless the difficulty of minute differences between the earlier infrared and Raman spectroscopic results could be resolved. Moreover, the previously unnotified peaks due to polymeric species have been identified.