• 제목/요약/키워드: Rajasthan

검색결과 105건 처리시간 0.026초

The Kinetics and Mechanism for the Oxidation of Nicotinic Acid by Peroxomonosulfate in Acidic Aqueous Medium

  • Agrawal, Anju;Sailani, Riya;Gupta, Beena;Khandelwal, C.L.;Sharma, P.D.
    • 대한화학회지
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    • 제56권2호
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    • pp.212-216
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    • 2012
  • The kinetics of oxidation of nicotinic acid by peroxomonosulfate (PMS) has been studied in acetate buffers. Stoichiometry of the reaction corresponds to the reaction of one mole of the oxidant with a mole of nicotinic acid. N${\rightarrow}$O product has been confirmed both by UV visible and IR spectroscopy. The reaction is second order viz. first order with respect to each reactant. Activation parameters have also been evaluated. A plausible reaction mechanism is mentioned and the derived kinetic rate law accounts for experimental observations.

Kinetics and Mechanism of Ruthenium(III) Catalyzed Oxidation of Butanone and Uncatalyzed Oxidation of Cychlohexanone by Cerium(IV) in Acid Sulphate Medium

  • Sharma, Priyamvada;Hemkar, Shalini;Khandelwal, C.L.;Sharma, P.D.
    • 대한화학회지
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    • 제56권1호
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    • pp.28-33
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    • 2012
  • The kinetics of ruthenium(III) chloride catalyzed oxidation of butanone and uncatalyzed oxidation of cyclohexanone by cerium(IV) in sulphuric acid medium have been studied. The kinetic rate law(I) in case of butanone conforms to the proposed mechanism. $$-\frac{1}{2}\frac{d[Ce^{IV}]}{dt}=\frac{kK[Ru^{III}][butanone]}{1+K[butanone]}$$ (1). However, oxidation of cyclohexanone in absence of catalyst accounts for the rate eqn. (2). $$-\frac{1}{2}\frac{[Ce^{IV}]}{dt}=\frac{(k_1+k_1K^'[H^+])[Ce^{IV}][Cyclohexanone]}{1+K_3[HSO_4^-]}$$ (2) Kinetics and activation parameters have been evaluated conventionally. Kinetically preferred mode of reaction is via ketonic and not the enolic forms.

Screening for the Hormonal Properties of the Chloroform Extract of Carica papaya Linn. Seeds for Antifertility Investigation

  • Mishra, P.K.;Pathak, N.;Manivannan, B.;Lohiya, N.K.
    • Natural Product Sciences
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    • 제6권1호
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    • pp.5-10
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    • 2000
  • The chloroform extract of the seeds of Carica papaya has been screened for the hormonal properties using ovariectomized female rats for estrogenicity, estrogen primed immature rats for progestogenicity and castrated adult male rats for androgenicity. The results revealed that the extract lacks progestogenicity and androgenicity as evident from the failure of the extract treated animals to mimic progestogen and androgen related changes in the target tissues. The increased weight of vagina and uterus, open status of vagina, cornified and epithelial cells in the vaginal smears and hypertrophy in the uterine epithelium, endometrium and stroma with increased glycogen and sialic acid content in the uterus of the chloroform extract treated animals, which are comparable to those of the ovariectomized estrogen treated animals, suggest that the chloroform extract possesses mild estrogenic activity.

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인도 라자스탄지방의 양귀비노균병에 대한 다이센의 방제효과 (Control of Opium Poppy Downy Mildew by Dithane Flowable and Dithane M-45 in Rajasthan, India)

  • 치마 H.S.;B.P. 차크라바르티;B.B. 랄타코레
    • 한국응용곤충학회지
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    • 제26권4호
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    • pp.269-272
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    • 1987
  • 다이센 수화제와 다이센 M-45, 비침투성 살균제를 공시하여 양귀비 노균병에 대한 약제 방제효과를 포장에서 조사하였다. 상기 다이센계통의 두약제는 타약제에 비하여 노균병의 방제에 효과적이었으며 라텍스 수량을 현저히 증가시켰다.

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Kinetics and Mechanism of Electron Transfer Reaction: Oxidation of Sulfanilic Acid by N-Chloro-p-Toluene Sulfonamide in Acid Perchlorate Medium

  • Sailani, Riya;Bhasin, Meneka;Khandelwal, C.L.;Sharma, P.D.
    • Bulletin of the Korean Chemical Society
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    • 제35권1호
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    • pp.111-116
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    • 2014
  • The kinetics and mechanism of oxidation of sulfanilic acid by N-chloro-p-toluene sulfonamide (chloramine-T) have been studied in acid medium. The species of chloramine-T were analysed on the basis of experimental observations and predominantly reactive species was taken into account for proposition of most plausible reaction mechanism. The derived rate law (1) conforms to such a mechanism. $$-\frac{d[CAT]}{dt}=\frac{kK_1[RNHCl][SA]}{K_1+[H^+]}$$ (1) All kinetic parameters were evaluated. Activation parameters such as energy and entropy of activation were calculated to be $(61.67{\pm}0.47)kJmol^{-1}$ and $(-62.71{\pm}2.48)kJmol^{-1}$ respectively employing Eyring equation.

Quitline Activity in Rajasthan, India

  • Gupta, Rakesh;Verma, Vinit;Mathur, Pankaj
    • Asian Pacific Journal of Cancer Prevention
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    • 제17권sup2호
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    • pp.19-24
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    • 2016
  • Quitline activity in Rajasthan, India is a voluntary activity of Rajasthan Cancer Foundation (RCF) since April 2013. To kick-off, it took the benefit of the State Government- PIRAMAL SWASTHYA (PS)1 collaborative 104 Health Information Helpline that existed already in public-private partnership. It is a reactive quitline that helps callers through the counselors and nursing staff trained specifically through the weekly sessions held by the first author, the RCF resource on quitline. Besides structuring of the scripts for primary intervention and follow-ups after 1 week, 1 month, 6 months and a year, he also monitors calls, advices and coordinates with the supervisors to manage and analyze the data base, and reports to the PS lead at the Jaipur Center on overall performance and to plan strategic communication with the State Government on its outcomes. The quitline has limitations of its informal existence through a voluntary effort of RCF, no specific resource allocation, suboptimal data management, minimal awareness in the masses due to poor IEC (Information, Education and Communication; except its efforts made by RCF in last 1 year through the government-run State TV and City Radio) and staff shortage and its attrition due to lack of plan for career advancement. Despite these challenges in the year 2013, the quit line has registered a quit rate (for complete abstinence) of 19.93% amongst 1525 callers. The quit rate were 58.01% (304/ 524) among the responders at the 3rd follow-up at 18 months (in September 2014)2. In view of an increase in quit rate by 5- 9 times over the prevailing quit rate in the former ever daily users [both smokers and the users of smokeless tobacco (SLT)], efforts are being made by RCF in concurrence with PS to have this cost-effective model established formally with optimal resource allocation in collaboration with willing agencies (the State and Central Governments and the International Quitline Agencies) and its replication in 4 more states where PS is collaborating with the respective state governments similarly (Assam, Chhattisgarh, Jharkhand and Karnataka).