• Title/Summary/Keyword: Radiation Properties

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Influence of Quaternary Ammonium Anion Exchange Moieties onto Mechanical Properties of Radiation-grafting Anion Exchange Membranes (방사선그라프팅 음이온교환막의 기계적 물성에 대한 4차 암모늄 음이온교환기의 영향)

  • Ko, Beom-Seok;Sohn, Joon-Yong;Shin, Junhwa
    • Journal of Radiation Industry
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    • v.6 no.1
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    • pp.49-54
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    • 2012
  • Various anion exchange membranes were prepared by radiation graft copolymerization of vinylbenzyl chloride onto fluorinated films and subsequent quaternization with various tertiary amines such as trimethylamine, N,N-dimethylbuthylamine, N,N-dimethylaniline, and N-methylpiperidine. The quaternizations of the anion exchange membranes were confirmed by measuring of the ion exchange capacities of the membranes. The mechanical properties and the water uptakes were also measured. The elongation at break was found to be largely dependent on the fluorinated film, the quateranry ammonium, and the degree of grafting. The results indicate that the poly (ethylene-alt-tetrafluoroethylene) with quaternized trimethylamine moiety exhibits higher flexible property compared to the other prepared anion exchange membranes.

Effects of Electron Beam Irradiation on Mechanical Properties of HDPE/α-Al2O3 Composites (전자선 가교에 의한 HDPE/α-Al2O3 복합재료의 기계적 특성 평가)

  • Jung, Seung Tae;Shin, Bum Sik;Kim, Hyun Bin;Kim, Tae Uk;Jeun, Joon Pyo;Kang, Phil Hyun
    • Journal of Radiation Industry
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    • v.5 no.2
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    • pp.131-135
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    • 2011
  • In this study, we fabricated the HDPE and ${\alpha}-Al_2O_3$ composites with PE-g-MA as a function of the ${\alpha}-Al_2O_3$ nanopowder weight ratios. The electron beam irradiations on HDPE/${\alpha}-Al_2O_3$ composites were carried out over a range of absorbed doses from 20 to 200 kGy to make three-dimensional network structures. The mechanical properties were characterized using UTM for confirming the changes of the flexural strength and tensile strength. It was observed that the mechanical properties of HDPE were enhanced by the addition of ${\alpha}-Al_2O_3$. However, the strength of the 5 wt% ${\alpha}-Al_2O_3$ added composites decreased due to the nano-powder aggregation. The mechanical properties of composites were increased as increasing the electron beam irradiation up to 150 kGy. We believed that the electron beam irradiated HDPE/${\alpha}-Al_2O_3$ composites can be a good candidate for a variety of industrial applications.

Spectral Radiative Characteristics of Heat Resisting Ceramics Materials (내열성 세라믹스 재료의 분광복사특성)

  • Sang, Hie Sun
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.1
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    • pp.35-40
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    • 2001
  • A spectral measurement system for reflection and transmission properties by using an optical fiber and an ellipsoidal mirror was newly developed. The hemispherical reflectance and transmittance spectra of several heating resisting ceramics materials were measured from visible to middle infrared region. The directional characteristics of reflection and transmission were also investigated in consideration of the absorptance. The measured data were analyzed by using a four flux model of radiation transfer, The radiation properties could be estimated by the obtained scattering and absorption coefficient spectra.

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Evaluation of Physical Properties of Ethylene Vinyl Acetate/Silicone Emulsion for Radon Shielding Prepared by Electron-beam Irradiation (전자선 조사에 의해 제조된 라돈 차폐용 ethylene vinyl acetate/silicone 에멀젼의 물리적 특성 평가)

  • Jong-Seok Park;Jang-Gun Lee;Sung-In Jeong;Jun-Pyo Jeon;Yoon-Mook Lim;Jae-Hak Choi;Kap-Soo Kim
    • Journal of Radiation Industry
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    • v.17 no.4
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    • pp.369-375
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    • 2023
  • Radon, a carcinogenic substance generated from soil or building materials, have to be fundamentally blocked from entering indoors. In this study, ethylene vinyl acetate (EVA)/silicone emulsions with excellent mechanical and thermal properties and effective blocking of radon gas were prepared by using radiation technology. As the electron-beam irradiation does increased, a partially crosslinked structure was formed in EVA molecular chain, increasing tensile properties and adhesive strength. The EVA/silicone film showed excellent thermal stability without deformation. In addition, the non-irradiated EVA/silicone film showed a radon blocking rate of about a 75%, while the EVA/silicone film irradiated with 3 and 5 kGy showed an excellent radon blocking rate of over 90% due to the formation of crosslinked structure in the EVA molecular chain. These results indicated that the radiation technology can effectively block radon by forming a partially crosslinked structure of EVA/silicone emulsion to improve tensile property, adhesive strength, and deformation stability.

A Study On the Radiation Corrections Applied to Thermocouple Measurements in Non-premixed Counterflow Flames (비예혼합 역류화염에서 열전대 측정을 적용하기 위한 복사보정에 관한 연구)

  • 오율권;허준영;차경옥
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.2
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    • pp.209-218
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    • 2002
  • The temperature field of a counterflow non-premixed flame is investigated using thermocouples of two sizes. A thermal balance is performed on the thermocouple in order to calculate the magnitude of the radiation corrections involved. Both the thermocouple wire and bead are separately considered to be the relevant thermal surface to which convective heat transfer takes place, and from which radiation lasses occur. The flame is also simulated by using a detailed chemical kinetic mechanism in a previously developed computer code. The local thermo-physical properties of the gas mixture, required to calculate the corrections, are determined both from the simulation, and by approximating the properties of the mixture as those of molecular nitrogen at the measured temperatures. It is concluded that the thermocouple wire is the appropriate thermal surface to which radiation corrections apply, in the absence of information about the gas mixture, its properties can be reasonably approximated by those of nitrogen rm ($N_2$), and the radiation corrections are very sensitive to misalignments in the temperature and velocity fields.

Thermal Properties of Chloroprene Rubber with $^{60}Co\;{\gamma}$-ray Irradiation ($^{60}Co\;{\gamma}$-선 조사에 따른 클로프렌 고무의 열적 특성)

  • Kim, Ki-Yup;Lee, Chung;Ryu, Boo-Hyung
    • Journal of the Korean Society of Safety
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    • v.18 no.4
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    • pp.64-70
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    • 2003
  • The thermal properties of chloroprene rubber (CR) with $^{60}Co\;{\gamma}$-ray irradiation has been investigated. The prepared CR was irradiated up to 1000kGy radiation dose by $^{60}Co\;{\gamma}$-ray and the radiation degradation of CR was investigated by thermogravimetric analysis and differential acanning calorimetry. Dynamic mechanical properties measurement and FT-IR observation are carried out as well. From these analyses results, the glass transition temperature($T_g$), decomposition onset temperature(DOT), oxidative induction time(OIT), the peak temperature of loss modulus and mechanical tan ${\delta}$ values were compared for the radiation degradation level of CR. The tendency between $T_g$ and peak temperature of loss modulus and mechanical tan ${\delta}$ agreed well with radiation doses. Decomposition temperature, OIT and DOT showed the same tendencies as increasing radiation doses. It was verified that these analyses are available to estimate the degradation level of CR.

Comparison of Three Radiation Sources on Quality Properties of Three Dried Condiments (건조 향신료 3종에 대한 방사선종별 조사효과 비교)

  • Park, Kyung-Sook
    • Journal of Radiation Industry
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    • v.8 no.2
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    • pp.83-88
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    • 2014
  • Application of X-ray irradiation of dried condiments was studied using commercially prepared dried garlic, onion and welsh onion flakes as model samples. Total load of aerobic microbes (TAM), color differences, and generation of off-flavor were quantified for samples individually irradiated with gamma rays, electrons, or X-rays. TAM load was decreased by irradiation in a dose-dependent manner. The three types of radiation did not differ in the extent of TAM reduction (P>0.05). The samples did not differ in color. Off-flavor was detected from 6 kGy-irradiated samples, regardless of radiation sources. The results indicated that X-ray irradiation could be used for irradiation of dried condiments with the same effects as gamma rays and an electron beam.

The Properties of Open-Ended Meander Slot Antenna and its Applications to Antenna Design

  • Lee, Young-Soon
    • Journal of Navigation and Port Research
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    • v.35 no.7
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    • pp.563-568
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    • 2011
  • The various properties such as the electric current distribution, resonant frequency and radiation patterns of open-ended meander slot antenna placed on a small ground plane, are investigated to give the help in performing antenna design. Based upon these characteristics, the designed antenna which is only 22mm($0.06{\lambda}_g$) in height and 31mm($0.09{\lambda}_g$) in width can operate at the 433 MHz with the measured radiation efficiency of 8% and end-fire radiation pattern. These properties make the antenna suitable for the handheld device such as the wireless remote controller.

Radiation Stress Properties of Insulation Cable (원전용 절연케이블의 방사선 열화)

  • Lee, Woo-Sun;Jung, Chan-Moon;Kim, Sang-Young;Seo, Yong-Jin;Lim, Jang-Sub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.220-223
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    • 2002
  • Experimental study for radiation stress properties of EPDM cable for nuclear power plant was investigated. Samples of EPDM are fabricated as hot press, then radiation rays irradiated 0~100Mrad and measured radiation properties in the voltage range of 0~10KV. Voltage-current and capacitance characteristics of linear and log curves and the relationship of current due to irradiation of radiaition rays are discussed.

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Effect of Deuterated Solvents on the Excited State Photophysical Properties of Curcumin

  • Barik, A.;Goel, N.K.;Priyadarsini, K.I.;Mohan, Hari
    • Journal of Photoscience
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    • v.11 no.3
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    • pp.95-99
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    • 2004
  • Optical absorption and emission studies have been carried out to understand the effect of deuterium on the solvent dependent photophysical properties of curcumin in deuterated solvents such as $CDCl_3,\;(CD_3)_2SO,\;(CD_3)_2CO,\;CD_3OD\;and\;CD_3CN$. Optical absorption spectral studies showed that there is no significant shift in absorption maxima compared to the non-deuterated solvent. The fluorescence maxima shows significant shift with polarity of solvent but not much affected by the deuteration. The fluorescence quantum yield of curcumin increased marginally in almost all the deuterated solvents, indicating reduction in the non-radiative pathways. The fluorescence decay was biexponential in all the solvents and the average fluorescence lifetime was not much affected with deuteration, but showed decrease with increasing solvent polarity. Based on these studies, it is concluded that intermolecular hydrogen transfer is only partially responsible for the excited state deactivation of curcumin.

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