• Nuclear Engineering and Technology
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• v.55 no.8
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• pp.2919-2926
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• 2023

In this paper, rare earth element (REE)/polyester composites were designed with lanthanum oxide, gadolinium oxide, and lutetium oxide as ray shielding agents, and polyethylene terephthalate (PET) as the base. Monte Carlo simulation was carried out using FLUKA software. We found that the radiation protection performance of the composite is affected by the type and amount of REE; a higher amount of REE equated to a better radiation protection performance of the composite. When the thickness of the composite and total thickness of the REE is constant, the number of superimposed layers inside the composite does not affect its shielding performance. Compared with a single-type REE/PET composite, a mixed-type REE/PET composite has a wider range of γ-ray absorption and better radiation protection performance. When the mass ratio of PET to REE is 2:8 and different types of REE are mixed with equal mass, several 0.2 cm-thick mixed-type REE/PET composites can shield >70% of 60 and 80 KeV γ-rays.

• 한국지구과학회:학술대회논문집
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• 2010.04a
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• pp.58-58
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• 2010

The sediment geochemistry, including REE of surface and core samples in the western part off Jeju Island have been carried out in order to understand the provenance and hydrolic sorting. The sediment in the study area were primarily composed of coarse silt with a mean grain size of $2.8{\sim}82.8{\mu}m$. The ratios of TOC over total nitrogen (TN) showed that the study area sediments contained more organic matters of marine origin than those of terrigenous origin. The total A1203, Fe203, K20, MgO, and MnO contents and REE concentration of the fine sediments are higher than those of the coarse sediments. The higher Zr/Th and Zr/Yb ratios in coarse sediments relative to fine-grained detritus indicates sedimentary sorting. Grain size influence the REE concentrations of the study area sediment significantly. The < $63{\mu}m$ fraction of the sediment has higher REE concentration and different REE patterns when compared with those in bulk samples, due to the presence of REE-enrich heavy minerals. The REE distribution patterns of the western part of Jeju Island sediments are relatively enriched in most LREEs than the Yellow River sediment and depleted in the Changjiang River, but the LaN/YbN ratios are similar to the Changjiang sediment. The Eu/Eu* ratios ranged from 0.594~0.665(0.631) is much similar to the Yellow River sediment, possibly mixture of the sediments from these two rivers.

• Membrane and Water Treatment
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• v.15 no.4
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• pp.193-202
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• 2024

It has been reported that rare earth elements (REEs) are considerably present in coal ash. In this study, an ecofriendly sequential extraction method was developed for the effective REE recovery from coal ash and leaching wastewaters. Citrate, a weak and environmentally benign solvent that replaces acetate employed in the existing sequential extraction methods (e.g., European community bureau of reference (BCR) and Tessier methods), was found to be highly effective in leaching REEs from coal ash. Microwave-assisted thermal digestion improved the REE extraction efficiency even further, with an overall leaching rate of 70%, which is 2.54 and 3.76 times higher than the values achieved by the conventional BCR and Tessier methods, respectively. It was also confirmed that the majority of REEs was strongly bound to CaO, Al₂O₃, Fe₂O₃, and P₂O₅, not to SiO₂. The sequential extraction method developed in this study is expected to be used as an effective and simple recovery procedure for REEs from coal ash and remaining leaching wastewaters.

• The Journal of the Petrological Society of Korea
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• v.17 no.3
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• pp.133-143
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• 2008

On the basis of chemical composition of granite, gneiss and their weathering products, in this paper, rare earth elements (REEs) was estimated as tracer for clarifying a geochemical variance of earth surface material during weathering process. The chemical composition of clay, clay ware and pottery also were measured for testifying usefulness of REE geochemistry in clarifying the source material of pottery. It was observed that there was no systematic variation of chemical composition among source rock, weathered rock and soil during weathering process. The chemical composition of clay, clay ware and pottery also did not show systematic variation by baking pottery. However, PAAS (Post Archean Australian Shale)-normalized REE patterns of rock-weathered rock-soil and clay-clay ware-pottery are similar regardless of weathering process or ceramic art. Our results confirm that REE geochemistry is powerful tool for clarifying the source materials of surface sediment or archaeological ceramic products.

• Journal of Powder Materials
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• v.25 no.2
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• pp.165-169
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• 2018

Rare earth elements (REEs) are considered to be vital to modern industry due to their important roles in applications such as permanent magnets, automobile production, displays, and many more. The imbalance between demand and supply of REEs can be solved by recycling processes. Regarding the needs of industry and society, the International Organization for Standardization, Technical Committee 298 (ISO/TC298) Rare Earths has been recently launched for developing international standards on rare earth elements. In accordance with the suggestion of its constituents, it is tentatively working to develop the appropriate standards under five working groups (WG) on terms and definitions (WG1), element recycling (WG2), environmental stewardship (WG3), packaging, labelling, marking, transport, and storage (WG4), and testing analysis (WG5). The scope and structure of ISO/TC298 on the topic of rare earths is discussed in this document.

• Journal of the Korean earth science society
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• v.42 no.4
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• pp.383-389
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• 2021

Several studies investigating the behavior and environmental distribution of rare earth elements (REEs) have been reviewed to determine the geochemical processes that may affect their concentrations and fractionation patterns in groundwater and whether these elements can be used as tracers for groundwater-rock interactions and groundwater flow paths in small catchments. Inductively coupled plasma-mass spectrometry (ICP-MS), equipped with an ultrasonic nebulizer and active-film multiplier detector, is routinely used as an analytical technique to measure REEs in groundwater, facilitating the analysis of dissolved REE geochemistry. This review focuses on the distribution of REEs in groundwater and their application as tracers for groundwater geochemistry. Our review of existing literature suggests that REEs in ice cores can be used as effective tracers for atmospheric particles, aiding the identification of source regions.

• Resources Recycling
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• v.27 no.6
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• pp.68-75
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• 2018

The rare earth elements (REE) contents in coal ashes generated from domestic circulating fluidized bed combustion (CFBC) were identified for evaluating the exploitation possibilities for recovering rare earth elements. Total REE contents for all of the samples in this study ranged from 82.2 ~ 311.7 ppm, much lower than the 403.5 ppm given on the average value of world coal ash. As a result of analysis using REE concentration and Outlook coefficient, six types of coal ashes falls in the unpromising area (I). These results suggest that it is difficult to recover rare earth element from coal ashes at this stage. It has been confirmed that to recover rare earth elements in coal ashes, research on the pretreatment and concentration process for critical REE is requirement.

• Proceedings of the KSEEG Conference
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• 2003.04a
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• pp.194-195
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• 2003

High-pressure amphibolite-facies rocks with serpentinized ultramafic rocks occur in the Gyeonggi Massif. Ultramafic rocks occur as lenses within Precambrian granite gneiss, which showing dominantly tectonic lines of NNE directions as well as east extensional area of the chinese collision belt between south and north China block(\ulcorner). This study regionally makes a comparative study of ultramafic rocks in the western part of the Gyeonggi Massif in Korea. (omitted)

• The Journal of the Petrological Society of Korea
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• v.16 no.1 s.47
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• pp.27-37
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• 2007

Here we discuss a geochemical characterisitc of rare earth element (REE) pattern of a Precambrain leucogranitic gneiss at Imweon, Gangwon Province, Korea. The outcrop includes biotite gneiss xenolith. The leucocratic granite gneiss contacting with biotite gneiss is pegmatitic. However, there is no evidence of contact metamorphism between biotite gneiss and leucocratic-pegmatitic granite gneiss. The leucocratic granite gneiss shows a specific phenomenon of M-type (convex curved) tetrad effect in chondrite-normalized REE patterns with large negative Eu anomaly. The degree of REE tetrad effect in the leucocratic-pegmatitic granitec gneiss is weak and shows partly W-type (concave curved) tetrad effect. The Eu anomaly of leucocratic granite gneiss has close relationship with the degree of tetrad effect as well as Ca/Sr ratio. Our results suggest that the REE tetrad effect from the leucocratic granite gneiss should be formed during differentiation process of granitic magma. We also confirmed that the weathering might affect Eu or Ce anomaly rather than the formation of REE tetrad effect in granitic rock.

• Journal of Environmental Science International
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• v.18 no.6
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• pp.621-632
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• 2009

Rare earth contents(REE) were analysed for the plants, M. sinensis. A. vulgaris and R. crataegitolius, from two different soils serpentine area consisting of serpentinite(SP) and non-serpentine area, containing amphibole schist(AS) of Gapyeong area, and were compared with soils and host rocks. The AS were high with the differences of several times in the top soils, and with the differences of several to ten times in the host rocks relative to the SP. In the same area, the SP were high in the soil, but the rocks for the AS. In the plants, the A. vulgaris were high, but low in the R. crataegitolius. Root parts were higher than the upper parts. Differences between the upper and root parts were big in the SP rather than the AS, and were big in the R. crataegitolius, but small in the M. sinensis. Among the parts of the plants, high elements were shown in the R. crataegitolius of the SP, and the A. vulgaris and M. sinensis of the AS. In the correlation coefficients, most of the REE showed positive relationships among the element pairs, especially high positive correlation coefficients in the upper parts of the SP.Differences of the soils and plants(average) were smalle in the M. sinensis and big in the R. crataegitolius. In the upper parts. contents of the A. vulgaris were close to the soils while the R. crataegitolius showed large discrepancies with the soils. In the root parts, contents of the A. vulgaris showed discrepancies with the soils regardless of soil types, but close in the R. crataegitolius of the SP and M. sinensis of the AS.