• Title/Summary/Keyword: RED-II

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Studies on Silk Fibroin Membranes(II) -Adsorption of Acid Dyes in Silk Fibroin Memberane- (Silk Fibroin 막에 관한 연구 (II) -Silk Fibroin 막에 대한 산성염료의 흡착-)

  • 최해욱;박수민;김경환
    • Textile Coloration and Finishing
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    • v.6 no.3
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    • pp.60-66
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    • 1994
  • With the view of studying on the dual adsorption mechanism of acid dyes in connection with the structural difference of silk fibroin, silk fiber and silk fibroin memberane were used for equilibrium dyeing at $60^{\circ}C$, $70^{\circ}C$, $80^{\circ}C$ and pH 3.2, pH 5.0. The dyes used were C.I.Acid Orange 7 and C.I.Acid Red 88 introduced aromatic hydrocabon into Acid Orange 7. From the adsorption isotherm experiment, the total uptake of dyes can be described by Langmuir sorption and Nernst partition. Nernst partition. Nernst partition coefficient $K_1$ decrease of crystalline regions and orientation. The saturation value S of Acid Red 88 were large than total amino group contents and it was attributed it hydrophobic bond. On the other hand, the standard afficity and enthalpy were increased with the in crease of hydrophobic part of dyes. Both $k_1$ and $K_2$ were decreased with the increase of pH, but $k_2$ were more effected than $K_1$.

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One Bath Dying of Silk/Synthetic Fiber Blends (2) (Color perseption of adsorption and desorption behavior of disperse dyes on silk and transfer to synthetic fibers) (견/합성섬유 혼방품의 일욕 염색 (II)(견에대한 분산염료의 염착, 탈착 및 합성섬유에의 이염의 색지각))

  • 김공주;곽인준;박미라;전재홍
    • Textile Coloration and Finishing
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    • v.5 no.2
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    • pp.99-108
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    • 1993
  • In one dyeing system of silk/synthetic blend fabrics (polyester, nylon, acetate) with acid dyes/disperse dyes, dyeability and desorptibility of disperse dyes on silk fabric and transfer from dyed silk fabrics to synthetic fabrics by color difference were examined. When silk dyed with C.I. Disperse Red 19 and C.I. Disperse Red 60 at 10$0^{\circ}C$ for 60 minutes, color difference of dyed silk were $\Delta$E=56.72, $\Delta$E=47.65 for blank silk, respectively. The desorption rate of the dyed silks were measured in boiling bath with and without dye-free synthetic fibers. The desorption rate of dyed silk was effected by affinity of synthetic fabrics contained. When silk dyed with Red 19 and Red 60 was reduced at 10$0^{\circ}C$ for 60 minutes, the decolouration rates of dyed silk were 75% and 40%, respecdtively.

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Complexation of Polyelectroyte-Metal(II) Ion. III. The Complex Formation of Iron(II), Cobalt(II), Nickel(II) and Copper(II) with Branched Poly(ethylene imine) (BPEI) in Aqueous Solution (Polyelectrolyte-Metal(II) 이온의 착물화 (제 3 보). Iron(II), Cobalt(II) Nickel(II) 및 Copper(II)와 Branched Poly(ethylene imine) (BPEI)간의 착물생성)

  • Dong Soo Kim;Tae Sub Cho
    • Journal of the Korean Chemical Society
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    • v.30 no.5
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    • pp.456-464
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    • 1986
  • The complex formation of branched poly(ethylene imine) (BPEI) with bivalent transition metal ions, such as Fe(II), Co(II), Ni(II) and Cu(II), have been investigated in terms of visible absorption and pH titration methods in an aqueous solution in 0.1M KCl at 30${\circ}$. The stability constants for M(II)-BPEI complexes was calculated with the modified Bjerrum method. The formation curves of M(II)-BPEI complexes showed that Fe(II), Co(II), Ni(II) and Cu(II) ions formed coordination compounds with four, two, two, and two ethylene imine group, respectively. In the case of Cu(II)-BPEI complex at pH 3.4 ∼ 3.8, ${\lambda}_{max}$ was shifted to the red region with a decrease in the acidity. The overall stability constants (log $K_2$) increased as the following order, Co(II) < Cu(II) < Ni(II) < Fe(II).

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Antioxidant and Oxidative DNA Damage Protection Potential of Methanol Extract of Red Tea Stem

  • Yadav, Anil Kumar;Kang, Sun Chul
    • Current Research on Agriculture and Life Sciences
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    • v.31 no.2
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    • pp.101-107
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    • 2013
  • This study was undertaken to determine free radical scavenging capacity and oxidative DNA damage protecting activity of methanol extract of red tea stem. The extract was subjected to assess their antioxidant potential using various in vitro systems such as $DPPH^{\bullet}$, $ABTS^{{\bullet}+}$, super oxide and nitric oxide free radicals and it exhibited $IC_{50}$ values of $68.88{\pm}1.1$, $12.08{\pm}0.65$, $404.38{\pm}1.6$, $93.6{\pm}2.7{\mu}g/mL$ respectively. Red tea extract also showed ferric reducing ability (FRAP) with 2606.85 mmol Fe (II)/g of extract. Furthermore, Methanol extract of red tea stem showed significant DNA damage protecting activity in concentration dependent manner against $H_2O_2+UV$ induced photolysis on pUC19 plasmid DNA. Results of this study showed that the methanol extract of Red Tea stem has strong antioxidant potential along oxidative DNA damage protecting capacity that would be the significant sources of natural antioxidants, which might be helpful in preventing the progress of various oxidative stress generated diseases. Further study is necessary for isolation and characterization of the active antioxidants, which may serve as a potential source of natural antioxidant.

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Effects of Korean Red Ginseng Water Extract on Bisphenol A-induced Developmental Toxicity in Rats (랫드에서 비스페놀 A의 발생독성에 대한 고려홍삼 물추출물의 효과)

  • 김종춘;임광현;서정은;위재준;남기열;정문구
    • Toxicological Research
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    • v.17 no.3
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    • pp.225-234
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    • 2001
  • The present study was conducted to investigate the effects of Korean red ginseng water extract (KRGWE) on developmental toxicity caused by the environmental estrogen bisphenol A (BPA) in Sprague-Dawley rats. fifty males successfully mated were randomly assigned to five experimental groups, 1.e., group I (vehicle control), group II (BPA 1000mg/kg), group III (KRGWE 400mg/kg), group IV (BPA 1000mg/kg & KRGWE 200mg/kg), and group V (BPA 1000mg/kg & KRGWE 400mg/kg). The test articles were administered by gavage to mated females from gestational days (GD) 1 through 20 (sperm vaginal lavage=day O). All females were subjected to caesarean section on GD 21 and their fetuses were examined for external, visceral, and skeletal abnormalities. In the group II, significant maternal toxic effects including suppressed body weight, decreased body weight gain during pregnancy, and reduced food consumption were observed in pregnant rats. The minimal developmental toxicity including fetal ossification delay was also found in fetuses. In addition, a tendency for increased pregnancy failure, increased pre-and postimplantation loss, and decreased fetal body weight was observed. However, no fetal morpho-logical abnormalities were seen in surviving fetuses at a dose level of 1000mg BPA/kg. On the other hand, the maternal toxicity and developmental toxicity found in the groups IV and V were comparable to those of the group II. There were no adverse signs of either maternal toxicity or developmental toxicity in the group III. These results showed that administration of BPA at a dose level of 1000mg/kg to pregnant rats resulted in significant maternal toxicity and minimal developmental toxicity, and that no protective effects on BPA-induced maternal toxicity and developmental toxicity were found by concomitant gavage dosing of KRGWE.

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MIRIS Paα Galactic Plane Survey: The results in l = 276°-296°

  • Kim, Il-Joong;Pyo, Jeonghyun;Jeong, Woong-Seob
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.58.1-58.1
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    • 2020
  • The Multipupose InfraRed Imaging System (MIRIS) Paα Galactic Plane Survey (MIPAPS) covers the whole Galactic plane with the latitude range of -3° < b < +3°. Next to the first result in l = 96°-116° (Cepheus), we present the results in l = 276°-296° (Carina). This region with the direction toward the inner Galaxy, has much higher extinction but much more Paα-emitting sources than Cepheus. We list up the detected Paα sources, and compare them with the WISE H II region catalog (there are 308 H II regions and candidates in this region) and VPHAS+ Hα image. By detecting the Paα and Hα recombination lines, 71 H II region candidates are newly confirmed as definite H II regions, out of which 53 H II regions are detected at Paα. For the Paα-detected sources, we measure the Paα and Hα fluxes and estimate the E(B-V) color excesses for the extended sources.

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Green flow injection spectrophotometric system for lead ion (II) evaluation in vegetables samples using new azo reagent

  • Fatimah Lateef Al-Zubaidi;Khdeeja Jabbar Ali
    • Analytical Science and Technology
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    • v.36 no.1
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    • pp.1-11
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    • 2023
  • A new, sensitive, and reliable flow injection methodology was investigated for the determination of lead ion (II) in vegetables' samples using a laboratory-prepared reagent 2-[(6-methoxy-2-benzothiazoly)azo]-4-methoxy phenol (6-MBTAMP). Infrared spectroscopy, UV-visible spectrophotometry, Energy dispersive X-ray spectroscopy (EDX), Elemental Analysis (CHN), nuclear magnetic resonance spectroscopy 1HNMR, and 13CNMR techniques were used to characterize the reagent and lead (II) complex. The method is based on lead ion (II) reacting with the reagent (6-MBTAMP) in a neutral solution to produce a green-red complex with a maximum absorbance at 670 nm. The optimum conditions, such as flow rate, lead ion (II) volume, reagent volume, medium pH, reagent concentration, and reaction coil length were thoroughly examined. The limits of detection (LOD) and quantification (LOQ) were determined to be 0.621 mg·L-1 and 2.069 mg·L-1 , respectively, while Sandell's sensitivity was determined to be 0.345 ㎍·cm-2.

Comparison of nitrogen transformation dynamics in non-irradiated and irradiated alfalfa and red clover during ensiling

  • Dong, Zhihao;Li, Junfeng;Chen, Lei;Yuan, Xianjun;Shao, Tao
    • Asian-Australasian Journal of Animal Sciences
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    • v.32 no.10
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    • pp.1521-1527
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    • 2019
  • Objective: To study the contribution of plant enzyme and microbial activities on protein degradation in silage, this study evaluated the nitrogen transformation dynamics during ensiling of non- and irradiated alfalfa (Medicago sativa L.) and red clover (Trifolium pratense L.). Methods: Alfalfa and red clover silages were prepared and equally divided into two groups. One group was exposed to ${\gamma}$-irradiation at a recommended dosage (25 Gky). Therefore, four types of silages were produced: i) non-irradiated alfalfa silage; ii) irradiated alfalfa silage; iii) non-irradiated red clover silage; and iv) irradiated red clover silage. These silages were opened for fermentation quality and nitrogen components analyses after 1, 4, 8, and 30 days, respectively. Results: The ${\gamma}$-irradiation successfully suppressed microbial activity, indicated by high pH and no apparent increases in fermentation end products in irradiated silages. All nitrogen components, except for peptide-N, increased throughout the ensiling process. Proteolysis less occurred in red clover silages compared with alfalfa silages, indicated by smaller (p<0.05) increment in peptide-N and free amino acid N (FAA-N) during early stage of ensiling. The ${\gamma}$-irradiation treatment increased (p<0.05) peptide-N and FAA-N in alfalfa silage at day 1, whereas not in red clover silage; these two nitrogen components were higher (p<0.05) between day 4 and day 30 in non-irradiated silages than the irradiated silages. The ammonia nitrogen and non-protein nitrogen were highest in non-irradiated alfalfa silage and lowest in irradiated red clover silage after ensiling. Conclusion: The result of this study indicate that red clover and alfalfa are two forages varying in their nitrogen transformation patterns, especially during early stages of ensiling. Microbial activity plays a certain role in the proteolysis and seems little affected by the presence of polyphenol oxidase in red clover compared with alfalfaa.