• Transactions of the Korean Society of Mechanical Engineers
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• v.15 no.6
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• pp.2189-2205
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• 1991

Thermodynamic properties of binary nonazeotropic refrigerant mixtures are estimated by using a modified Carnhan-Starling equation of state. In this study, pure component refrigerants such as R14, R23, R13, R13 B1, R22, R12, R134a, R152a, R142b, RC318, R114, R11, R123 and R113 are chosen and the thermodynamic properties of enthalpy and entropy are calculated in terms of relevant variables. The modified Carnahan-Starling equation of state is compared with the carnahan-Staring-De Santis equation of sate. Results show that the relative errors become slightly smaller with the equation of state proposed in this study. Correlations are obtained for the mixtures of which the vapor liquid equilibruim data are available to us in the literature. Those mixtures are R14/R23, R23/R12, R13/R12, R13/R11, R13B1/R22, R13B1/RC318, R12/RC138, R12/R114 and R12/R11. The binary interaction coefficients are found under the condition of minimizing the pressure deviations at the vapor liquid equiblibrium state and the estimation of the vapor liquid equilibrium for the refrigerant mixtures is done. Pressure-enthalpy and temperature-entropy diagrams are plotted for the refrigerant mixtures of specific composition.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.4 no.1
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• pp.33-47
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• 1992

Experimental investigation on the performance of a heat pump system using refrigerant mixtures is done. The condenser and the evaporator are double pipe heat exchangers of counter flow type and the compressor is driven by a variable speed motor. The refrigerant mixture used in the experiment is R22/R142b. Experiments are performed by changing the compressor speed, composition on ratio of mixture, and the average temperatures of condenser and evaporator. The compressor work, heating capacity and the coefficient of performance are calculated. Results show that the heating capacity can be changed by varying the mass flow rate of refrigerant mixtures to meet the heating load. It is shown that the capacity control by changing the composition ratio is more effective than by changing the compressor speed. Under the condition where the external conditions are fixed and the heating loads are equal, the coefficient of performance has its maximum value near 50 : 50 mass fraction of the refrigerant mixture in this study.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.4 no.2
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• pp.123-136
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• 1992

A preliminary thermodynamic design model of two-evaporator refrigerator/freezer system is constructed. This system is based on Lorentz-Meutzner cycle using refrigerant mixtures. This model screens alternative refrigerant (R32, R125, R143a, R22, R134a, R152a, R124, R142b, R123) mixtures to select the best performance-giving refrigerant mixtures and its composition for the system. Also, it estimates the effects of cooling temperatures of intercoolers, evaporator's area ratio, cooling load ratio on the performance of the system. The COP of the system ranges from 1.4 to 1.6, which is superior to that of the single evaporator system charged with R12 by 13% to 29%. Among 15 mixtures, R22/R123, R143a/R123, R32/R142b, and R32/R124 (in the order of high COP) are most recommendable. For the case of R22/R123, R22 mass fraction more than 0.5(Load Ratio=1.0) or 0.7(Load Ratio=0.33) is recomended in order to replace R12 without reduction in volumetric capacity when keeping the compressor as the same one. COP has the highest value with X(R22)=0.7 and 0.8, respectively. For the case of R143a/R123, in the similar manner, mass fraction of R143a is more than 0.5 or 0.6 while best performance occurs at X(R143a)=0.8. Higher temperature intercooler is more important for the performance of the system than lower temperature intercooler. The area ratio of evaporators is roughly proportional to load ratio of the evaporators.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.11 no.1
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• pp.48-60
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• 1999

An experimental study on the performance enhancement of a screw-compressor-type chiller with 100kW of nominal cooling capacity has been carried out. Performance test facility was developed to investigate the effects of a partial modification from the existing chiller on the performance. By replacing the existing shell-and -tube heat exchangers with plate heat exchangers, the cooling capacity is increased by 15~18% and the COP is also increased by 19~21% depending on the operation temperature range. Charging mixed refrigerant R22/R142b(80 : 20) instead of R22 into the chiller with plate heat exchangers improves the cooling capacity by 4% and the COP very largely by 30%. Each contribution of the plate evaporator, plate condenser, and mixed refrigerant to the performance enhancement is examined by analyzing the refrigeration cycle and the heat transfer processes. It is also shown that the chiller performance can be improved by adapting 2-stage-compression cycle using an economizer.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.4 no.4
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• pp.360-369
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• 1992

A heat pump system is constructed to evaluate its performance and heat transfer characteristics with mixtures of R22/R142b as working fluids. The heat transfer in the evaporator and the overall performance are measured and analyzed in terms of the compositions and relevant variables. Possibility of capacity modulation by changing composition is observed without degradation of heat transfer coefficients and coefficient of performance. The cooling capacity is varied continuously within 200 percent based on minimum capacity at constant compressor speed. For similar cooling capacity, COP is improved by mixing two refrigerants and shows maximum value at 60％ mass fraction of R22. Average heat transfer coefficients of mixtures decrease in comparison with pure refrigerants at similar cooling capacity and mass flow rate. However, the overall heat transfer coefficients decrease moderately. A cycle simulation is performed in order to manifest the advantages of using refrigerant mixtures, considering experimentally observed heat transfer characteristics.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.2 no.3
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• pp.218-225
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• 1990

Studies on the performance of a heat pump using non-azeotropic refrigerant mixtures are done. In order to estimate the thermodynamic properties for the selected non-azeotropic refrigerant mixtures including R22/R152a, R22/R142b, R22/R114 and R13B1/R152a, Peng-Robinson equation of state is adopted. The pressure-enthalpy diagram and the temperature-entropy diagram are plotted for each refrigerant mixture. Considerations on the capacity modulation for the heat pump system using refrigerant mixtures are taken into. Results show that when the heating load varies, the possibility for the capacity modulation is found in the heat pump system using a compressor with constant volume flow rate. Under a constant heating capacity condition in the heat pump system, the coefficient of performance increases when the refrigerant mixtures are used. The volume flow rate decreases as the mass fraction of lower boiler increases in this case.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.2 no.2
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• pp.142-154
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• 1990

A theoretical cycle analysis has been performed for a basic heat pump, charged with non-azeotropic refrigerant mixtures, R22/R114 and R13B1/R152a. At first, a procedure is introduced to calculate thermodynamic properties simply and correctly, and the advantages of using refrigerant mixtures are discussed through the cycle analysis. It is shown that by using refrigerant mixtures in the heat pump, several improvements can be made. In comparison with conventional pure refrigerants, the application of refrigerant mixtures results in high reliabilities caused by the extension of the application limit, energetic improvements, and a continuous capacity control. From generalizing various results, the optimum compositions in refrigerant mixtures are also determined. The 30%/70% and 40%/60% compositions are selected for R22/R114 and R13B1/R152a, respectively.