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Stereospecific Coordination of 2,2$^\prime$-Diaminobiphenyl in the Square Planar Platinum(Ⅱ) Comdlexes

  • Jun, Moo-Jin;Choi, Sung-Rack
    • Bulletin of the Korean Chemical Society
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    • v.5 no.6
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    • pp.237-240
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    • 1984
  • 2,2'-Diaminobiphenyl platinum (II) complexes of optically active trans-1,2-diaminocyclohexane and 1,2-diaminopropane, [Pt(S,S-chxn)(dabp)]Cl2, [Pt(R,R-chxn)(dabp)]$C_{12}$, [Pt(S-pn)(dabp)]$C_{l2}$, and [Pt(R-pn)(dabp)]Cl2, where S,S-chxn and R,R-chxn are, respectively, S and R isomers of trans-1,2-diaminocyclohexane, and S-pn and R-pn are, respectively, S and R isomers of 1,2-diaminopropane, and dabp the 2,2'-diaminobipheny, have been prepared. The dabp ligand has been found to take the $=delta$ conformation in the S,S-chxn and S-pn platinum (II) complexes, while it takes the $\lambda$ conformation in the R,R-chxn and R-pn platinum (II) complexes.

Launch Point Estimation for a Ballistic Missile using the Phase Division Least Square Method (단계 분리형 최소 자승법을 이용한 탄도 미사일의 발사지점 예측 연구)

  • Kim, Jun-Ki;Lee, Dong-Kwan;Cho, Kil-Seok;Song, Taek-Lyul
    • Journal of Institute of Control, Robotics and Systems
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    • v.20 no.4
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    • pp.414-421
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    • 2014
  • This paper presents a method of ballistic missile launch point estimation using phase division least squares. The proposed algorithm employs smoothing to enhance estimation accuracy and generates functions of time for total velocity, flight path angle and heading angle, allowing extrapolation to estimate the launch point. Performance of the proposed algorithm is tested in conjunction with the extended Kalman filter and the Kalman filter.

Mathematical representation to assess the wind resource by three parameter Weibull distribution

  • Sukkiramathi, K.;Rajkumar, R.;Seshaiah, C.V.
    • Wind and Structures
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    • v.31 no.5
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    • pp.419-430
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    • 2020
  • Weibull distribution is a conspicuous distribution known for its accuracy and its usage for wind energy analysis. The two and three parameter Weibull distributions are adopted in this study to fit wind speed data. The daily mean wind speed data of Ennore, Tamil Nadu, India has been used to validate the procedure. The parameters are estimated using maximum likelihood method, least square method and moment method. Four statistical tests namely Root mean square error, R2 test, Kolmogorov-Smirnov test and Anderson-Darling test are employed to inspect the fitness of Weibull probability density functions. The value of shape factor, scale factor, wind speed and wind power are determined at a height of 100m using extrapolation of numerical equations. Also, the value of capacity factor is calculated mathematically. This study provides a way to evaluate feasible locations for wind energy assessment, which can be used at any windy site throughout the world.

Evaluation of wind power potential for selecting suitable wind turbine

  • Sukkiramathi, K.;Rajkumar, R.;Seshaiah, C.V.
    • Wind and Structures
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    • v.31 no.4
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    • pp.311-319
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    • 2020
  • India is a developing nation and heavily spends on the development of wind power plants to meet the national energy demand. The objective of this paper is to investigate wind power potential of Ennore site using wind data collected over a period of two years by three parameter Weibull distribution. The Weibull parameters are estimated using maximum likelihood, least square method and moment method and the accuracy is determined using R2 and root mean square error values. The site specific capacity factor is calculated by the mathematical model developed by three parameter Weibull distribution at different hub heights above the ground level. At last, the wind energy economic analysis is carried out using capacity factor at 30 m, 40 m and 50 m height for different wind turbine models. The analysis showed that the site has potential to install utility wind turbines to generate energy at the lowest cost per kilowatt-hour at height of 50 m. This research provides information of wind characteristics of potential sites and helps in selecting suitable wind turbine.

Surface roughness model of end-milling surface (엔드밀 가공면의 표면거칠기 모델)

  • Chin, Do-Hun;Kim, Jong-Do;Yoon, Moon-Chul
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.12 no.2
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    • pp.68-74
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    • 2013
  • In this paper, an average surface roughness, $R_a$, was measured by optical measurement and its mathematical model according to spindle speed and feedrate was obtained by least square method. Also, its result is compared and investigated with real measured average surface roughness. The optical measurement of surface roughness is performed by CLSM(confocal laser scanning microscope) and the captured HEI(height encoded image) data is used as an original data for the generation of average surface roughness and its mathematical plane or contour surface of surface roughness. Using this polynomial model with two independent variables, the behavior of an average surface roughness is investigated and analyzed with an experimental modeling of least square algorithm. And it can be used for the prediction of $R_a$ in different condition of machining.

A study on velocity profiles and inlet length of developing transitional pulsating flows in the entrance region of a square duct (정4각 덕트 입구영역에서 천이파동유동의 속도분포와 입구길이에 관한 연구)

  • 유영태;모양유;홍성삼
    • Journal of the korean Society of Automotive Engineers
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    • v.15 no.2
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    • pp.92-104
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    • 1993
  • In the present study, the velocity profiles and entrance length of developing transitional pulsating flows are investigated both analytically and experimentally in the entrance region of a square duct. The systems of conservation equations for transitional pulsating flows in a square duct are solved analytically by linearizing the non-linear convective terms. Analytical solutions are obtained in the form of infinite series for velocity pofiles. The experimental study for the air flow in a square duct(40mm*40mm*4000mm) is carried out to measure velocity profiles and other parameters by using a hot-wire anemometer with a data acquisition and processing system. The distribution of velocity profiles( $u_{ps}$ / $u_{m,ta}$) in the decelerating period is higher than in the accelerating period. The distribution of the axial component of the axial component of velocity in the transitional flow is nearly uniform in the central region of the duct, and decrease rapidly near the wall. The entrance length correlation of the transitional pulsating flows in a square duct is obtained to be $L_{e}$/ $D_{h}$=0.83 $A_{1}$R $e_{ta}$ /(.omega. sup+1)$^{2}$TEX>

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A NOTE ON CONVERTIBLE {0,1} MATRICES

  • Kim, Si-Ju;Park, Taeg-Young
    • Communications of the Korean Mathematical Society
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    • v.12 no.4
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    • pp.841-849
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    • 1997
  • A square matrix A with $per A \neq 0$ is called convertible if there exists a {1, -1} matrix H such that $per A = det(H \circ A)$ where $H \circ A$ denote the Hadamard product of H and A. In this paper, ranks of convertible {0, 1} matrices are investigated and the existence of maximal convertible matrices with its rank r for each integer r with $\left\lceil \frac{n}{2} \right\rceil \leq r \leq n$ is proved.

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Estimation of Gauge R&R by Variance Components of Measurement ANOVA (측정 ANOVA의 분산성분에 의한 게이지 R&R 추정)

  • Choi, Sung-woon
    • Journal of the Korea Safety Management & Science
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    • v.12 no.1
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    • pp.199-205
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    • 2010
  • The research proposes the three-factor random measurement models for estimating the precision about operator, part, tool, and various measurement environments. The combined model with crossed and nested factors is developed to analyze the approximate F test by degrees of freedom given by Satterthwaite and point estimation of precisions from expected mean square. The model developed in this paper can be extended to the three useful models according to the type of nested designs. The study also provides the three-step procedures to evaluate the measurement precisions using three indexes such as SNR(Signal-To-Noise Ratio), R&R TR(Reproducibility&Repeatability-To-Total Precision Ratio), and PTR(Precision-To-Tolerance Ratio), The procedures include the identification of resolution, the improvement of R&R reduction, and the evaluation of precision effect.

The Impacts of Foodservice Employees Communication Type on Self-Efficiency and Organizational Commitment (외식업체 종사원의 커뮤니케이션 유형이 자기효능감 및 조직몰입에 미치는 영향)

  • Lim, Hyun-Cheol
    • Journal of the East Asian Society of Dietary Life
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    • v.23 no.6
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    • pp.862-870
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    • 2013
  • This study examines the effect of communication type of food service employees on the self-efficiency and organizational commitment. To accomplish the purpose of the study, a survey was conducted to employees of food service companies located in Seoul, from August 5, 2013 to August 25, 2013 as a method of empirical study. The results of this study was analyzed using the SPSS WIN 12.0 and statistical reliability analysis, factor analysis, frequency analysis, correlation analysis and multiple regression analysis were conducted for hypothesis verification. The analysis results of this study are as follows. First, the R-square of regression result for 'communication type will have a positive effect on self-efficiency' was .220. Also, it was found that factors of consideration (Beta=.286, t=5.622), instruction (Beta=.303, t=5.970) and business (Beta=.214, t=4.217) had positive effects on self-efficiency. Values for factors of consideration and instruction were higher than business. Second, the R-square of regression result for 'communication type will have a positive effect on organizational commitment' was .429. Also, it was found that factors of consideration (Beta=.453, t=10.428), instruction (Beta=.380, t=8.749) and business (Beta=.282, t=6.477) had positive effects on organizational commitment. Values for factors of instruction and business were high but value of consideration factor turned out the highest. Third, the R-square of regression result for 'self-efficiency will have a positive effect on organizational commitment' was .334. Also, it was found that out of the factors of positivity (Beta=.369, t=8.423), confidence (Beta=.415, t=8.833) and negativity (Beta=-.072, t=-1.536), positivity and confidence had positive effects on organization commitment, and only positivity and confidence showed high values in organization commitment. Upon analyzing the effect of factors of self-efficiency (positivity, confidence, negativity) on organizational commitment, it was found that positivity and confidence showed high relevance but the negativity factor did not have any correlation.

Determinants of Capital Structure of Korea Listed Firms (우리나라 상장기업(上場企業)의 자본구조(資本構造) 결정요인(決定要因)에 관한 연구(硏究))

  • Shin, Min-Shik
    • The Korean Journal of Financial Management
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    • v.6 no.2
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    • pp.33-69
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    • 1989
  • The Purpose of this study is to test empirically the determinants of capital structure of the Korea Listed Firms. In order to accomplish the purpose of this study, both literature survey and empirical test have been made. For the empirical test, agency and asymmetric information factors as well as traditional ones have been throughly reviewed. Traditional factors tested in this study include firm-size, collateral value of the assets, business risk, tax, non-debt tax shields, and industry effects. Agency and asymmetric information factors include growth opportunities, the percentage of outstanding equity held by inside stockholders, and the number of inside stockholders. From the results of the cross-sectional regression analysis, the adjusted R-square is 1931%, and the overall F-value indicates significance. For the analysis period, the signs of the variables except business risk are as predicted. Firm-size, collateral value of the assets, and business risk significant at the.01-.05 level. In order to determine the influence of industry factors on the financial leverage, a total of 8 dummy variables are added to the regression model. The adjusted R-square inclosed by 4.2% for the first analysis period(1983-1985) and 6% for the second analysis period(1986-1987). This suggests that industry factors are significant in explaining the variations in financial leverage across firms. In order to pursue the influence of agency and asymmetric information factors on the financial leverage, again the cross-sectional regression analysis is done for the middle size firms gruop(n=40). The adjusted R-square increased by 9.8% for the first analysis period(1983-1985) and 6.1% for the total analysis period(1983-1987), and all the signs was as predicted. But both the variables except the number of inside stockholders was not significant.

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