• Bulletin of the Korean Chemical Society
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• 제28권4호
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• pp.567-573
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• 2007

The crystal structure of ZnI2 molecule synthesized in zeolite A (LTA) has been studied by single-crystal X-ray diffraction techniques. A single crystal of |Zn6|[Si12Al12O48]-LTA, synthesized by the dynamic ion-exchange of |Na12|[Si12Al12O48]-LTA with aqueous 0.05 M Zn(NO3)2 and washed with deionized water, was placed in a stream of flowing 0.05 M KI in CH3OH at 294 K for four days. The resulting crystal structure of the product (|K6Zn3(KI)3(ZnI2)0.5|[Si12Al12O48]-LTA, a = 12.1690(10) A) was determined at 294 K by single-crystal X-ray diffraction in the space group Pm3m. It was refined with all measured reflections to the final error index R1 = 0.078 for 431 reflections which Fo > 4σ (Fo). At four crystallographically distinct positions, 3.5 Zn2+ and nine K+ ions per unit cell are found: three Zn2+ and five K+ ions lie on the 3-fold axes opposite 6-rings in the large cavity, two K+ ions are off the plane of the 8-rings, two K+ ions are recessed deeply off the plane of the 8-rings, and the remaining a half Zn2+ ion lie on the 3-fold axes opposite 6-rings in the sodalite cavity. A half Zn2+ ion and an I- ion per unit cell are found in the sodalite units, indicating the formation of a ZnI2 molecule in 50% of the sodalite cavities. Each ZnI2 (Zn-I = 3.35(5) A) is held in place by the coordination of its one Zn2+ ion to the zeolite framework oxygens and by the coordination of its two I- ions to K+ ions through 6-rings (I-K = 3.33(8) A). Three additional I- ions per unit cell are found opposite a 4-ring in the large cavity and form a K3I2+ and two K2ZnI3+ ionic clusters, respectively.

• 생명과학회지
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• 제20권3호
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• pp.356-364
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• 2010

본 연구는 비교적 청정한 지역인 춘천시에 거주하는 일반인 모유 중 PBDEs의 노출 경로를 확인하기 위해 처음으로 시도된 연구이다. 본 연구지역의 모유 중 ${\sum}PBDEs$의 수준은 북아메리카지역에 비하여 낮은 수준이었으나 일부 아시아, 유럽국가와 유사하였다. 모유 내 PBDEs의 축적은 산모의 특성과 상관관계가 나타나지 않았으나, 상엽용 PBDEs 제품을 포함하여 여러 복합적 인자에 의하여 노출되고 있었으며, 식품 섭취와 같은 식이노출은 한국인에 있어 중요한 노출 경로의 하나로 판단되었다. 따라서 본 연구 결과는 한국인의 PBDEs 노출 경로 파악에 중요한 정보를 제공하여, 장차 PBDEs 및 관련 브롬계 난연제의 노출에 따른 인체 위해성 평가를 수행함에 있어 중요한 참고자료가 될 것이다. 또한, 한국 내의 PBDEs에 대한 인체노출 경로를 명확하게 하기 위한 연구는 계속적으로 이루어져야 할 것이다.

• 한국식품과학회지
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• 제33권6호
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• pp.686-692
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• 2001

전곡립을 이용한 기능성 식품개발을 위하여 현미, 현미찹쌀, 보리, 현미율무를 온도 $110{\sim}130^{\circ}C$, 수분함량 $15{\sim}25%$, 스크류속도 $200{\sim}300rpm$의 조건에서 압출성형하고, 반응표면분석법(RSM)을 이용하여 최적조건을 분석하였다. 압출공정에 의한 전곡립의 수용화 효과는 수분용해지수(WSI), 농도(수율), 고유점도를 측정하였으며, 수율과 고유점도를 동시에 고려하여 새로운 무차원군의 최적인자인 $([\eta])$를 적용하여 최적조건을 찾고자 하였다. 각 조건별 실험결과를 반응표면분석을 실시하여 본 결과, 종속변수들에 대한 결정계수$(R^2)$는 $0.936{\sim}0.984$ 범위로 나타났다. 현미의 경우에는 수용화 수율, 현미찹쌀은 고유점도, 보리와 현미율무는 수용화 수율과 고유점도에 대해서 모델식이 유의성을 나타내었다. 특히 독립변수 중에서는 수분함량이 가장 큰 영향을 보였다. 최적인자인 $([\eta])$에는 고유점도가 더 큰 영향을 미치므로, 현미의 경우에서는 유의성을 보이지 않았다. 현미의 경우를 제외하고 최적화 인자로 설정한 $([\eta])$의 최적값을 찾기 위하여 회귀분석을 한 결과 임계점은 스크류 속도는 약 300rpm, 수분함량은 20%, 온도는 $120^{\circ}C$인 지점에서 나타났다.

• 한국농공학회지
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• 제29권4호
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• pp.59-72
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• 1987

Although long-term runoff analysis is important as much as flood analysis in the design of water works, the technological level of the former is relatively lower than that of the latter. In this respect, the precise estimation model for the volume of successive runoff should he developed as soon as possible. Up to now, in Korea, Gajiyama's formula has been widely used in long-term runoff analysis, which has many problems in applying in real situation. On the other hand, in flood analysis, unit hydrograph method has been exclusively used. Therefore, this study aims at trying to apply unit hydrograph method in long-term runoff analysis for the betterment of its estimation. Four test catchment areas were selected ; Maesan area in Namlum river as a representative area of Han river system, Cheongju area in Musim river as one of Geum river system, Hwasun area in Hwasun river as one of Yongsan river system, and Supyung area in Geum river as one of Nakdong river system. In the analysis of unit hydrograph, seperation of effective rainfall was carried out firstly. Considering that effective rainfall and moisture condition of catchrnent area are inside and outside of a phenomenon respectively and the latter is not considered in the analysis, Initial base flow(qb)was selected as an index of moisture condition. At the same time, basic equation(Eq.7) was established, in which qb can take a role as a parameter in relating between cumulative rainfall(P) and cumulative loss of rainfall(Ld). Based on the above equation, computer program for estimation model of qbwas seperately developed according to the range of qb, Developed model was applied to measured hydrographs and hyetographs for total 10 years in 4 test areas and effective rainfall was estimated. Estimation precision of model was checked as shown in Tab- 6 and Fig.8. In the next stage, based on the estimated effective rainfall(R) and runoff(Qd), a runoff distribution ratio was calculated for each teat area using by computerised least square method and used in making unit hydrographs in each test area. Significance of induced hydrographs was tested by checking the relative errors between estimated and measured runoff volume(Tab-9, 10). According to the results, runoff estimation error by unit hydrograph itself was merely 2 or 3 %, but other 2 or 3 % of error proved to be transferred error in the seperation of effective rainfall. In this study, special attentioning point is that, in spite of different river systems and forest conditions of test areas, standardized unit hydrographs for them have very similar curve shape, which can be explained by having similar catchinent characteristics such as stream length, catchinent area, slope, and vegetation intensity. That fact should be treated as important factor ingeneralization of unit hydrograph method.

• 한국산림과학회지
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• 제99권3호
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• pp.414-422
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• 2010

본 연구에서는 Eucalyptus pellita와 Acacia mangium 용기묘를 대상으로 관수 주기 처리를 통해 3가지 수준(1회/1일, 1회/2일, 1회/3일)으로 수분 조건을 달리하여 광합성, 수분이용효율, 기공전도도 및 생장 특성 변화를 조사 분석하였으며, 열대림 두 수종에 대한 용기 양묘 시 최적의 수분 환경을 구명 하고자 하였다. 그 결과, E. pellita는 1회/1일 관수 처리구에서 우수한 광합성 능력을 보였으며, A. mangium은 세 처리구 모두 좋은 광합성 능력을 나타냈다. 두 수종 모두 관수 주기가 짧을수록 기공전도도는 높아진 반면, 수분이용효율은 낮은 값을 보였다. 근원경과 간장 생장은 두 수종 모두 1회/1일 관수 처리구에서 높았으며 관수 주기가 짧을수록 높은 생장을 나타냈다. H/D율, 물질생산량 및 묘목품질지수(DQI)도 같은 경향을 보였으나, T/R율은 반대의 경향을 나타냈다. 1회/1일 관수 처리구는 건전하게 양묘된 묘목으로 평가할 수 있으며, 세 처리구 중 가장 우수한 묘목을 생산할 수 있는 수분 조건으로 판단된다.

• Journal of Ginseng Research
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• 제40권1호
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• pp.28-37
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• 2016

Background: Panax ginseng cannot be cultivated on the same land consecutively for an extended period, and the underlying mechanism regarding microorganisms is still being explored. Methods: Polymerase chain reaction and denaturing gradient gel electrophoresis (PCR-DGGE) and BIO-LOG methods were used to evaluate the microbial genetic and functional diversity associated with the P. ginseng rhizosphere soil in various cultivation ages and modes. Results: The analysis of microbial diversity using PCR-DGGE showed that microbial communities were significantly variable in composition, of which six bacterial phyla and seven fungal classes were detected in P. ginseng soil. Among them, Proteobacteria and Hypocreales dominated. Fusarium oxysporum, a soilborne pathogen, was found in all P. ginseng soil samples except R0. The results from functional diversity suggested that the microbial metabolic diversity of fallow soil abandoned in 2003was the maximum and transplanted soil was higher than direct-seeding soil and the forest soil uncultivated P. ginseng, whereas the increase in cultivation ages in the same mode led to decreases in microbial diversity in P. ginseng soil. Carbohydrates, amino acids, and polymers were the main carbon sources utilized. Furthermore, the microbial diversity index and multivariate comparisons indicated that the augmentation of P. ginseng cultivation ages resulted in decreased bacterial diversity and increased fungal diversity, whereas microbial diversity was improved strikingly in transplanted soil and fallow soil abandoned for at least one decade. Conclusion: The key factors for discontinuous P. ginseng cultivation were the lack of balance in rhizosphere microbial communities and the outbreak of soilborne diseases caused by the accumulation of its root exudates.

• 한국인터넷방송통신학회논문지
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• 제15권3호
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• pp.169-173
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• 2015

이 논문은 사용한지 13년 지난 운전 중 22 kV 케이블시스템을, 7년 동안 절연저항을 측정하여 그 결과를 연구한 논문이다. 우리는 발전소에서 설치 운전 중인 고전압 케이블이 시간에 따라 성능이 악화되는 현상의 추세를 결정하는 수명지수를 파악하였다. 위한 논문이다. 케이블 시스템은 시간에 따라 절연 저항이 감소한다. 초기 케이블 시스템은 아레니우스 열화 곡선을 따른다. 초기에는 수명 지수 n값이 9로 설계하였고, 이후 n값을 상향하여 16으로 결정하였다. 이유는 고전압에서 케이블이 동작할 경우, n값이 클 때 파괴특성이 높지 않고, n값이 낮은 값에서 파괴특성이 높았기 때문이다. 그러나 전압열화에 의하여 와이블 프롯을 따른 v-t 특성에 의하여 n값은 10~11의 값을 갖는 것을 확인하였다. 과거 케이블 설계 시 정한 n=9의 이론적 근거와 n=16 으로 높아진 원인을 파악함으로써 누설 전류 및 절연 저항의 선형적인 변화를 확인하였다. 단기적으로는 운전 중 케이블 시스템의 진단 평가에 활용되며, 장기적으로는 발전소 부하에서 동작 중인케이블 시스템의 설치 및 운영에 있어서 원가를 절감하기 위한 노력에 기여하고자 한다.

• Journal of the Korean Academy of Child and Adolescent Psychiatry
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• 제31권3호
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• pp.121-130
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• 2020

Objectives: We investigated the differences in cognitive and emotional empathic ability between adolescents and adults, and the differences of the brain activation during cognitive and emotional empathy tasks. Methods: Adolescents (aged 13-15 years, n=14) and adults (aged 19-29 years, n=17) completed a range of empathic ability questionnaires and were scanned functional magnetic resonance imaging (fMRI) during both cognitive and emotional empathy task. Differences in empathic ability and brain activation between the groups were analyzed. Results: Both cognitive and emotional empathic ability were significantly lower in the adolescent compared to the adult group. Comparing the adolescent to the adult group showed that brain activation was significantly greater in the right transverse temporal gyrus (BA 41), right insula (BA 13), right superior parietal lobule (BA 7), right precentral gyrus (BA 4), and right thalamus whilst performing emotional empathy tasks. No brain regions showed significantly greater activation in the adolescent compared to the adult group while performing cognitive empathy task. In the adolescent group, scores of the Fantasy Subscale in the Interpersonal Reactivity Index, which reflects cognitive empathic ability, negatively correlated with activity of right superior parietal lobule during emotional empathic situations (r=-0.739, p=0.006). Conclusion: These results strongly suggest that adolescents possess lower cognitive and emotional empathic abilities than adults do and require compensatory hyperactivation of the brain regions associated with emotional empathy or embodiment in emotional empathic situation. Compensatory hyperactivation in the emotional empathy-related brain areas among adolescents are likely associated with their lower cognitive empathic ability.

• Bulletin of the Korean Chemical Society
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• 제26권7호
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• pp.1090-1096
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• 2005

$Ag_4Br_4$ nanoclusters have been synthesized in about 75% of the sodalite cavities of fully $K^+$-exchanged zeolite A (LTA). An additional KBr molecule is retained in each large cavity as part of a near square-planar $K_4Br^{3+}$ cation. A single crystal of $Ag_{12}$-A, prepared by the dynamic ion-exchange of $Na_{12}$-A with aqueous 0.05 M $AgNO_3$ and washed with $CH_3OH$, was placed in a stream of flowing 0.05 M KBr in $CH_3OH$ for two days. The crystal structure of the product ($K_9(K_4Br)Si_{12}Al_{12}O_{48}{\cdot}0.75Ag_4Br_4$, a = 12.186(1) $\AA$) was determined at 294 K by single-crystal X-ray diffraction in the space group Pm m. It was refined with all measured reflections to the final error index $R_1$ = 0.080 for the 99 reflections for which $F_o\;{\gt}\;4_{\sigma}\;(F_o)$. The thirteen $K^+$ ions per unit cell are found at three crystallographically distinct positions: eight $K^+$ ions in the large cavity fill the six-ring site, three $K^+$ ions fill the eight-rings, and two $K^+$ ions are opposite four-rings in the large cavity. One bromide ion per unit cell lies opposite a four-ring in the large cavity, held there by two eight-ring and two six-ring $K^+$ ions ($K_4Br^{3+}$). Three $Ag^+$ and three $Br^-$ions per unit cell are found on 3-fold axes in the sodalite unit, indicating the formation of nano-sized $Ag_4Br_4$ clusters (interpenetrating tetrahedra; symmetry $T_d$; diameter ca. 7.9 $\AA$) in 75% of the sodalite units. Each cluster (Ag-Br = 2.93(3) $\AA$) is held in place by the coordination of its four $Ag^+$ ions to the zeolite framework (each $Ag^+$ cation is 2.52(3) $\AA$ from three six-ring oxygens) and by the coordination of its four $Br^-$ ions to $K^+$ ions through six-rings (Br-K = 3.00(4) $\AA$).

• The Korean Journal of Ecology
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• 제28권1호
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• pp.15-23
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• 2005

아까시나무 우점림의 식생유형에 대한 분류와 분포양식 그리고 생태식물상적 특성을 규명하였다. 전통적인 식물사회학적 방법과 식생조사자료 및 식생유형간의 유사성 분석을 위하여 주좌표분석법(Principal Coordinates Analysis)과 상관 계수(correlation coefficient)가 이용되었다. 생태식물상의 분석에는 출현 식물종들의 특질(넌출형, 일이년생 생명환, 삼림식생요소, 체감도시화지수)이 이용되었다. 이러한 분석은 출현종의 상대기여도를 바탕으로 하는 입지-식생조사구 매트릭스의 식물군락표 및 군락합성표를 토대로 이루어졌다. 아까시나무 우점림은 총 77과 193속 323종으로 이루어져 있었으며, 아까시나무-닭의장풀군집(전형아군집, 떡갈나무아군집, 자귀나무아군집, 소나무아군집, 굴참나무아군집, 가중나무아군집), 아까시나무-갈대군락(전형하위군락, 띠하위군락)으로 분류되었으며, 크게 네 가지 식생형(도시형, 농촌형, 하천형, 복합형)으로 구분되었다. 아까시나무-닭의장풀군집은 졸참나무-작살나무아군단의 냉온대 남부 저산지대의 아까시나무 조림식생을 대표하는 식생단위이며, 아까시나무-갈대군락은 하천(정수역)형으로 기재되었다. 가중나무아군집은 높은 체감도시화지수에 의하여 도시형 아까시나무림으로 규정되었다. 하천형을 제외한 우리나라의 아까시나무 우점림은 지속군락으로 고려되었다.