• Title/Summary/Keyword: Quenching Curve

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A Numerical Analysis on Combustion Characteristics of the Gasoline Engine using Methanol Reformulated Fuels under WOT Condition (전부하 운전조건에서 메탄올 개질연료를 사용한 가솔린 엔진의 연소특성에 대한 수치해석)

  • Lee, Suk-Young;Jeon, Chung-Hwan
    • Journal of Energy Engineering
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    • v.20 no.2
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    • pp.163-169
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    • 2011
  • This research is to decide the possibility of using RM50(reformulated methanol fuel) without any modification of engine by the method of numerical analysis. Comparing the heat release rate, the difference among each fuel was decreased according to the increase of the engine speed, and the maximum heat release rate was higher in the order of RM50 and gasoline fuel. Also, this order corresponds to the order of burning speed. RM50 had the higher turbulent burning speed, and the curve of turbulent intensity was showed similar tendency to the curve of turbulent burning speed. RM50 had relatively high burning speed, short quenching length, high temperature in cylinder, so that it might increase NO emission, but owing to chemical reaction dynamics, it was decreased NO emission. Therefore, in order to predict the possibility of using RM50, it is needed to consider not only the temperature in cylinder by low heating value, but also combustion characteristics including burning speed.

Impact toughness improvement of an undercarriage track shoe using the Taguchi orthogonal array experiment (다구찌 직교배열 실험을 이용한 무한궤도용 트랙 슈의 충격인성 향상 연구)

  • Kim, Young Suk;Chang, Keun Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.3
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    • pp.1611-1619
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    • 2015
  • This study examined the toughness improvement of a track shoe used as the undercarriage of excavator and bulldozer parts. The excavator is operated under poor conditions, such as the build-up field and quarry. Therefore, the track shoe requires high strength and impact toughness to endure immense shock while at work. The track shoe was made of heat treated boron steel. The sufficient possibility of hardenability with the theoretical Jominy curve for boron steel was confirmed while quenching. The Taguchi orthogonal array experiment method was used to optimize the process variables, such as area reduction ratio and heat treatment conditions (tempering temperature and holding time), to achieve toughness improvement. The toughness of the track shoe increased with increasing area reduction, and a tempering temperature of $210^{\circ}C$ and a tempering time of 80 min are beneficial for improving the toughness of the track shoe.

Early Alterations of Chlorophyll Fluorescence by Light-Chilling in Cucumber (Cucumis sativus) Leaves and Their Usage as Stress Indicators (오이 잎에서 저온 광저해에 의한 형광유도과정의 초기 변이와 스트레스 지표)

  • Ha, Suk-Bong;Young-Jae Eu;Choon-Hwan Lee
    • The Korean Journal of Ecology
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    • v.19 no.2
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    • pp.151-163
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    • 1996
  • To investigate the early symptoms of light-chilling, alterations of chlorophyll fluorescence transients were monitored in cucumber (Cucumis sativus L. cv. Ilmichungjang) leaves. During 24 h chilling, decreases in (Fv)m/Fm, qE and qQ, and an increase in Fo were observed. The chilling effects were not recovered at room temperature, and a significant increase in Fo was observed during the recovery period. After 6 h chilling, ‘dip’(D) level of the transients became obscure, and the negative slope after ‘peak’(P) disappeared. The first derivative (dFv/dt) of the fast fluorescence rise curve was used to obtain more accurate information about the changes in the transients. The maximal rate of the fluorescence increase in the D-p rise curve (Fr) has been the most frequently used chilling stress indicator. However, a correct value of Fr could not be measured when the D level became obscure. This problem was overcome by introducing a new indicator, HFr (dFv/dt at Fv = 1/2 (Fv)m), and HFr gave very similar values to Fr. To monitor the changes in curvature around D level, another new parameter, ${\Delta}S$(D-Fr), was also introduced. These three parameters decreased very sensitively during light-chilling. In addition, increases in these parameters were observed during the first 2 h chilling, but this increase in Fr was also observed in pea leaf discs dark-chilled for 15 min, suggesting that this very early change is a common response to chilling in both pea and cucumber leaves. Quenching coefficients were also very sensitive to chilling, especially qE. Discussion on the usage of these parameters as chilling stress indicators is given in the text.

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A Study on the Mechanical Properties by High-Frequency Induction Hardening of SCM440 Steel (고주파 담금질에 의한 SCM440강의 기계적 특성에 관한 연구)

  • Ahn, Seok-Hwan;Nam, Ki-Woo;Kim, Tae-Il;Lee, Mun-Yong;Kim, Dong-Kyu
    • Journal of Ocean Engineering and Technology
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    • v.23 no.2
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    • pp.74-80
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    • 2009
  • Surface hardening treatments, such as using the high-frequency induction hardening method, are widely used to increase the fatigue life and prevent the failure of materials by locally increasing the surface hardness. This method, in particular, brings an improvement in static strength by compressive residual surface stress due to the hardening. In this study, the mechanical properties of high-frequency induction hardened SCM440 steel were investigated. These results were also compared with those for base metal and a Q/T (tempering after quenching) treatment specimen. The test results showed that partially high-frequency induction hardened SCM440 steel specimens were more improved in static strength, surface hardness, fatigue limit, and anti-wear than the base metal and Q/T treatment specimens. In particular, the fatigue limit of the high-frequency induction hardened SCM440 steel increased by more than about 52% compared to that of base metal and by about 25% compared to that of the Q/T specimen.

Mercury-Induced Light-Dependent Alterations of Chlorophyll a Fluorescence Kinetics in Barley Leaves

  • Lee, Choon-Hwan
    • Journal of Plant Biology
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    • v.38 no.1
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    • pp.11-18
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    • 1995
  • Mercury-induced changes in Chl a fluorescence induction kinetics of scratched barley leaf segments were dependent on the presence of light. By the treatment of 50$\mu$M HgCl2 under light condition, Fm and Fp were decreased. However, they were not significantly reduced under dark condition even after 2 h of mercury treatment. Under dark condition the decrease in variable fluorescence (Fv) after P transient was blocked within 20 min of the treatment. The analysis of fast fluorescence rise curve suggests that the inhibitory site of mercury under both light and dark conditions is not at QB binding site and the inhibition does not involve the increase in inactive PSII centers. Under light condition the decrease in Fp was partially recovered by addition of 50 $\mu$M NH2OH. These results suggest that a major inhibitory site of mercury under dark condition is at the reducing side of PSII and the site under light condition is at the oxidizing side of PSII possibly in addition to the one under dark condition. Under both light and dark conditions, energy-dependent quenching(qE) was alomost completely repressed within 20 min of mercury treatment and noticible change in Fo was not observed. The qE repression is probably due to the blockage of transthylakoid ΔpH formation.

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Microstructure and Magnetic Properties of Nanocomposite Sm2Fe15Ga2Cx/α-Fe Permanent Magnets

  • Cheng, Zhao-hua
    • Journal of Magnetics
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    • v.8 no.1
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    • pp.18-23
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    • 2003
  • In our previous work, microstructure and magnetic properties of two-phase exchange-coupled $Sm_2Fe_{15}Ga_2C_{x}$/$\alpha$-Fe nanocomposites have been investigated by means of x-ray diffraction, transmission electron microscopy and magnetization measurement. It was found the exchange coupling between the magnetically hard phase $Sm_2Fe_{15}Ga_2C_{x}$ and the magnetically soft one ${\alpha}$-Fe results in an enhancement of the remanence. The sizes of crystallites of both phases are, however much larger than the Block domain-wall width of the magnetically hard phase. This microstructure gives rise to a concave demagnetization curve and consequently reduces the maximum energy Product. In order to improve their magnetic properties, a few Percent of Zr, which may be effective to refine the microstructure through rapid quenching, was introduced into the nanocomposites. The addition of Zr was found to improve the magnetic properties significantly, Under optimum heat-treatment conditions, the remanence, coercivity and maximum energy Product increase from 0.65 T, 0.48 T and 50 kJ/$m^{3}$ for the Zr-free sample to 0.72 T, 0.77 T and 71.6 kJ/$m^{3}$ for the 1 at.% Zr-containing one, respectively, The improvements of magnetic properties are due to the refinement of microstructure by the addition of Zr.

Changes in High-temperature Coefficient of Thermal Expansion of Artificial Aging Heat-treated Al-Si-Mg-Cu-(Ti) Alloys (시효 열처리 된 Al-Si-Mg-Cu-(Ti) 합금의 고온 열팽창 계수 변화)

  • Choi, Se-Weon
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.5
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    • pp.226-232
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    • 2021
  • The relationship between precipitation and coefficient of thermal expansion of Al-6%Si-0.4%Mg-0.9%Cu-(Ti) alloy (in wt.%) after various heat treatments were studied by the thermodynamic analyzer (TMA) and differential scanning calorimetry (DSC). Solution heat treatment of the alloy was carried out at 535℃ for 6 h followed by water quenching, and the samples were artificially aged in the air at 180℃ and 220℃ for 5 h. The coefficient of thermal expansion (CTE) curve showed some residual strain and decreased with increasing aging temperature. The CTE curves changed sharply in the temperature range of 200℃ to 400℃, and the corresponding peak shifted for the aged samples due to the change in the precipitation behavior of the secondary phase. These transformation peaks in the aged sample are related to the volume of the precipitation of the Si phase as determined by DSC analysis. The change in CTE is mainly caused by the precipitation of the Si phase in the Al-Si alloy, and the size of the change occurs simultaneously with the size of the precipitate.

A Study on the Wear Characteristics and Lifetime Of High Chromium Roll (고크롬 롤의 수명과 마멸특성에 관한 연구)

  • Kim, M.K.;Kim, S.K.;Jeon, E.C.
    • Journal of the Korean Society for Precision Engineering
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    • v.14 no.2
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    • pp.58-65
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    • 1997
  • Work rolls used in cold rolling mills must have outstanding wear resistance and very little plastic defor- mation. Thus, these rolls require a higher surface hardness and harding to a greater depth. To meet these requirements, the rolls, in general, have basic chemical composition of 0.7 to 1.0% carbon and 1.0 to 5.0% Cr(chromium), plus a small amounts of special elements, and are subjected to intensive water quenching and tempering at low temperature to provide a surface hardness of over 90 shore. This test results are as follows. Deflection and fracture load of 5% Cr material are than those of 3% Cr material and show flat curve from surface to subsurface. It will be clear that 5% Cr work roll has a superior resisti- bility against wear and abrasion comparing with 3% Cr work roll. The improvement of wear and abrasion in 5% Cr work roll will be achieved by the large amount of wpheroidal carbide. In grindability and polish, 5% Cr work roll will be a little inferior comparing with 3% Cr work roll.

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Europium-Enoxacin Complex as Fluorescence Probe for the Determination of Folic Acid in Pharmaceutical and Biological Samples

  • Alam, Al-Mahmnur;Kamruzzaman, Mohammad;Lee, Sang-Hak;Kim, Young-Ho;Min, Kyung
    • Bulletin of the Korean Chemical Society
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    • v.33 no.9
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    • pp.3055-3060
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    • 2012
  • A simple, rapid and sensitive spectrofluorometric method was developed for the determination of folic acid (FA), based on its quenching effect on the fluorescence intensity of enoxacin (ENX)-europium ($Eu^{3+}$) complex as a fluorescent probe. Fluorometric interaction between ENX-$Eu^{3+}$ complex and FA was studied using UV-visible and fluorescence spectroscopy. The quenched fluorescence intensity at an emission wavelength of 614 nm was proportional to the concentration of FA. Optimum conditions for the determination of FA were investigated. Under optimal conditions, the reduced fluorescence intensity at 614 nm was responded linearly with the concentration of FA. The linearity was maintained in the range of $1.25{\times}10^{-9}$ to $1.50{\times}10^{-7}$ M (R = 0.9986) with the limit of detection ($3S_b/m$) (where $S_b$ is the standard deviation of blank and m is the slop of linear calibration curve) of $6.94{\times}10^{-10}$ M. The relative standard deviation (RSD) for 9 repeated measurements of $1.0{\times}10^{-9}$ M FA was 1.42%. This method was simple, cost effective, and relatively free of interference from coexisting substances. Successful determinations of FA in pharmaceutical formulation and biological samples with the developed method were demonstrated.

High Strength SA508 Gr.4N Ni-Cr-Mo Low Alloy Steels for Larger Pressure Vessels of the Advanced Nuclear Power Plant (차세대 원전 대형 압력용기용 고강도 SA508 Gr.4N Ni-Cr-Mo계 저합금강 개발)

  • Kim, Min-Chul;Park, Sang-Gyu;Lee, Ki-Hyoung;Lee, Bong-Sang
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.10 no.1
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    • pp.100-106
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    • 2014
  • There is a growing need to introduce advanced pressure vessel steels with higher strength and toughness for the optimizatiooCn of the design and construction of longer life and larger capacity nuclear power plants. SA508 Gr.4N Ni-Cr-Mo low alloy steels have superior strength and fracture toughness, compared to SA508 Gr.3 Mn-Mo-Ni low alloy steel. Therefore, the application of SA508 Gr.4N low alloy steel could be considered to satisfy the strength and toughness required in advanced nuclear power plants. The purpose of this study is to characterize the microstructure and mechanical properties of SA508 Gr.4N low alloy steels. 1 ton ingot of SA508 Gr.4N model alloy was fabricated by vacuum induction melting followed by forging, quenching, and tempering. The predominant microstructure of the SA508 Gr.4N model alloy is tempered martensite having small packet and fine Cr-rich carbides. The yield strength at room temperature was 540MPa, and it was decreased with an increase of test temperature while DSA phenomenon occurred at around $288^{\circ}C$. Overall transition property of SA508 Gr.4N model alloy was much better than SA508 Gr.3 low alloy steel. The index temperature, $T_{41J}$, of SA508 Gr.4N model alloy was $-132^{\circ}C$ in Charpy impact tests, and reference nil-ductility transition temperature, $RT_{NDT}$ of $-105^{\circ}C$ was obtained from drop weight tests. From the fracture toughness tests performed in accordance with the ASTM standard E1921 Master curve method, the reference temperature, $T_0$ was $-147^{\circ}C$, which was improved more than $60^{\circ}C$ compared to SA508 Gr.3 low alloy steels.