• Journal of Advanced Marine Engineering and Technology
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• v.19 no.2
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• pp.20-26
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• 1995

The very rapid cooling problem from $820^{\circ}$C to $20^{\circ}$C on the surface of the steel by thermal conduction including the latent heat of phase transformation of steel and by transient boiling heat transfer of water are considered to principal problem in quenching. The transient boiling process of water at the surface of specimen during the quenching process were experimentally analyzed. Then the heat flux was numerically calculated by the numerical method of inverse heat condition problem. In this report, the simulation program to calculate the cooling curves for large rolls was made using the subcooled transient boiling curve as a boundary condition. By this simulation program, the cooling curves of rolls from D=50mm to D=200mm were calculated and the effects of agitation of circulation of water also investigated.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.6
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• pp.1529-1540
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• 1993

The quenching of steels by water is one of the imprtant problems in the applications of heat treatment, but the fundamental researches by way of theoretical approaches have not been satisfactorily improbed yet. This study aimed at measuring the exact subcooled transient boiling curve for cylindrical specimens and at conducting the analytical researches into the prediction of cooling curves, including the latent heat of phase transformation of steel. Experiments of quenching were made with cylindrical specimens of carbon steel S45C of diameters from 12 to 30 mm and with Cu specimens of 12 mm diameter respectively. The internal temperature of specimens during the quenching process was measured by C-A sheathed thermocouple. The heat fluxes were numerically calculated by the numerical method of inverse heat conduction problem, using the measured inner temperature of specimen as a boundary condition. In case of ${\Delta}T_{sub}=80K$, $q_{s}$ is as follows $q_{s}=2.02{\times}10^{5}{\Delta}T_{set}^{0.05}:{\Delta}T_{set}\le500K.$ And the numerical analysis of unsteady heat conduction during the quenching process was made and the cooling curves were calculated by TDMA method.

• Journal of Advanced Marine Engineering and Technology
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• v.18 no.3
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• pp.10-16
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• 1994

This study aimed at measuring the latent heat of phase transformation of S45C carbon steel in quenching and at conducting the analytical researches into the calculation of cooling curves including the latent heat. The temperature of phase transformation of steel and its latent heat are dependant upon the cooling rates at the temperature of A1 phase transformation point. The effect of the latent heat of phase transformation is especially manifest at the cooling curve of center of specimens. The higher the cooling rates became, the lower fell the temperature region of phase transformation. In the figures of cooling rates, the phenomena of cooling rate dropping into zero was caused by the latent heat of phase transformation.

• Journal of Soil and Groundwater Environment
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• v.12 no.6
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• pp.53-59
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• 2007

Optimal quenching curves have been studied for the accurate analysis of $^{14}C$ in groundwater polluted by reducing efficiency of volatile organic compounds (VOCs) in liquid scintillation counter (LSC). The quenching parameters (SQP(E)) were measured for ten VOCs such as benzene, toluene, ethylbenzene, o-(m-,p-)xylene, trichloroethylene (TCE), tetrachloroethylene(PCE), carbon tetrachloride and chloroform. The quenching curves were plotted using $^{14}C$ standard solution and chloroform as a quenching agent. Optimal plotting conditions were determined for standard solution, LSC measuring time and the concentration of chloroform. The quenching effects of chlorinated organic compounds such as TCE, PCE, carbon tetrachloride and chloroform were greater than those of BTEX (benzene, toluene, ethylbenzene and xylene). Optimum measuring time was 100 minutes far 7,000 dpm/mL standard solution. A few mL of chloroform should be added for good quenching curves. These quenching curves have good correlation coefficients (> 0.99) and the curves could be applied to accurate analysis of $^{14}C$ in groundwater and tap water.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.4
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• pp.69-76
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• 2018

This study examined the effect of the heat treatment and alloying elements (B, Ti) on the microstructures and mechanical properties of API J55 steel. The experiments were carried out using various austenization temperatures ($880^{\circ}C$, $910^{\circ}C$, $940^{\circ}C$), cooling methods (water quenching, oil quenching) and tempering temperatures (none, $550^{\circ}C$, $650^{\circ}C$) with J55 and J55+B,Ti steels. The phase diagram and CCT curve were simulated based on the chemical compositions of the J55 and J55+B,Ti steels to predict the microstructures. The results showed that the A1 and A3 temperatures decreased and, as a result, the noses of the ferrite and bainite parts of the CCT curve moved to the right. Various microstructures were formed, namely martensite, bainite, ferrite and pearlite, in accordance with the heat treatment, which had an effect on the hardness, tensile strength and toughness. Martensite was formed after water quenching, but bainite and ferrite appeared after oil quenching with the J55 specimens. On the other hand, martensite was formed, regardless of the cooling method (water quenching, oil quenching), with the J55+B,Ti specimens, because of the improvement of the hardenability caused by the addition of boron. Therefore, the J55+B,Ti specimens exhibited much higher mechanical properties than the J55 specimens, even after the tempering treatment, since the addition of Ti caused fine precipitates to be formed, which inhibited grain growth at the recrystallization temperature.

• Journal of the Korean Chemical Society
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• v.56 no.5
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• pp.577-582
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• 2012

Quinine quantitative analysis, photo-bleaching, fluorescence quenching, and urine analysis have been performed by means of a UV-LED fluorometer, which can be easily built and used in a high-school laboratory. The quinine detection range is estimated to be 0.05-80 ppm, enough for many classroom luminescence experiments. The quinine content in commercial tonic water is determined from the calibration curve, and UV photo-bleaching of this anti-malarial drug is demonstrated with clear wavelength dependence. Halide quenching of quinine fluorescence is also observed and the increase in quenching efficiency in the order of $Cl^-$, $Br^-$, and $I^-$ is evident. Urine analyses for the student volunteers have been carried out and the results clearly reveal excretion of the ingested quinine. The student participants are exuberant throughout the course of this study and sense the practices resourceful.

• Bulletin of the Korean Chemical Society
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• v.31 no.6
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• pp.1479-1484
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• 2010

Photosynthesis uses light energy to drive the oxidation of water at an oxygen-evolving catalytic site within photosystem II (PSII). Chlorophyll binding by the photosystem II subunit S protein, PsbS, was found to be necessary for energy-dependent quenching (qE), the major energy-dependent component of non-photochemical quenching (NPQ) in Arabidopsis thaliana. It is proposed that PsbS acts as a trigger of the conformational change that leads to the establishment of nonphotochemical quenching. However, the exact structure and function of PsbS in PSII are still unknown. Here, we clone and express the recombinant PsbS gene from Arabidopsis thaliana in E. coli and purify the resulting homogeneous protein. We used various biochemical and biophysical techniques to elucidate PsbS structure and function, including circular dichroism (CD), fluorescence, and DSC. The protein shows optimal stability at $4^{\circ}C$ and pH 7.5. The CD spectra of PsbS show that the conformational changes of the protein were strongly dependent on pH conditions. The CD curve for PsbS at pH 10.5 curve had the deepest negative peak and the peak of PsbS at pH 4.5 was the least negative. The fluorescence emission spectrum of the purified PsbS protein was also measured, and the ${\lambda}_{max}$ was found to be at 328 nm. PsbS revealed some structural changes under varying temperature and oxygen gas condition.

• Journal of Powder Materials
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• v.1 no.2
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• pp.181-189
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• 1994

The compacts of pure and phosphorus-coated iron powder with 0~0.8%C were sintered at $1100^{\circ}C$ for 40 min. in cracked ammonia gas atmosphere. The tensile and impact strengths were measured and the relationship of the results with carbon content, phosphorus, quenching and tempering was investigated. The results obtained can be summarized as follows : (1) The tensile strength of sintered compacts increased slowly with carbon content. Increase in tensile strength by heat treatment was evident especially in the low carbon specimen. The specimen with phosphorus showed higher strength compared to pure iron compacts value. (2) No inflection point of elasticplastic deformation on stress-strain curve was observed in sintered steel. The elastic modulus of sintered steel had the same tendency as tensile strength. But the elongation showed the opposite tendency. (3) The impact absorption energy of sintered steel without addition of phosphorus decreased successively with carbon content and by quenching and tempering. On the contrary, addition of phosphorus resulted in an increase of the impact absorption energy. Quenching and tempering did not affect the impact energy especially in high carbon content. (4) The main fracture source was pore in specimen and the propagation of crack occured mostly along the grain boundaries. But the intragranular fracture was also observed in high carbon, quenched and tempered specimen, and especially in the specimen with phosphorus.

• Bulletin of the Korean Chemical Society
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• v.7 no.2
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• pp.137-142
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• 1986

The luminescence spectra of $Ru(bpy)_3^{2+}$ in poly(methacrylic acid) (PMA) solutions varied sensitively with pH. At pH < 5.5, the emission intensity increased with pH up to 4 times, while it decreased with pH beyond the pH. The enhanced emission intensity was accompanied by blue-shift of the emission maxima as much as 15 nm. The enhancement of emission intensity was attributed to the restricted rotational mobility of ligand of the cation bound to densely coiled PMA molecules at pH < 5.5. The sharp decrease in emission intensity with increasing pH near pH 5.6 was accounted for conformational transition of the polymer to more extended structure, which was also revealed in viscosity measurement. The enhancement of emission intensity became higher as NaCl concentration of the solution increased. The binding constant of $Ru(bpy)_3^{2+}$ with two carboxylate groups of PMA was calculated as $2{\times}10^5\;M^{-1}$ in 0.1 M NaCl at pH 5.2. The pH dependence of luminescence quenching rate of $Ru(bpy)_3^{2+}$ by $Cu^{++}$ also showed maximum near pH 5, and the rate was more than $10^3$ times higher than that in water, whereas the maximum enhancement of quenching rate (about 20 times) in poly(acrylic acid) (PAA) solution occurred at pH 4.5. On the other hand, the pH dependence for neutral water soluble nitrobenzene (NB) exhibited opposite trend to that of $Cu^{++}$. The quenching constant vs pH curve for $MV^{++}$ was composite of those for $Cu^{++}$ and NB. The anomalous high quenching rate for $Cu^{++}$ in PMA solution at pH < 5.5 was attributed to the binding of $Ru(bpy)_3^{2+}$ and $Cu^{++}$ to the same region of PMA, when it conforms densely coiled structure in the pH range. The observation of mininium quenching rate for NB near pH 5.5 indicated that the $Ru(bpy)_3^{2+}$ bound to the densely coiled PMA is not accessible by NB, which is in bulk water phase. The composite nature of the pH dependence of quenching rate for $MV^{++}$ in PMA solution was attributed to the smaller binding affinity of the cation to PMA, compared to that of $Cu^{++}$. The sharp, cooperative conformational transition with pH observed in PMA was not revealed in PAA. But, the pH dependence of quenching rates in this polymer reflected increased charge density and, thus, binding of cations to the polymer, and expansion of the polymer chain with pH.

• Journal of Radiation Protection and Research
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• v.43 no.3
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• pp.114-119
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• 2018

Background: The retrospective dosimetry using RTL quartz can be improved by information for an optical sensitivity of sample connected with the equivalent dose determination. Materials and Methods: The quartz sample from a volcanic rock of Japan was used. After correcting the thermal quenching effect, RTL peaks of quartz were separated by the CGCD method cooperated with the general order kinetics. The number of overlapped glow peaks were ascertained by the $T_m-T_{stop}$ method. The optical sensitivity was examined by comparing the change of intensity on RTL glow peaks measured after exposure to light from a solar simulator with various illumination times. Results and Discussion: Seven glow peaks appeared to be overlapped on the RTL glow curve. The general order kinetics model was appropriate to separate glow peaks. After exposure to light from a solar simulator from a few minutes to 416 hr, the signals for peaks P4 and P5 decayed following the form of $f(t)=a_1e^{-{\lambda}1t}$, while the signals for peaks P6 and P7 decayed by the form of $f(t) = a_1e^{-{\lambda}1t}+a_2e^{-{\lambda}2t}+a_3e^{-{\lambda}3t}$. Conclusion: For dosimetric peaks, the times taken to reduce the RTL signal to half of its initial value were 70 sec for the peak P4, 54 s for the peak P5, 9,840 sec for the peak P6 and 26,580 sec for the peak P7, respectively. We conclude that the optical sensitivity of peaks P4, and P5 gives much higher than that of peaks P6 and P7.