• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.587-596
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• 2014

A new ${\pi}$-stacked donor-acceptor (D-A) system, [Ru(1-([2,2'-bipyridine]-6-yl-methyl)-3-(2-cyclohexa-2',5'-diene-1,4-dionyl)-1H-imidazole)(2,2':6',2"-terpyridine)]$[PF_6]_2$ (ImQ_T), has been synthesized and characterized. Similar to its precedent, [Ru(6-(2-cyclohexa-2',5'-diene-1,4-dione)-2,2':6',2"-terpyridine)(2,2':6',2"-terpyridine)]$[PF_6]_2$ (TQ_T), this system has a cofacial alignment of terpyridine (tpy) ligand and quinonyl (Q) group, which facilitates an electron transfer through ${\pi}$-stacked manifold. Despite the presence of lowest-energy charge transfer transition from the Ru-based-HOMO-to-Q-based-LUMO (MQCT) predicted by theoretical calculations by using time-dependent density functional theory (TD-DFT), the experimental steady-state absorption spectrum does not exhibit such a band. The selective excitation to the Ru-based occupied orbitals-to-tpy-based virtual orbital MLCT state was thus possible, from which charge separation (CS) reaction occurred. The photo-induced CS and thermal charge recombination (CR) reactions were probed by using ultrafast visible-pump/mid-IR-probe (TrIR) spectroscopic method. Analysis of decay kinetics of Q and $Q^-$ state CO stretching modes as well as aromatic C=C stretching mode of tpy ligand gave time constants of <1 ps for CS, 1-3 ps for CR, and 10-20 ps for vibrational cooling processes. The electron transfer pathway was revealed to be Ru-tpy-Q rather than Ru-bpy-imidazol-Q.

• Proceedings of the KIEE Conference
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• 1999.07f
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• pp.2481-2483
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• 1999

This paper proposed the p-q-r coordinate system where the instantaneous active power p, and the two instantaneous reactive powers $q_{q}$, $q_{r}$ were defined. The three power components are linearly independent, so the compensation for the two instantaneous reactive powers leads to control the two components of the current space vector. With the theory, the neutral current of a three-phase four-wire system can be eliminated by only compensating the instantaneous reactive power using no energy storage element.

• The KIPS Transactions:PartA
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• v.8A no.1
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• pp.1-8
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• 2001

This paper describes the design and implementation of C standard library for real-time operating system Q+, that is being developed for the internet appliance. The C library in the real-time operating system should be defined according to the standard interface and support the concurrent execution of threads. The implemented C standard library is reentrant and follows POSIX.l standard interface. And, the C standard library functions, which are adequate to the Q+ application and commonly provided by commercial real-time operating systems, are selected among POSIX.l standard functions. The C standard library is implemented on the Q+ kernel and D-TV set-top box according to the implementation sequence, which is determined by analyzing the relation of function calls.

• Bulletin of the Korean Mathematical Society
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• v.50 no.1
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• pp.37-56
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• 2013

This paper deals with the behavior of positive solutions to the following nonlocal polytropic filtration system $$\{u_t=(\mid(u^{m_1})_x{\mid}^{{p_1}^{-1}}(u^{m_1})_x)_x+u^{l_{11}}{{\int_0}^a}v^{l_{12}}({\xi},t)d{\xi},\;(x,t)\;in\;[0,a]{\times}(0,T),\\{v_t=(\mid(v^{m_2})_x{\mid}^{{p_2}^{-1}}(v^{m_2})_x)_x+v^{l_{22}}{{\int_0}^a}u^{l_{21}}({\xi},t)d{\xi},\;(x,t)\;in\;[0,a]{\times}(0,T)}$$ with nonlinear boundary conditions $u_x{\mid}{_{x=0}}=0$, $u_x{\mid}{_{x=a}}=u^{q_{11}}u^{q_{12}}{\mid}{_{x=a}}$, $v_x{\mid}{_{x=0}}=0$, $v_x|{_{x=a}}=u^{q21}v^{q22}|{_{x=a}}$ and the initial data ($u_0$, $v_0$), where $m_1$, $m_2{\geq}1$, $p_1$, $p_2$ > 1, $l_{11}$, $l_{12}$, $l_{21}$, $l_{22}$, $q_{11}$, $q_{12}$, $q_{21}$, $q_{22}$ > 0. Under appropriate hypotheses, the authors establish local theory of the solutions by a regularization method and prove that the solution either exists globally or blows up in finite time by using a comparison principle.

• Journal of KIISE:Software and Applications
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• v.29 no.1_2
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• pp.30-41
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• 2002

We focus on the mobile agents which are considered as new paradigm to solve information retrieval of large volumes of data in the distributed and heterogeneous environment. The mobile agent moves the computation to data instead of large volumes of data to computations. In this paper, we propose an information retrieval model, which can effectively search data in the distributed and heterogeneous environment, using mobile agents. Our model is applied to the design and implementation of an Q&A(Question and Answer) retrieval system. Our Q&A retrieval system, called QASSMA(Q&A Search System using Mobile Agents), uses mobile agents to retrieve articles from Q&A boards and newsgroups that exist in the heterogeneous and distributed environment. QASSMA has the following features and advantages. First, the mobile retrieval agent moves to the destination server to retrieve articles to reduce the retrieval time by eliminating data traffics from the server to the client host. Also it can reduce the traffic that was occurred in the centralized network system, and reduce the usage of resources by sending its agent and running in the destination host. Finally, the mobile retrieval agent of QASSMA can add and update dynamically the class file according to its retrieval environment, and support other retrieval manner. In this paper, we have shown that our Q&A retrieval system using mobile agents is more efficient than the retrieval system using static agents by our experiments.

• Applied Chemistry for Engineering
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• v.7 no.2
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• pp.379-386
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• 1996

Photosensitive compound, 1-methyl-4-[2-(4-diethylacetylphenyl)ethenyl] pridinium methosulfate(SbQ-A salt), was synthesized from dimethyl sulfate, terephthalaldehyde mono-(diethylacetal) and 4-picoline. SbQ-A salts were reacted with poly(vinyl alcohol)s, (PVA) in aqueous solution with phosphoric acid as catalyst to give photosensitive PVA-SbQ with different SbQ content and molecular weight. Relative photosensitivity of PVA-SbQ was determined by gray scale(GS) method. The rotative sensitivity of PVA-SbQ increased with increasing amount of bound SbQ in the case of high molecular weight(MW=77,000-79,000g/mol) as substrate and decreased with decreasing molecular weight of PVA with about constant(1.3mol%) amount of bound SbQ. The most sensitive polymer was obtained when SbQ group content in PVA-SbQ reached about 2.63mol% in the case of high molecular weight(77,000-79,000g/mol) PVA. This sample showed 90 times greater sensitivity than dichromated PVA as reference photosensitive system. PVA-SbQ photosensitive polymer synthesized was applied to the photolithographic screening process of phosphor on the panel of cathode ray tube(CRT). Phosphor slurry was made with PVA-SbQ, phosphor, a small amount of surfactant and other additives using water as medium. The slurry was coated onto panel, dried by heater, exposed to UV light and then developed by distilled water. When a small amount of cationic surfactant such as cetyltrimethylammonium chloride was used in the slurry formulation, the sharpness of phosphor pattern was equal to or better than that of dichromated PVA photosensitive polymer system used currently.

• Proceedings of the CALSEC Conference
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• 2001.08a
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• pp.503-510
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• 2001

Q+-reader, an E-Book reader system for XML based contents is introduced. The system is developed for the embedded platform, called Q+, which targets for the digital home electronics systems. The system supports XML contents and CSS based styling as described in Open e-Book standard. The system renders the e-book contents for users, so the contents are secured for a proper use. This will found an essential part of business infra for electronic books with copyright protection. The system was developed in Java language to be used in various platforms, and has an open architecture to be reusable for other standards as well.

• Kyungpook Mathematical Journal
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• v.47 no.3
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• pp.381-392
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• 2007

In 1906, da Rios, a student of Leivi-Civita, wrote a master's thesis modeling the motion of a vortex in a viscous fluid by the motion of a curve propagating in $R^3$, in the direction of its binormal with a speed equal to its curvature. Much later, in 1971 Hasimoto showed the equivalence of this system with the non-linear Schr$\ddot{o}$dinger equation (NLS) $$q_t=i(q_{ss}+\frac{1}{2}{\mid}q{\mid}^2q$$. In this paper, we use the same idea as Terng used in her lecture notes but different technique to extend the above relation to the case of $R^3$, and obtained an analogous equation that $$q_t=i[q_{ss}+(\frac{1}{2}{\mid}q{\mid}^2+1)q]$$.

• The Transactions of the Korean Institute of Electrical Engineers A
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• v.48 no.3
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• pp.278-285
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• 1999

This paper utilizes the method of Q-parameterization control to design a controller which solves the problem of imbalance in magnetic bearing systems. There are two methods to solve this problem using feedback controal. The first method is to compensate for the imbalance forces by generating opposing forces on the bearing surface (imbalance compensation). The second method is to make the rotor rotate around its axis of inertia (automatic balancing);in this case no imbalance forces will be generated. In this paper we deal with only imbalance compensation. The free parameter of the Q-parameterization controller is chosen such that these goals are achieved. After the introduction of a model of the magnetic bearing system, we explain the Q-parameterization controller design of the magnetic bearing system with emphasis on the rejection of sinusoidal disturbance for imbalance compensation design. The design objectives are formulated as a linear equations in the controller free paramete Q. Finally, simulation and experimental results are presented and showed the robustness and effectiveness of the proposed controllers.

• Journal of the Korean Mathematical Society
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• v.40 no.5
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• pp.769-788
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• 2003

In this paper, we study the optimal control for the damped semilinear hyperbolic systems with unknown parameters (C(t)y')'＋ $A_2$(t, q)y'＋ $A_1$(t, q)y = f(t, q, y, u). We will prove the existence of weak solution of this system and is to find the optimal control pair (q, u) $\in$ $Q_{t}$ ${\times}$ $U_{ad}$ such that in $f_{u}$$\in$ $Q_{t}$/ J(q, u) = J(q, u).$_{t}$/ J(q, u) = J(q, u).