• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2003.10a
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• pp.334-343
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• 2003

The discharge gap clearly is to order and to promote the improvement of processing feature of die-sinking electro discharge machining(EDM). If creation carbon, which generated by Pyrolysis of EDM oil and processing pace power which is generated in between an electrode and a workpiece, are overproduced, they will lower the processing speed and roughness of the surface. Therefore, it is gone through an experiment and the flow analysis of EDM oil in order to improve the treatment of processing chips, which is an important problem by contriving a new flushing method. The condition of an electric discharge is not considered to be a progressing of processing. It is assumed that the flow of processing fluid is equal to the flow of processing chip, which is remaining in the discharge gap, and thus, analyzing then comparing with the data of the experiment and investigate its correlation.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2005.05a
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• pp.272-277
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• 2005

The discharge gap clearly is to order and to promote the improvement of processing feature of die-sinking electro discharge machining(EDM). If creation carbon, which generated by pyrolysis of EDM oil and processing pace power which is generated in between an electrode and a workpiece, are overproduced, they will lower the processing speed and roughness of the surface. Therefore, it is gone through the .flow analysis of EDM oil in order to improve the treatment of processing chips, which is an important problem by contriving a new flushing method. The condition of an electric discharge is not considered to be a progressing of processing. It is assumed that the flow of processing fluid is equal to the flow of processing chip, which is remaining in the discharge gap, and analyzing its correlation.

• Journal of Environmental Health Sciences
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• v.26 no.4
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• pp.38-44
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• 2000

Compared to other waste, waste tire has much discharge quantity and calorie. When we use waste heat from waste tire, it can be definitely better substitute energy than coal and anthracite in high oil price age. To use as a basic data for providing low cost and highly effective heating system, following conclusion was founded. Annual waste tire production was 19,596 million in 1999, Recycling ratio was almost 55% and more than 8.78 million was stored. Waste tire has lower than 1.5% sulfur contain ratio which is resource of an pollution, So it is a waste fuel which can be combustion based on current exhaust standard value without any extra SOx exclusion materials. Waste tire has 9,256Kcal/kg calorific value and it is higher than waste rubber, waste rubber, waste energy as same as B-C oil. When primary and second air quantity was 1.6, 8.0 Nm$^3$/min, dry gas production time was 270min and total combustion time was 360 min. In the SOx, NOx, HC of air pollution material density were lower than exhaust standard value at the back of cyclone and dusty than exhaust standard value without dust collector.

• Carbon letters
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• v.9 no.1
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• pp.17-22
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• 2008

A carbon nanotube (CNT) of diameter ~20 nm has been synthesized by spray pyrolysis of turpentine oil using Ni/Fe catalyst. Pellet of CNTs has been used as a target to produce semiconducting carbon thin film of band gap 1.4 eV. Presence of oxygen pressure in the pulse laser deposition (PLD) chamber helped to control the $sp^3/sp^2$ ratio to achieve the desired band gap. Results are discussed with the help of Raman spectra, SEM TEM micrographs and optical measurements suggest that semiconducting carbon thin film deposited by PLD technique has retained its nanotubes structure except that its diameter has increased from 20 nm to 150 nm.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.6
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• pp.1055-1061
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• 2000

The kinetics of tar formation has been studied experimentally and modeled mathematically for waste lubricating oil after pyrolyzed at batch reactor. And stabilization of pyrolyzed oil has been studied. A combination of series and parallel reaction was assumed for the mechanism of tar formation. From the proposed kinetic model, pyrolyzed oil to tar was found to be rate limiting step for tar formation. It was found that the fly ash and coke had the ability to remove materials of tar formation and to protect oxidation of pyrolyzed oil.

• Applied Chemistry for Engineering
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• v.28 no.4
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• pp.432-436
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• 2017

Carbon blocks were prepared by compression molding process using the mixture of isotropic cokes and binder pitches, which were reformed with different ${\beta}$-resin contents from pyrolysis fuel oil. Physical and chemical properties and also thermal behavior of binder pitches were investigated through elemental analysis, FT-IR and thermogravimetric analysis, respectively. The adhesion of binder pitches to isotropic coke particles was evaluated from SEM images of the fracture surface of carbon blocks. From these results, it is shown that the adhesion between the cokes and binder was enhanced by increasing the ${\beta}$-resin content of binder pitches. The density of the carbon block after carbonization also increased from 1.325 to $1.383g/cm^3$ by increasing the ${\beta}$-resin content of binder pitches from 1.4 to 20.1%.

• Carbon letters
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• v.25
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• pp.95-102
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• 2018

We examined the pressure effects on petroleum pitch synthesis by using open and closed reaction systems. The pressure effects that occur during the pitch synthesis were investigated in three pressure systems: a closed system of high pressure and two open systems under either an atmosphere or vacuum. A thermal reaction in the closed system led to the high product yield of a pitch by suppressing the release of light components in pyrolysis fuel oil. Atmospheric treatment mainly enhanced the polymerization degree of the pitch via condensation and a polymerization reaction. Vacuum treatment results in a softening point increase due to the removal of components with low molecular weights. To utilize such characteristic effects of system pressure during pitch preparations, we proposed a method for synthesizing cost-competitive pitch precursors for carbon materials. The first step is to increase product yield by using a closed system; the second step is to increase the degree of polymerization toward the desired molecular distribution, followed by the use of vacuum treatment to adjust softening points. Thus, we obtained an experimental quinoline insolubles-free pitch of product yield over 45% with softening points of approximately $130^{\circ}C$. The proposed method shows the possibility to prepare cost-competitive pitch precursors for carbon materials by enhancing product yield and other properties.

• Carbon letters
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• v.3 no.1
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• pp.1-5
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• 2002

The regional bio-wastes available in abundance in India were converted into porous carbon by heat treatment at different temperatures from $650-950^{\circ}C$. The wood retain shapes after pyrolysis though shrinkage occured both in axial and radial directions. The shrinkage in radial direction was found to be more than in axial direction in all woods. The density of woods and chars from these at a given temperature has been found to follow linear relationship. Chars were steam activated at temperature $700-800^{\circ}C$ for different times between 45-240 min. Both the temperature and time of activation with steam has a profound effect on surface area. Chars from softwoods like bagasse and castor oil plant were activated at lower temperature, i.e. $700-750^{\circ}C$ whereas hard wood chars have to be activated at higher temperature around $800^{\circ}C$. The morphology of wood as well as of chars has been studied by SEM. The comparison of the two showed that the nature of porosity in chars depends on precursor morphology, nature and physical state of wood and presence of inorganic compounds in the wood. Hard wood results in cross inter connected pores while softwood leads to fibriller structure. The present studies show that activated carbon with reasonably good surface area (${\sim}1000m^2/gm$) can be prepared from soft wood bio-wastes like bagasse and castor oil plant, while surface area ${\sim}1370m^2/gm$ was achieved from hard wood bio waste of pine wood.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.4
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• pp.421-430
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• 2016

To prepare mesophase pitches through low energy process, pyrolysis fuel oil with $AlCl_3$ has been modified using two-step heat treatment which is heat-treated at $330^{\circ}C$ for 3~5 h after pre-treatment at $250^{\circ}C$. The result of polarized optical microscope observation, mesophase is not observed in pitches carried out only pre-heat treatment. While mesophase content is significantly increased from 9% to 100% according to increasing secondary heat treatment time from 3 h to 5 h. Synthesizing of the mesophase pitch at low temperature of $330^{\circ}C$ is attributed to decrease of viscosity of the pitches carried out first heat treatment with $AlCl_3$. The result of Fourier-transform infrared spectroscopic analysis, it is expected that aromatization of aliphatic compounds is dominant at early secondary heat treatment, on the other hand, polycondensation reaction becomes dominant as secondary heat treatment time increases. Aromaticity and stacking height of the pitches secondary heat treated for 5 hours are more increased about 25% and 107%, respectively, than that of pitches carried out only first heat treatment.

• 한국신재생에너지학회:학술대회논문집
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• 2011.11a
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• pp.107.2-107.2
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• 2011

억새는 척박한 토양 조건에서도 쉽게 자라며 관리가 용이하다는 장점이 있어 바이오에너지 작물로 주목을 받고 있다. 억새는 주로 Miscanthus sacchariflorus(물억새)와 Miscanthus sinensis(참억새) 그리고 두 억새의 잡종인 Miscanthus giganteus로 구분되며, 최근 기존의 억새보다 생체량을 크게 늘린 거대억새가 개발되기도 하였다. 본 실험에서는 우리나라 전역에서 가장 흔하게 볼 수 있는 물억새와 참억새를 유동층 반응기를 이용하여 급속열분해 하였다. 본 연구의 목적은 억새로부터 얻은 바이오원유와 나무로부터 얻은 바이오원유의 특성을 비교하고, 시료투입속도의 변화를 주어 억새로부터 얻은 바이오원유의 수율과 특성을 알아보고자 함이다. 시료의 투입속도는 200g/h, 300g/h, 500g/h, 1000g/h로 변화를 주었으며, 반응온도($500^{\circ}C$), 공탑속도(0.19m/s), 응축기온도($10^{\circ}C$)는 매 실험마다 동일하게 유지하였다. 수집한 바이오원유는 공업분석을 통해 연료로서의 가치를 알아보았다. 목재를 급속열분해 한 경우 바이오원유의 수율은 56.03wt.%로 동일한 조건에서 억새를 급속열분해 한 경우 보다 약 6wt.%가량 높았다. 바이오원유의 발열량은 큰 차이가 없었으나 수분과 점도에서 큰 차이를 보였다. 투입속도가 증가할수록 바이오원유의 수율은 증가하는 경향을 보였으며, 시간당 1000g을 투입하였을 때는 수율이 감소하였으나 수율의 변화는 크지 않았다. 투입속도가 증가하는 경우 바이오원유의 고위발열량과 점도는 감소하고 수분이 증가하는 경향을 보였다.