• Title/Summary/Keyword: Pure lead

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Removal Characteristics of Lead by Immobilizing Agents and Immobilized Seaweed (고정화제와 고정화된 해조류에 의한 납의 제거 특성)

  • 이학성;서정호;서근학
    • Journal of Environmental Health Sciences
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    • v.27 no.1
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    • pp.83-87
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    • 2001
  • In this study, the characteristics of lead removal by PVA and alginate bead which used widely as immobilizing agents were investigated, and the difference of removal amounts between pure PVA/alginate bead and Sargassum thunbergii immobilized bead was studied. All PVA beads, pure and S. thunbergii immobilized, reached an equilibrium state in about 1 hour, and S. thunbergii immobilized bead adsorbed more lead than pure one. But in the case of alginate beads, they needed much time, about 5 hours, to reach an equilibrium state, and adsorbed lead four times higher than PVA beads. Therefore, it was considered that alginate beads had more mass transfer resistance and function groups which adsorb lead such as hydroxyl, carboxyl and etc. than PVA bead. To examine the continuous usage of alginate beads, the process of adsorption/desorption of lead was conducted repeatedly. As the process proceeded, the amounts of lead adsorption decrease, so it was indicated that the non-desorbed lead from alginate bead at first adsorption/desorption process remained constantly.

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The study on the scattering ratio at the edge of the block according to the increasing block thickness in electron therapy (전자선 치료 시 차폐블록 두께 변화에 따른 블록 주변 선량에 관한 연구)

  • Park, Zi On;Gwak, Geun Tak;Park, Ju Kyeong;Lee, Seung Hun;Kim, Yang Su;Kim, Jung Soo;Kwon, Hyoung Cheol;Lee, Sun Young
    • The Journal of Korean Society for Radiation Therapy
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    • v.31 no.1
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    • pp.57-65
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    • 2019
  • Purpose: The purpose is to clarify the effect of additional scattering ratio on the edge of the block according to the increasing block thickness with low melting point lead alloy and pure lead in electron beam therapy. Methods and materials: $10{\times}10cm^2$ Shielding blocks made of low melting point lead alloy and pure lead were fabricated to shield mold frame half of applicator. Block thickness was 3, 5, 10, 15, 20 (mm) for each material. The common irradiation conditions were set at 6 MeV energy, 300 MU / Min dose rate, gantry angle of $0^{\circ}$, and dose of 100 MU. The relative scattering ratio with increasing block thickness was measured with a parallel plate type ion chamber(Exradin P11) and phantom(RW3) by varying the position of the shielding block(cone and on the phantom), the position of the measuring point(surface ans depth of $D_{max}$), and the block material(lead alloy and pure lead). Results : When (depth of measurement / block position / block material) was (surface / applicator / pure lead), the relative value(scattering ratio) was 15.33 nC(+0.33 %), 15.28 nC(0 %), 15.08 nC(-1.31 %), 15.05 nC(-1.51 %), 15.07 nC(-1.37 %) as the block thickness increased in order of 3, 5, 10, 15, 20 (mm) respectively. When it was (surface / applicator / alloy lead), the relative value(scattering ratio) was 15.19 nC(-0.59 %), 15.25 nC(-0.20 %), 15.15 nC(-0.85 %), 14.96 nC(-2.09 %), 15.15 nC(-0.85 %) respectively. When it was (surface / phantom / pure lead), the relative value(scattering ratio) was 15.62 nC(+2.23 %), 15.59 nC(+2.03 %), 15.53 nC(+1.67 %), 15.48 nC(+1.31 %), 15.34 nC(+0.39 %) respectively. When it was (surface / phantom / alloy lead), the relative value(scattering ratio) was 15.56 nC(+1.83 %), 15.55 nC(+1.77 %), 15.51 nC(+1.51 %), 15.42 nC(+0.92 %), 15.39 nC(+0.72 %) respectively. When it was (depth of $D_{max}$ / applicator / pure lead), the relative value(scattering ratio) was 16.70 nC(-10.87 %), 16.84 nC(-10.12 %), 16.72 nC(-10.78 %), 16.88 nC(-9.93 %), 16.90 nC(-9.82 %) respectively. When it was (depth of $D_{max}$ / applicator / alloy lead), the relative value(scattering ratio) was 16.83 nC(-10.19 %), 17.12 nC(-8.64 %), 16.89 nC(-9.87 %), 16.77 nC(-10.51 %), 16.52 nC(-11.85 %) respectively. When it was (depth of $D_{max}$ / phantom / pure lead), the relative value(scattering ratio) was 17.41 nC(-7.10 %), 17.45 nC(-6.88 %), 17.34 nC(-7.47 %), 17.42 nC(-7.04 %), 17.25 nC(-7.95 %) respectively. When it was (depth of $D_{max}$ / phantom / alloy lead), the relative value(scattering ratio) was 17.45 nC(-6.88 %), 17.44 nC(-6.94 %), 17.47 nC(-6.78 %), 17.43 nC(-6.99 %), 17.35 nC(-7.42 %) respectively. Conclusions: When performing electron therapy using a shielding block, the block position should be inserted applicator rather than the patient's body surface. The block thickness should be made to the minimum appropriate shielding thickness of each corresponding using energy. Also it is useful that the treatment should be performed considering the influence of scattering dose varying with distance from the edge of block.

Electrochemical Renewal Method for Enhancing Cyclic Ability of Lead-Acid Battery (납축전지의 사이클 성능향상을 위한 전기화학적 재생방법)

  • Tae, Uk;Yang, Jeong-Jin;Hong, Kyoung-Mi;Kim, Han-Joo;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.160-164
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    • 2012
  • The lead-acid batteries are the most often used in human life, because of their low cost, good reversibility and high potential but they have limit cycle ability with low capacitance. The main causes of this problem are forming recrystallization of $PbSO_4$ on electrodes surface during cycles which the recrystallization of $PbSO_4$ is known as sulfation. In this study, formation process of sulfation was investigated depending on charge and discharge cycle numbers. And we decomposed sulfation to renew cycle ability of lead-acid batteries. The renewed lead-acid batteries recovered to 84% compared to first capacity after 600 cycles.

Demonstration of an ultrasonic imaging system for molten lead

  • Jonathan Hawes;Jordan Knapp;Robert Burrows;Robert Montague;Paul Wilcox;Hual-Te Chien;Jeff Arndt;Steve Walters
    • Nuclear Engineering and Technology
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    • v.56 no.4
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    • pp.1460-1471
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    • 2024
  • 2D and 3D ultrasonic imaging has so far not been demonstrated in pure molten lead in the open literature. In this study the development of such an ultrasonic device for imaging is outlined and results from testing at 380 ℃ in lead are presented. The main difficulties were found to be achieving then maintaining suitable wetting while ensuring suitable durability of the device, both due to the harsh nature of molten lead and the elevated temperatures. The successful detection and imaging (2D and 3D), of differently shaped targets, where the features were above the size of the transmitted ultrasound beam was demonstrated.

An Experimental Study of Environmental Effects on the Rolling Resistance of Bearings Coated by Soft Metallic Films (연금속 박막이 코팅된 베어링의 구름 저항 거동에 미치는 분위기의 영향에 대한 실험적 고찰)

  • 양승호;공호성;윤의성;김대은
    • Tribology and Lubricants
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    • v.14 no.3
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    • pp.1-6
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    • 1998
  • An experimental study was performed to discover the effect of environmental conditions on the rolling resistance behavior of pure silver and lead coated 52100 bearing steel. Pure silver and lead coatings were produced by a thermal evaporation coating method. Experiments using a thrust ball bearing-typed rolling test-rig were performed under vacuum, dry air and controlled humidity conditions. Results showed that agglomeration of particles were suppressed in vacuum environment and resulted in low and stable rolling resistance by shakedown phenomena. Also, humidity related closely to the agglomeration of particles and the rolling resistance after the failure of coated layer.

An Experimental Study of Environmental Effects on the Rolling Resistance of Bearing Surfaces Coated by Soft Metallic Films (연금속 박막이 코팅된 베어링 표면의 구름 저항 거동에 미치는 분위기의 영향에 대한 실험적 고찰)

  • 양승호;공호성;윤의성;김대은
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1998.04a
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    • pp.47-54
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    • 1998
  • An experimental study was performed to discover the effect of environmental conditions on the rolling resistance behavior of pure silver and lead coated 52100 bearing steel. Pure silver and lead coating were produced by a thermal evaporation coating method. Experiments using a thrust ball bearing-typed rolling test-rig were performed under vacuum, dry air and controlled humidity conditions. Results showed that agglomeration of particles were prevented in vacuum environment and as it showed low and stable rolling resistance by shakedown phenomena. Also, humidity relates closely to the agglomeration of particles and increased the rolling resistance after the failure of coated layer.

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Volumetric Determination of Tungsten Lead Amalgam Method (탕그스텐의 용량분석법에 관하여 -Pb 아말감법)

  • Q. Won Choi;Kyung Rok Min
    • Journal of the Korean Chemical Society
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    • v.7 no.2
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    • pp.186-188
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    • 1963
  • An attempt to improve the method of volumetric determination of tungsten developed by Luke has been made successfully. Using amalgam coated lead instead of pure metallic lead in the reduction procedure. W(VI)-W(III) reduction has been found to be quantitative in rather concentrated hydrochloric acid. Since there was no excessive dissolution of lead via reduction of hydrogen ion, lead surface was totally accessible for the reduction of tungsten and no trouble was caused by dereposition of $PbCl_2$ crystals at the nozzle of Jones reductor. Furthermore, it has been confirmed that almost 100 mg. of $WO_3$ can be handled easily if the chloride concentration of the HCl is increased by adding solid $NH_4Cl$.

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Study on the Mechanical Properties and Thermal Conductive Properties of Cu/STS/Cu Clad Metal for LED/semiconductor Package Device Lead Frame (LED 및 반도체 소자 리드프레임 패키징용 Cu/STS/Cu 클래드메탈의 기계적/열전도/전기적 특성연구)

  • Lee, Chang-Hun;Kim, Ki-Chul;Kim, Young-Sung
    • Journal of Welding and Joining
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    • v.30 no.3
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    • pp.32-37
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    • 2012
  • Lead frame which has a high thermal conductivity and high mechanical strength is one of core technology for ultra-thin electronics such as LED lead frames, memory devices of semiconductors, smart phone, PDA, tablet PC, notebook PC etc. In this paper, we fabricated a Cu/STS/Cu 3-layered clad metal for lead frame packaging materials and characterized the mechanical properties and thermal conductive properties of the clad metal lead frame material. The clad metal lead frame material has a comparable thermal conductivity to typical copper alloy lead frame materials and has a reinforced mechanical tensile strength by 1.6 times to typical pure copper lead frame materials. The thermal conductivity and mechanical tensile strength of the Cu/STS/Cu clad metal are 284.35 W/m K and $52.78kg/mm^2$, respectively.

The Specficity of Phase Transitions of Lead Monoxide (산화납의 특이상전이)

  • 김정욱;최성철;이응상
    • Journal of the Korean Ceramic Society
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    • v.30 no.8
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    • pp.623-628
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    • 1993
  • Lead monoxide has two phases at room temperature. One is a yellow orthorhombic phase, the other is a redtetragonal phase. Sometimes two phases are hybrided. The specificity of phase transitions of lead oxide is found during the milling of the batch including lead oxide. The pure orthorhombic phase of PbO can be transformed to the tetragonal phase perfectly by wet ball milling (milling liquid is distilled water) without thermal energy. However, when ethyl alcohol, isopropyl alcohol and aceton are used as milling liquid, respectively, the hybrid form of orthorhombic andtetragonal phases is obtained by wet ball milling. From the hybrid form heat-treated at $600^{\circ}C$ for 3hrs, this work results that mechanical phase transition of orthorhombic phase make a new form as distorted type orthorhombic phase of PbO.

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Study on the Performance of Heat Pump Using Non-azeotropic Refrigerant Mixtures R-22+R-114 (비공비혼합냉매 R-22+R-114를 이용한 열펌프의 성능에 관한 연구)

  • 박기원;구학근;오후규
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.17 no.9
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    • pp.2131-2137
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    • 1993
  • This study, examines the performance and the heat pump cycle systematizing characteristics for non-azeotropic refrigerant systems. In order to conduct such an examination, the cycle characteristics of heat pumps for pure R-22, R-114, and their mixtures were experimentally investigated. The results show that cooling/heating capacities for the mixtures was more suited at the evaporating temperature of $5^{\circ}C$ than that of $0^{\circ}C$, $-5^{\circ}C$, and $-10^{\circ}C$. The C.O.P of the 50 wt% mixtures was considerably higher than for pure R-22, and the compression power of the 25 wt% was as much as 60% lower than that of pure R-22. Even small fractional mixture variations can lead to significant changes in the characteristics of the heat pump cycle. This experiment verified the importance of accurate weight fractions of refrigerant mixtures.