• Title/Summary/Keyword: Pure Co

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Analysis of the Stress Generated during Phase Boundary Movement in Pure and $Co(OH)_2$ Incorporated $Ni(OH)_2$ Film Electrodes Using Laser Beam Deflection and Current Transient Techniques (레이져 빔 반사법과 전류 천이법을 이용한 순수한 니켈 수산화물과 코발트가 포함된 니켈 수산화물 전극에서 상계면 이동시 발생되는 응력 해석에 대한 연구)

  • 김광훈;변수일;한정남
    • 한국전기화학회:학술대회논문집
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    • 1999.10a
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    • pp.49-49
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    • 1999
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NO Emission Characteristics of Oxygen-Enriched Combustion with $CO_2$ Recirculation in Counterflow Diffusion Flame (대향류 화염에서 $CO_2$ 재순환 산소부화연소의 NO 배출 특성)

  • Park, June-Sung;Cho, Han-Chang;Park, Jeong
    • Journal of the Korean Society of Combustion
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    • v.12 no.1
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    • pp.28-37
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    • 2007
  • Numerical study is conducted to grasp the flame structure and NO emissions for a wide range of oxy-fuel combustion (covering from air blown combustion to pure oxygen combustion) and for various mole fractions of recirculated $CO_2$ in $CH4-O_2/N_2/CO_2$ counterflow diffusion flames. Special concern is given to the difference of the flame structure and NO emissions between air blown combustion and oxy-fuel combustion w/o recirculated $CO_2$ and is also focused on chemical effects of recirculated $CO_2$. Air blown combustion and oxy-fuel combustion w/o recirculated $CO_2$ are shown to be considerably different in the flame structure and NO emissions. Modified fuel oxidation reaction pathways in oxygen-enriched combustion are provided in detail compared to those in air blown combustion w/o recirculated $CO_2$. The formation and destruction of NO through Fenimore and thermal mechanisms are also compared for air blown combustion and oxyegn-enriched combustion w/o recirculated $CO_2$, and the role of the recirculated $CO_2$ and its chemical effects are discussed. Importantly contributing reaction steps to the formation and destruction of NO are also estimated in oxygen-enriched combustion in comparison to air blown combustion.

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Effect of Co additive on the Abnormal Grain Growth of WC (Co첨가에 의한 WC의 비정상입성장)

  • 이동범;채기웅
    • Journal of the Korean Ceramic Society
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    • v.41 no.2
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    • pp.131-135
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    • 2004
  • The effect of Co additive on the microstructural evolusion of WC was investigated. A small amount of Co powder was placed on the top-center of the pure WC powder compact and then sintered at 1950$^{\circ}C$. During sintering some abnormally large WC grains of different size and shape observed depending on the distance from the liquid source. However, in the region far away from Co liquid source, it showed low densification and the grains of WC were very small and uniform in size. A small amount of Co liquid phase has a remarkable influence on the AGG of WC and it has been explained in terms of 2-D nucleation and growth mechanism.

A Preliminary Experimental Study on the Development of Oxy-Fuel Combustion Heating System with $CO_2$ Recycle ($CO_2$ 재순환형 산소연소 가열시스템개발에 관한 실험적 연구)

  • Lee, Eun-Kyung;Go, Chang-Bok;Jang, Byung-Lok;Han, Hyung-Kee;Noh, Dong-Soon;Jeong, Yu-Seok
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.69-74
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    • 2006
  • An Experimental study was conducted on $CO_2$ recycle combustion heating system using pure oxygen instead of conventional air as an oxidant, which is thereby producing a flue gas of mostly $CO_2$ and water vapor($H_2O$) and resulting in higher $CO_2$ concentration. The advantages of the system are not only the ability to control high temperatures characteristic of oxygen combustion with recycling $CO_2$. but also the possibility to reduce NOx emission in the flue gas. A small scale industrial reheating furnace simulator and specially designed variable flame burner were used to characterize the $CO_2$ recycle oxy-fuel combustion, such as the variations of furnace pressure, temperature and composition in the flue gas during recycle. It was found that $CO_2$ concentration in the flue gas was about 80% without $CO_2$ recycle, but increased to $90{\sim}95%$ with $CO_2$ recycle. The furnace temperature and pressure was decreased due to recycle and the NOx emission was also reduced to maintain under 100ppm.

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Material Properties for Reliability Improvement in the FEA Results for Rubber Parts (고무 제품 유한요소해석 결과의 신뢰 향상을 위한 물성치 연구)

  • Baek, Un-Cheol;Cho, Maeng-Hyo;Hawong, Jai-Sug
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.11
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    • pp.1521-1528
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    • 2011
  • We studied the material properties for reliability improvement in finite element analysis results for a nitrile butadiene rubber hub-bearing seal and for a carbon-filled rubber mount used in a vehicle. It was difficult to measure the material properties of hundreds of types of rubber for the mount design. Thus, we suggested that the engineering stressstrain relations from pure shear test data could be synthesized by using simple tension data and Poisson's ratio. We defined Poisson's ratio by using a function of principal stretches to synthesize the stress-strain relations for a pure shear test. A transformation of the pure shear data was applied to the experimental values to obtain the predicted results when the strain approaches 100%. In the finite element analysis for the contact force of a hub-bearing seal, the strain results that used the transformation of the pure shear data and simple tension data almost corresponded to the experimental values. Ogden constants were used to analyze.

Performance Analysis of an Oxy-fuel Combustion Power Generation System Based on Waste Heat Recovery: Influence of CO2 Capture (배열회수형 순산소연소 발전시스템의 성능해석: CO2 포집의 영향)

  • Tak, Sang-Hyun;Park, Sung-Ku;Kim, Tong-Seop;Sohn, Jeong-Lak;Lee, Young-Duk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.33 no.12
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    • pp.968-976
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    • 2009
  • As the global warming becomes a serious environmental problem, studies of reducing $CO_2$ emission in power generation area are in progress all over the world. One of the carbon capture and storage(CCS) technologies is known as oxy-fuel combustion power generation system. In the oxy-fuel combustion system, the exhaust gas is mainly composed of $CO_2$ and $H_2O$. Thus, high-purity $CO_2$ can be obtained after a proper $H_2O$ removal process. In this paper, an oxy-fuel combustion cycle that recovers the waste heat of a high-temperature fuel cell is analyzed thermodynamically. Variations of characteristics of $CO_2$ and $H_2O$ mixture which is extracted from the condenser and power consumption required to obtain highly-pure $CO_2$ gas were examined according to the variation of the condensing pressure. The influence of the number of compression stages on the power consumption of the $CO_2$ capture process was analyzed, and the overall system performance was also investigated.

Material and Electrical Characteristics of Oxynitride Gate Dielectrics prepared in $N_2$O ambient by Rapid Thermal Process (RTP로 $N_2$O 분위기에서 제조한 Oxynitride Gate 절연체의 물질적 전기적 특성)

  • Park, Jin-Seong;Lee, Woo-Sung;Shim, Tea-Earn;Lee, Jong-Gil
    • Korean Journal of Materials Research
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    • v.2 no.4
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    • pp.285-292
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    • 1992
  • Ultrathin(8nm) oxynitride (SiOxNy) film have been formed on Si(100) by rapid thermal processing(RTP) in $O_2$and $N_2$O as reactants. Compared with conventional furnace $O_2$ oxide, the oxynitride dielectrics shows better characteristics of I-V and TDDB, and less flat-band voltage shift. The oxynitride has a behavior of Fowler-Nordheim tunneling in the region of V 〉${\varphi}_0$ simialr to pure Si$O_2$oxide. The relative dielectric constant of oxynitride is higher than that of conventional pure oxide. Excellent diffusion harrier property to dopant(B$F_2$) is also observed. Nitrogen depth profiles by SIMS, AES, and XPS show nitrogen pile - up at Si$O_2$/Si interface, which can explain the improved properties of oxynitride dielectrics.

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Polymer-Ceramic Composite Gel Polymer Electrolyte for High-Electrochemical-Performance Lithium-Ion Batteries (고성능 리튬 이온전지를 위한 폴리머-세라믹 복합 겔 고분자 전해질)

  • Jang, So-Hyun;Kim, Jae-Kwang
    • Journal of the Korean Electrochemical Society
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    • v.19 no.4
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    • pp.123-128
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    • 2016
  • In this study, poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP)-based gel polymer electrolyte incorporating nano-size $Al_2O_3$ ceramic particle was prepared by electrospinning. The gel polymer electrolyte (GPE) incorporated with $Al_2O_3$ ceramic particle showed higher ionic conductivity of $9.5{\times}10^{-2}Scm^{-1}$ than pure PVdF-HFP GPE without ceramic particle and improved the electrochemical stability up to 5.2 V. The GPEs were assembled with $LiNi_{1/3}Mn_{1/3}Co_{1/3}O_2$ (NMC) cathode for electrochemical test. The GPE batteries at 0.1 C-rate delivered $168.2mAh\;g^{-1}$ for pure GPE and $189.6mAh\;g^{-1}$ for hybrid GPE, respectively. Therefore, the incorporation of high dielectric constant ceramic particle will be good strategy to enhance the stability and electrochemical properties of lithium ion gel polymer batteries.

Effect of $K_2$CO$_3$ on Dangerous Gas Sensing Characteristics of ${\gamma}$-Fe$_2$O$_3$ Sensor. (${\gamma}$-Fe$_2$O$_3$센서의 위험성 가스 감지 특성에 $K_2$CO$_3$가 미치는 영향)

  • 임병오;박영구
    • Journal of the Korean Society of Safety
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    • v.5 no.2
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    • pp.32-39
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    • 1990
  • The ${\gamma}$-Fe$_2$O$_3$ compounds were oxidized in the furance after gas detecting sensor made molding as the Fe$_3$O$_4$ the synthesized Fe$_3$O$_4$, by ferrous sulfate and sodium hydroxide. Their sensities on carbon monoxide, ethyl alcohol and L. P. G. were measured at various temperatures, respectively. And then their electrical resistivities, thermal properties (D.T.A. & T.G.A.), were examined about their having an effet on the gas-sensing in company with the effect of pure ${\gamma}$-Fe$_2$O$_3$ and the detecting sensor ${\gamma}$-Fe$_2$O$_3$, which reacts with $K_2$CO$_3$ in the hydrothermal coundition, and the electrical conductive mechanism was reflected simultaneously. It was observed that the electrical conductivities and response ratios showed highest value at the endothermic temperature part, 300~35$0^{\circ}C$ of D.T.A.―curve. Consequently, the response ratios and response times of the hydrothermal detecting sensor were higher than that of pure detecting sensor, the specific surface areas were the highest at the endothermic range of D.T.A.-curve. These response ratios of detecting sensor for $K_2$CO$_3$, process at hydrothermal condition on carbon monoxide appeared higher than that on ethyl alcohol and in case of L.P.G. last.

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