• Title/Summary/Keyword: Pure Co

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Ultrasonic Synthesis of CoSe2-Graphene-TiO2 Ternary Composites for High Photocatalytic Degradation Performance

  • Ali, Asghar;Oh, Won-Chun
    • Journal of the Korean Ceramic Society
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    • v.54 no.3
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    • pp.205-210
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    • 2017
  • In this study, we examined the photo-degradation efficiency of $CoSe_2$-Graphene-$TiO_2$ ($CoSe_2-G-TiO_2$) nanocomposites under visible light irradiation using rhodamine B (RhB) as standard dye. $CoSe_2-G-TiO_2$ nanocomposites were synthesized by ultrasonication and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopic analysis and UV-Vis absorbance spectra analysis. Our results show that the $CoSe_2-G-TiO_2$ nanocomposite exhibited significant photo degradation efficiency compared to pure $TiO_2$ and $CoSe_2-G$, approximately 85.2% of the rhodamine (Rh B) degraded after 2.5 h. It is concluded that the $CoSe_2-G-TiO_2$ nanocomposite is a promising candidate for use in dye pollutants.

A Study of Weldability for Pure Titanium by Nd:YAG Laser(II) - Welding Properties of Butt Welding - (순티타늄판의 Nd:YAG 레이저 용접성에 관한 연구(II) - 맞대기 용접 특성 -)

  • Kim, Jong-Do;Kwak, Myung-Sub;Song, Moo-Keun;Park, Seung-Ha
    • Journal of Welding and Joining
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    • v.27 no.6
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    • pp.68-73
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    • 2009
  • Recently, as titanium and titanium alloys are being increasingly used in wide areas, there are on-going researches to obtain high quality weld zone. In particular, growing interest is being drawn to laser welding, which involves low heat input and large aspect ratio in various welding processes and can facilitate shield in atmospheric condition compared with electron beam welding. The first report covered the analysis of embrittlement by the bead color of weld zone through quantitative analysis of oxygen and nitrogen and measurement of hardness as basic experiment to apply laser welding to titanium. Results indicated that the element that affect embrittlement the most was nitrogen, and as embrittlement and oxygenation go on, bead color changed to silver, gold, brown, blue and gray. This study performed butt welding of pure titanium and STS304 by using 1kW CW Nd:YAG laser, and to find out basic physical properties, evaluated welding performance by laser output, welding speed, root gap and misalignment etc, and examined mechanical properties through tensile stress and Erichsen test. The reason particles of pure titanium welded metal and HAZ are greater than STS304 is because they are pure metal and do not include many impure elements that work as nuclei in case of resolidification, thus becoming coarse columnar crystals eventually. In addition, the reason STS304 requires more energy during welding than pure titanium is because the particle size of base metal is smaller.

A Fusion Algorithm of Pure Pursuit and Velocity Planning to Improve the Path Following Performance of Differential Driven Robots in Unstructured Environments (차동 구동형 로봇의 비정형 환경 주행 경로 추종 성능 향상을 위한 Pure pursuit와 속도 계획의 융합 알고리즘)

  • Bongsang Kim;Kyuho Lee;Seungbeom Baek;Seonghee Lee;Heechang Moon
    • The Journal of Korea Robotics Society
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    • v.18 no.3
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    • pp.251-259
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    • 2023
  • In the path traveling of differential-drive robots, the steering controller plays an important role in determining the path-following performance. When a robot with a pure-pursuit algorithm is used to continuously drive a right-angled driving path in an unstructured environment without turning in place, the robot cannot accurately follow the right-angled path and stops driving due to the ground and motor load caused by turning. In the case of pure-pursuit, only the current robot position and the steering angle to the current target path point are generated, and the steering component does not reflect the speed plan, which requires improvement for precise path following. In this study, we propose a driving algorithm for differentially driven robots that enables precise path following by planning the driving speed using the radius of curvature and fusing the planned speed with the steering angle of the existing pure-pursuit controller, similar to the Model Predict Control control that reflects speed planning. When speed planning is applied, the robot slows down before entering a right-angle path and returns to the input speed when leaving the right-angle path. The pure-pursuit controller then fuses the steering angle calculated at each path point with the accelerated and decelerated velocity to achieve more precise following of the orthogonal path.

Two-Phase Magnet in the Co/Co2MnSn System

  • Kim, Tae-Wan;Yim, Hye-In;Lee, Hyun-Yong;Lee, Kyoung-Il
    • Journal of Magnetics
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    • v.16 no.1
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    • pp.10-14
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    • 2011
  • This study reports on Co/$Co_2$MnSn two-phase magnets. The Co/$Co_2$MnSn two-phase magnet has Co precipitates in a $Co_2MnSn$ Heusler alloy matrix, in which the two phases are exchange-coupled at the phase boundary. The as-casted Co/$Co_2$MnSn system, which has Co-Mn solid solution precipitates in a $Co_2$MnSn Heusler alloy matrix, showed that the Co solid solution precipitates are crystallographically coherent and there is exchange coupling at the phase boundary. To form pure Co precipitates by removal of Mn solute atoms in Co-Mn solid solution, annealing was carried out 48 hours at $870^{\circ}C$. After annealing, the low $T_c$ and low magnetization phase of the Co-Mn solid solution became a high $T_c$ and high magnetization phase of hexagonal Co.

Preparation of Zeolite-Filled PDMS Membranes and Its Properties for Organic Vapor Separation

  • Kim, Min-Joung;Youm, Kyung-Ho
    • Korean Membrane Journal
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    • v.2 no.1
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    • pp.48-55
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    • 2000
  • In order to improve organic vapor separation efficiency of polydimethylsiloxane (PDMS) membrane, various zeolites (zeolite 4A, zeolite 13X and natural zeolite) were introduced into a thin PDMS film. The measurements of permeability and selectivity of zeolite-filled PDMS membranes were carried out with a CO$_2$gas and a CO$_2$gas/acetic acid vapor mixture, respectively. The CO$_2$permeability of zeolite-filled membranes decreased with increasing zeolite content and then recovered up to 30 wt% content. The effect of zeolite type on the improvement of CO$_2$permeability was found to be in the order of zeolite 13X > natural zeolite > 4A. The CO$_2$selectivity of zeolite-filled membranes was enhanced up to 9 times compared with the selectivity of a pure (unfilled) PDMS membrane. The effect of zeolite type on the improvement of CO$_2$selectivity was found to be in the order of natural zeolite > zeolite 13X > zeolite 4A.

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Consolidation of Binderless and Low-Binder WC hardmetal by Vacuum Sintering (진공 소결공정에 의한 고밀도 바인더리스 및 극저바인더 초경합금의 제조)

  • Min, Byoung-June;Park, Young-Ho;Lee, Gil-Geun;Ha, Gook-Hyeon
    • Journal of Powder Materials
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    • v.14 no.5
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    • pp.315-319
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    • 2007
  • Pure WC or WC with low Co concentration less than 0.5 wt.% is studied to fabricate high density WC/Co cemented carbide using vacuum sintering and post HIP process. Considering the high melting point of WC, it is difficult to consolidate it without the use of Co as binder. In this study, the effect of lower Co addition on the microstructure and mechanical properties evolution of WC/CO was investigated. By HIP process after vacuum sintering, hardness and density was sharply increased. The hardness values was $2,800kgf/mm^2$ using binderless WC.

Performance Behavior by H2 and CO as a Fuel in Intermediate Temperature Solid Oxide Fuel Cell (IT-SOFC) (중.저온형 고체산화물 연료전지에서 연료로 공급되는 CO 와 H2 가 성능에 미치는 영향)

  • Park, Kwang-Jin;Bae, Joong-Myeon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.12
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    • pp.963-969
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    • 2008
  • The performance behavior of solid oxide fuel cell using $H_2$ and CO as fuels was investigated. The power densities and impedance results showed a little variation as the ratio of $H_2$ and CO changed. However, when the pure CO was used as a fuel, area specific resistance (ASR), especially low frequency region, was increased. This might be due to carbon deposition on anode. The maximum power density was 60% lower using CO than using $H_2$. Carbon deposition reduced after constant current was applied. The SOFC performance was recovered from the carbon deposition after applying constant current during 100h.

Numerical study of CO2 hydrate dissolution rates in the ocean: Effect of pressure, temperature, and salinity

  • Kyung, Daeseung;Ji, Sukwon;Lee, Woojin
    • Advances in environmental research
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    • v.4 no.1
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    • pp.17-24
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    • 2015
  • In this study, we numerically investigated the effect of pressure (100-250 bar), temperature (274-288 K), and salinity (3.5% w/w electrolytes) on $CO_2$ hydrate dissolution rates in the ocean. Mass transfer equations and $CO_2$ solubility data were used to estimate the $CO_2$ hydrate dissolution rates. The higher pressure and lower temperature significantly reduced the $CO_2$ hydrate dissolution rates due to the increase of $CO_2$ particle density. In the high salinity condition, the rates of $CO_2$ hydrate dissolution were decreased compared to pure water control. This is due to decrease of $CO_2$ solubility in surrounding water, thus reducing the mass transfer of $CO_2$ from the hydrate particle to $CO_2$ under-saturated water. The results obtained from this study could provide fundamental knowledge to slow down or prevent the $CO_2$ hydrate dissolution for long-term stable $CO_2$ storage in the ocean as a form of $CO_2$ hydrate.

Magnetic Properties of Thin Cu/Co Multilayers Made by Electrodeposition

  • Lee, Jung-Ju;Lee, Jin-Han;Hong, Kim-In
    • Journal of Magnetics
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    • v.10 no.3
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    • pp.118-121
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    • 2005
  • We have investigated the magnetic properties of electroplated thin Cu/Co multilayers by using electrolytes made of copper sulphate and cobalt sulphate and by applying alternating plating voltage. While the multilayers plated with pure electrolyte showed superparamagnetism, those plated with organic additives showed ferromagnetic behavior. These changes are attributed to the so-called 'self-annealing' effect and reduction of grain size caused by the organic additives.