• Title/Summary/Keyword: Pulp yield

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Improvement of Hardwood Pulp Yield in Continuous Kraft Cooking and Estimation of Pulp Yields Pulp yields of isothermal cooking with polysulfide and anthraquinone

  • Ohi, Hiroshi;Yokoyama, Tomoya
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2006.06b
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    • pp.295-303
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    • 2006
  • The pulp yield was improved by about 4.5-5% when polysulfide (PS) and anthraquinone (AQ) were added to the kraft cooking liquor (white liquor). The exchange of the black liquor with fresh white liquor further increased the yield. The highest pulp yield was obtained when the PS cooking liquor containing 70% of total active alkali (AA) and 100% of AQ was used from the beginning of the reaction and the black liquor was exchanged with fresh white liquor containing the residual 30% of AA just after temperature reached $135^{\circ}C$. There was a good correlation between kraft pulp yields of a hardwood species and the ratios of the amount of xylose to glucose (X/G ratio), liberated by an acid hydrolysis of the pulps. However, the correlation was dependent on raw material wood species. Therefore, it is required in advance to establish a correlation between the yields and X/G ratios for raw material wood species of a target pulp in order to estimate pulp yield using X/G ratio. The X/G ratios of relatively high yield pulps showed higher values than those expected from the correlation. In a mill trial, the superiority of the PS-AQ isothermal cooking (ITC) process over the kraft ITC process was confirmed by examining X/G ratio of pulps obtained. The pulp yield in the PS-AQ ITC process was estimated at about 57.0%. This yield is very high, which indicates that reaction conditions of the PS-AQ ITC process are optimal.

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Preliminary Study on Organosolv Pulping of Acacia Hybrid

  • Chong, Eunice Wan Ni;Liew, Kang Chiang;Phiong, Siaw Kian
    • Journal of Forest and Environmental Science
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    • v.29 no.2
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    • pp.125-130
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    • 2013
  • An attempt was made on pulp production from the fast growing plant, Acacia hybrid to determine the total yield, screened yield, Kappa number, and fibre morphology of organosolv Acacia hybrid pulp. Uniform-sized chips were taken to undergo pulping in a digester with five different concentrations of ethanol, 50%, 60%, 70%, 80% and 90% (v/v) with 1 M of sodium hydroxide as catalyst. All chips were digested in a temperature-controlled digester with constant amount of water added and temperature of $185^{\circ}C$ with the duration of three hours cooking time and correspond pressure 1.1-1.2 MPa. It was observed that increasing of ethanol concentration has led to pulp yield increment and decreased in the degree of delignification at the same time. This study was aimed to focus on the effect of the varied concentration of organic solvent towards the pulp yield and its relationship with Kappa number and pulp yield.

Soda Pulp Properties from Corn Stalk as Raw Material (옥수수 줄기를 원료로 제조한 소다 펄프의 특성)

  • Song, Woo-Yong;Lee, Kyu-seong;Lee, Jai-Sung;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.6
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    • pp.73-80
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    • 2015
  • Corn stalk is the lignocellulosic biomass, which remain as leftover after harvesting. To use the corn stalk as raw material for paper industry, soda pulping was applied. In chemical compositional analysis, extractive contents of corn stalk (45.1%) was higher than hardwood. With corn stalk pith, soda pulp yield was 25.3% at 10.6 Kappa number, but 39.5% yield with 14.8 Kappa number for corn stalk rind. Higher extractives content in pith is one of the reason for lower pulp yield than rind. Pith pulp fibers had higher fines content than rind pulp. Pith parenchyma cell was removed as fines during pulping or washing process, which caused the lower yield. To use the corn stalks as a raw material for paper making, de-pith process is essential for higher pulp yield and longer pulp length.

Optimization of Process Variables for the Soda Pulping of Carpolobia Lutea (Polygalaceae) G. Don

  • Ogunsile, B.O.;Uba, F.I.
    • Journal of the Korean Chemical Society
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    • v.56 no.2
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    • pp.257-263
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    • 2012
  • The selection of suitable delignification conditions and optimization of process variables is crucial to the successful operation of chemical pulping processes. Soda pulping of Carpolobia lutea was investigated, as an alternative raw material for pulp and paper production. The process was optimized under the influence of three operational variables, namely, temperature, time and concentration of cooking liquor. Equations derived using a second - order polynomial design predicted the pulp yield and lignin dissolution with errors less than 8% and 11% respectively. The maximum variations in the pulp yield using a second order factorial design was caused by changes in both time and alkali concentration. Optimum pulp yield of 43.87% was obtained at low values of the process variables. The selectivity of lignin dissolution was independent of the working conditions, allowing quantitative estimations to be established between the pulp yield and residual lignin content within the range studied.

State-of-the-Art Review on High Yield Pulping Research in Japan

  • Nakano, J.
    • Journal of the Korean Wood Science and Technology
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    • v.8 no.3
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    • pp.64-76
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    • 1980
  • Fig. 8 summarizes the present status of high yield pulp production and the directions of research on modification. A thick line indicates pulping process presently in use. As mentioned previously, one kind of modification is to introduce hydrophilic groups onto the pulp. Still unsolved is whether or not the introduction of hydrophilic groups should be restricted to lignin only. Goring (28) reported that middle lamella lignin has fewer phenolic hydroxyl groups than cell wall lignin and suggested that such a difference in the lignin may be useful in the removal of middle lamella lignin. The introduction of hydrophilic groups onto pulp may not be enough to modify high yield pulp. The removal of some portion of carbohydrate may be also necessary from the standpoint of softening of pulp fibers. There is no information at what lignin and carbohydrate, and how much should be removed. The combination with synthetic high polymers may also be important in modifying high yield pulp. Prof. C. Schuerch of the State University of New York who was a visiting professor at the University of Tokyo in 1974, mentioned that the hydrophilicity of lignin would be promoted, if phenolic hydroxyl or carboxyl groups could be introduced into the aromatic nucleus of lignin. If this were possible. this process would also mean a pulp yield of more than 100%. This idea is just one example of the expectation made possible through lignin chemistry. Instead of the introduction of hydrophilic group, the oxidative degradation of aromatic nucleus of lignin may also be useful in promoting the hydrophilicity of pulp. In this case, ozone may be an excellent chemical. However, there are a lot of problems to be solved such as homogeneity of reaction and selectivity of ozone for lignin. The above ideas are summarized in Fig. 9. There are many problems to be solved in the production of an excellent high yield pulp which is comparable to chemical pulp. The information from wood chemistry hopefully will elucidate some of the problems mentioned above.

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Kraft Pulping of Sapwood-A Sawmill Waste

  • Jahant M. Sarwar;Chowdhury D.A. Nasima;Islam M. Khalidul;Mun Sung Phil
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.5 s.113
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    • pp.41-49
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    • 2005
  • This paper deals the effect of anthraquinone (AQ) on the contribution of sulphidity in kraft pulping of sapwood. The pulping conditions namely- active alkali concentration, pulpingtime, temperature and liquor ratio were varied in low ($15\%$) and high ($30\%$) sulphidity. $0.1\%$ AQ was added in the low and high sulphidity pulping with varying active alkali concentration and cooking time. At optimum conditions, low sulphidity kraft process produced about $44\%$ pulp yield with kappa number of about 23. But in high sulphidity kraft process kappa number was reduced to about 20 at the same yield. An addition of AQ reduced alkali requirement by $2\%$ on oven dried raw material and cooking time by 1 hour to produce pulp yield of about $44\%$ at kappa number 20. AQ is more effective in low sulphidity pulping than the high sulphidity pulping. The breaking length of kraft-AQ pulp was slightly higher than that of kraft pulp.

The Effect of Fines on the Property of High Yield Pulp (미세섬유(微細纖維)가 고수율(高收率)펄프의 지질(紙質)에 미치는 영향(影響))

  • Cho, Nam Seok
    • Journal of Korean Society of Forest Science
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    • v.57 no.1
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    • pp.14-19
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    • 1982
  • Fines in high-yield sulfite pulp have much higher water retention value as compared with fines in Stone groundwood pulp. Therefore, they are apt to adhere partially or entirely onto the fiber surface during the paper making. This tendency is greatly enhance with decrease of the pretreated yield and increase of the water retention value of fines. Fines, which adhere onto the fiber surface in paper, contribute to the light scattering of the paper. Accordingly, the specific scattering coefficient of fines in high-yield sulfite pulp is considerably lower than that of fines in stone groundwood pulp, which hardly adhere onto the fiber surface. The fact that high-yield sulfite pulp is inferior to stone groundwood pulp in opacity is explained on the basis of the high degree of swelling of fined in addition to the softening of fiber fraction.

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Performance Evaluation of Batch Pulp Digester using By-product (Sheath) from Bamboo Laminate Production

  • Fatoki, Jimoh Gbenga
    • Journal of Biosystems Engineering
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    • v.43 no.4
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    • pp.362-368
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    • 2018
  • Purpose: Self-sufficiency in paper production is desired in Nigeria. This study was aimed at evaluating the performance of a locally fabricated batch pulp digester. Methods: The pulp yields of sheaths generated as waste in the production of bamboo (Bambusa vulgaris) laminates were determined at different liquor concentrations and treatment time after preliminary experiments to ascertain the conditions under which the sheath started to pulp. Moreover, the optimum pulping conditions and fiber characteristics were determined and estimated, respectively, to ascertain the pulp fiber suitability for paper production. Results: An optimum pulp yield of 65.1% was obtained at 50% NaOH and 25% $Na_2S$ liquor concentration (w/w) when the cooking time was 4 h. The results of fiber characterization of the pulp indicated an average fiber length of 2.19 mm with a low Runkel ratio of 1.63, both of which signify the suitability of the pulp for medium quality paper production. Conclusions: Softwood pulp can be blended with the fibers to improve the strength of the produced paper; further investigation should be carried out to use other non-woody plants for pulp and papermaking.

The Effect of Chemical Pretreatment on Steam Explosion and Oxygen-alkali Pulping of Oak Wood (참나무재의 약액함침 처리가 폭쇄 및 산소-알칼리펄프화에 미치는 영향)

  • 박승영;최태호;조남석
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.3
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    • pp.75-83
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    • 2001
  • The potential of oxygen delignification is a powerful tool to reduce detrimental environmental effects. This study was performed to investigate the effect of steam explosion treatment of chemically treated oak wood on oxygen-alkali pulping. Pulp yield during steam explosion treatment by ${Na_2}{O_3}$-NaOH impregnation was higher than the other impregnation chemicals. Also, NaOH extraction at room temperature after steam explosion treatment improved the kappa number from 140~116 to 90~64. Oxygen-alkali pulping of chemical steam explosion treated woods affected to pulp yields. ${Na_2}{O_3}$-NaOH impregnation was very effective to higher carbohydrate yields at same delignification level. Its carbohydrate yield seemed to be highly related to the effluent pH. Oxygen-alkali pulping after steam explosion treatment of ${Na_2}{O_3}$-NaOH impregnated wood was shown that carbohydrate yield was very high because its effluent pH was increase from natural to mild alkali. Even if oxygen bleaching limit the delignification to 50% in order to avoid unacceptable yield and viscosity losses, oxygen-alkali pulping after steam explosion by ${Na_2}{O_3}$-NaOH impregnation was possible to extend the delignification more than 80%. Considering high pulp yield with lower lignin content from steam explosion treated wood, it might be profitable to end the cook at a high kappa number instead of a low kappa number, and continuously apply the oxygen delignification, in order to better quality pulp.

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Application of Naturally Antioxidant for Inhibition of Brightness Reversion of Paper Made from High Yield Bagasse Pulp

  • El-Sakhawy Mohamed;El-Ghorab Ahmed;El-Gendy Ahmed;El-Sabour Mona A.;El-Sayed Essam S. A.
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.5 s.113
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    • pp.15-24
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    • 2005
  • Different types of antioxidants compounds were prepared economically from natural sources. Application of these compounds towards photo stabilization of high yield bagasse pulp has been investigated. It was found that potato peel antioxidant followed by clove volatile oil provides lower brightness reversion and better photo stabilization effect for paper made from high yield bagasse pulp after exposure to UV lights in comparison with butyl hydroxy anisol or chamomile volatile oil.