• Journal of the Korean Institute of Telematics and Electronics A
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• v.32A no.6
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• pp.59-66
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• 1995

The hot electron induced effective channel length modulation (${\Delta}L_{H}$) and HEIP characteristics in PMOSFET's after bidirectional stress are presented. Trapped electron charges in gate oxide and lateral field are calculated from the gate current model, and ${\Delta}L_{H}$(${\Delta}L_{HD},\;{\Delta}L_{HS}$) is calculated using trapped electron charges and lateral field. It has been found that ${\Delta}I_{d}$and ${\Delta}L_{H}$ are more affected by the stress order (Forward-Reverse of Reverse or Reverse-Forward) than the stress direction, and they vary logarithmically with the stress time. In contrast, ${\Delta}V_{t}$ and ${\Delta}V_{pt}$ are more affected by the stress direction thatn the stress order. The correlation between ${\Delta}V_{pt}$ and the stress time can be explanined as the following polynomial functin: ${\Delta}V_{pt}$=AT$^{n}$. It has also been shown that PMOSFET degradation is related with the gate current and the effects of ${\Delta}V_{pt}$ is the most significant.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.208-211
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• 2007

Polymer Electrolyte Membrane fuel cell(PEMFC)의 촉매로는 주로 carbon을 지지체로 사용한 Pt/C 흑은 Pt alloy/C을 사용하게 된다. 이때 PEMFC의 상용화에 있어 촉매의 안정성은 상용화 실현에 있어 중요한 요인으로 인식되고 있다. 촉매의 성능 저하는 Pt의 활성 면적(Active surface area)의 감소가 원인으로 얘기되어 지고 있으며 이는 지지체로 사용한 탄소에 나노 크기로 분산되어 있던 Pt 입자가 커지면서 활성 면적이 감소되어 지기 때문이다. 이번 연구에서는 상용 Pt/C를 사용하여 Cyclic Voltammetry(CV)의 장기간 운전 및 다양한 조건 변화를 통하여 Pt입자의 크기 증가에 미치는 요인에 대한 연구를 진행하였다. 이와 더불어 Linear Sweep Voltammety(LSV), TEM, 등을 통한 분석이 진행되었다.

• Journal of Electrochemical Science and Technology
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• v.7 no.4
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• pp.269-276
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• 2016

Carbon-supported ordered Pt-Ti alloy nanoparticles were prepared as a durable and efficient oxygen reduction reaction (ORR) electrocatalyst for polymer electrolyte membrane fuel cells (PEMFCs) via wet chemical reduction of Pt and Ti precursors with heat treatment at $800^{\circ}C$. X-ray diffraction analysis confirmed that the prepared electrocatalysts with Ti precursor molar compositions of 40% (PtTi40) and 25% (PtTi25) had ordered $Pt_3Ti$ and $Pt_8Ti$ structures, respectively. Comparison of the ORR polarization before and after 1500 electrochemical cycles between 0.6 and 1.1 V showed little change in the ORR polarization curve of the electrocatalysts, demonstrating the high stability of the PtTi40 and PtTi25 alloys. Under the same conditions, commercial carbon-supported Pt nanoparticle electrocatalysts exhibited a negative potential shift (10 mV) in the ORR polarization curve after electrochemical cycling, indicating degradation of the ORR activity.

• Journal of Korean Society of Water and Wastewater
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• v.25 no.4
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• pp.527-534
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• 2011

In this research, the photocatalytic degradation of dibenzothiophene (DBT) in $TiO_2$ aqueous suspension has been studied. $TiO_2$ photocatalysts are prepared by a sol-gel method. The dominant anatase-structure on $TiO_2$ particles is observed after calcining the $TiO_2$ gel at $500^{\circ}C$ for 1hr. Photocatalysts with various transition metals (Nd, Pd and Pt) loading are tested to evaluate the effect of transition metal impurities on photodegradation. The photodegradation efficiencies with $TiO_2$ including Pt and Pd are higher than pure $TiO_2$ powder. Also we investigated the applicability of $H_2O_2$ to increase the efficiency of the $TiO_2$ photocatalytic degradation of dibenzothiophene. The degradation efficiency increases with increasing dosage of $H_2O_2$ in the range of 0.01M to 0.1M . The effect of pH is investigated; we obtained the maximum photodegradation efficiency at pH 5. In addition, the intermediate analysis found dihydroxyl -dibenzothiophene as a reaction intermediate of dibenzothiophene during the photodegradation.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.07a
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• pp.631-635
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• 2000

Recently, the epoxy molded type PT for indoor and applied 25.8kV was often distroyed by degradation of insulation that effected many electric stress and defect of manufactured goods. therefore In this work, We can present a method of solution in the process of produce the PT through analysis of experiments. In order to reduce the PD (Partial Discharge) which was occurred at the insulation material of epoxy resin, we has many tried to remove faults In the process of the products,

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.15 no.10
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• pp.865-869
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• 2002

The structural and electrical properties of PZT (lead zirconate titante) thin films grown on Pt (platinum) and Ru/Ru $O_2$(ruthenium/ruthenium oxide) electrodes were investigated. Thin films of PZT were deposited on a variety of electrodes using the rf-magnetron sputtering process. PZT films exhibited polycrystalline structure with strong PZT (100) plane and weak (211) plane for an optimizied Pt electrode and (100), (101), (111), (200), (210), (211) planes for Ru/Ru $O_2$. Switching polarization versus fatigue characteristic of Pt/Ti electrodes showed 20% degradation up to 1 $\times$ 10$_{9}$ cycles. No significant fatigue was observed in the films on Ru/Ru $O_2$ electrodes up to Ix109 test cycles. The results show that the new Ru/Ru $O_2$ bottom electrodes are expected to reduce the degradation of ferroelectric fatigue.

• Korean Chemical Engineering Research
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• v.52 no.6
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• pp.695-700
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• 2014

Proton Exchange Membrane Fuel Cells (PEMFC) can generate hydrogen and oxygen from water by electrolysis. But the electrode and polymer electrolyte membrane degrade rapidly during PEM water electrolysis because of high operation voltage over 1.7V. In order to reduce the rate of anode electrode degradation, unsupported $IrO_2$ catalyst was used generally. In this study, Pt/C catalyst for PEMFC was used as a water electrolysis catalyst, and then the degradation of catalyst and membrane were analysed. After water electrolysis reaction in the voltage range from 1.8V to 2.0V, I-V curves, impedance spectra, cyclic voltammograms and linear sweep voltammetry (LSV) were measured at PEMFC operation condition. The degradation rate of electrode and membrane increased as the voltage of water electrolysis increased. The hydrogen yield was 88 % during water electrolysis for 1 min at 2.0V, the performance at 0.6V decreased to 49% due to degradation of membrane and electrode assembly.

• Proceedings of the Materials Research Society of Korea Conference
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• 1998.08a
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• pp.131.2-131
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• 1998

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.09a
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• pp.67-71
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• 2001

PT of epoxy mold type have tendency to occur dielectric breakdown in high voltage system. These are using for measurement of voltage or protection of system and application voltage is 25.8kV. Therefore, for improving a lots of problems like as partial discharge, we had analyze on the destroyed Epoxy molded type PT and processing of production. As a results, we concluded that the reason of dielectric breakdown was defect of processing and degradation of insulation by electrical stress. In this work, We presented a method of solution in processing of production. which is reduction of the PO which was occurred at the insulation material. so we must many try to remove faults, these problems are mainly to winding methods of 1st coil. the other side, Reformation of 1st coil improved property of PD and we could prove it with experiments.

• Proceedings of the Materials Research Society of Korea Conference
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• 1998.08a
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• pp.41.1-41
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• 1998